Development and Prospects of M olecular-based Magnetic Materials

J4 ›› 2011, Vol. 10 ›› Issue (4): 43-47.

Development and Prospects of M olecular-based Magnetic Materials

This paper described the related issues of molecular-based magnetic materials in recent years．The classification and function of molecular magnets were introduced．Focuses on the current molecular—based magnetic materials in some of the typical single-molecule magnets，the research history and development trends were reviewed．At the same time，the hot spots of molecular magnetic materials were introduced．The prospects of molecular-based magnetic materials were also looked forward．

1．College of Pharmacy and Chemistry，Dali University，Dali，Yunnan 671000，China；
2．College of Chemical Science and Technology，Yunnan University，Kunming 650091，China

Online:2011-04-01 Published:2011-04-01

Abstract

Abstract:

Key words: molecular—based magnetic materials, molecular magnetism, coordination compounds

CLC Number:

References

[1]H．H．Wickman，A．M．Trozzolo，H．J．Williams，et a1．Spin一3／2 Iron Ferromagnet：Its MOssbauer and Magnetic Properties[J]．Phys．Rev．，1967，155：563—575．
[2] M．Soler，P．Artus，K．Folting，et a1．Si“gle—Molecule Mag—nets：Preparation and Properties of Mixed—Carboxylate Complexes[Mn。 O。 (O：CR) (O CR ) (H O) ][J]．Inorg．Chem．，2001，40：4902-4912．
[3 ] N．Arai，M．Sorai，H．Suga，et a1．Heat Capacity of a Five—coordinated Ferromagnet．Chloro bis(N．N—diethyldi—thiocarbamato)iron(III)，in the Temperature Range from 0．4 to 20 K[J]_J．Phys．Chem. Solids．，1977，38：1341—1344．
[4]赵琦华，廖代征，姜宗慧．氮氧自由基一金属配合物一维链磁体系的研究进展[J]_化学通报，2000(9)：1—7．
[5]J．S．Miller，A．J．Epstein．Prescription for Stabilization of Ferromagnetic Exchange in Molecular Ssolids via Admixing of the Ground State with a Virtual Charge——transfer Excited State[J]．J．Am．Chem．Soc．，1987，109(13)：3850—3855．

[6]LI X B，SHANG R L，SUN B W．Diaquabis(Picolinic acid N—oxide—k O O )zinc(II)[J 3．Aeta Crystallographica Section，2008(64)：131-138．
[7]R．Sessoli，H_L．Tsai，A．R．Schake，et a1．High—spin mole—cules：[Mn 2O 2(O。CR) (H2O) ][J]．J．Am．Chem．Soc．，1993．115(5)：1804—1816．
[8]J．s．Miller，J．C．Calabrese，H_Rommelmann，et a1．Ferro—Magnetic behavior of[Fe(C5Me5)2] [TCNE3一．Structural and Magnetic Characterization of DecamethylfeⅡocen m Tetra—cyanoethenide，[Fe(C5Me5)2] [TCNE]一MeCN and deca—methylferrocenium Pentacyan0pmpenide， [Fe(csMe5)2]
[C，(cN) ][J3．J．Am．Chem．Soc．，1987，109(3)：769—781．

[9] S．M．J．Aubin，N．R．Dilley，M．W．Wemple，et a1．Half-Integer—Spin Small Molecule Magnet Exhibiting Resonant Magnetization Tunneling[J]．J．Am．Chem．Soc．，1998 ,120(4)：839—840．
[10]王天维，林小驹，韦吉宗，等．单分子磁性材[J]．无机化学学报，2002，18(11)：1071—1080．
[1 1 ] A．L．Barra，P．Debrunner，D．Gatteschi，et a1．Superpara—magnetic like Behavior in an Octanuclear IronCluster[J]．Europhys．Lett．，1996，35(2)：133—138．
[12 ] C．Delfs，D．Gatteschi，L．Pardi，et a1．Magnetic Properties of an Octanuclear Iron(III)Cation[J]．Inorg．Chem．，1993．32(14)：3099—3103．
[1 3 ] W．Micklitz，S．J．Lippard．Heptadecanuclear Mixed Metal Iron Oxo—Hydroxo Complexes，[Fe16MO】0(OH)10(O2CPh)2()J，M =Mn or Co，Structurally Comprised of Two Fragments Derived from[FellO6(OH)6(02CPh)15][J]．J．Am．Chem．Soc．．1989．111(17)：6856—6858．

[14 ] S．Osa，T．Kido，N．Matsumoto。et a1．A Tetranuclear 3d一4f Single Molecule Magnet：[Cu”LTb (hfac)2]2[J]．J．Am．Chem．Soc．，2004，126(2)：420—421．
[15] G．Schmid，N．Klein．Novel Modifications of Gold．Rhodium，and Ruthenium —MI 3 Clusters as Building Blocks of “Superclusters”[J]．Angew．Chem．Int．Edit．。1986,25(10)：922—923．
[16] S．Ferlay，T．Emallsah，R．Ouahes，et a1．A Room—temper—ature Organometallic Magnet Based on Prussian Blue[J ]．Nature．1995．378：701—703．