西南石油大学学报(自然科学版) ›› 2010, Vol. 32 ›› Issue (6): 93-97.DOI: 10.3863/j.issn.1674-5086.2010.06.019

• 石油与天然气工程 • 上一篇    下一篇

草舍油田CO2驱中沥青质沉淀分析及防治措施

刘伟1,李实2,王思然3,孙 雷3,4
  

  1. 1.中国石化华东分公司,江苏 南京 225300; 2.中国石油勘探开发研究院,北京 海淀 100083;3.西南石油大学石油工程学院,四川 成都 610500; 4.“油气藏地质及开发工程”国家重点实验室.西南石油大学,四川 成都 610500
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2010-12-20 发布日期:2010-12-20

THE ASPHALTINE PRECIPITATION AND CONTROLLING MEASURES DURING THE PROCESS OF CO2 DISPLACEMENT IN CAOSHE OILFIELD

Liu Wei1,Li Shi2,WANG Si-ran3,Sun Lei3,4   

  1. 1.Huadong Branch,SINOPEC,Nanjing Jiangsu 225300,China;2.Research Institute of Petroleum Exploration and Development,CNPC,Haidian Beijing 100083,China;3.School of Petroleum Engineering,Southwest Petroleum University,Chengdu Sichuan 610500,China;4.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Southwest Petroleum University,Chengdu Sichuan 610500,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2010-12-20 Published:2010-12-20

摘要: CO2驱油容易引发地层原油中的沥青质沉淀,使渗透率降低、润湿性反转,造成地层伤害,降低注气采油效率。针对草舍油田泰州组油藏CO2驱实际,开展了CO2混相驱过程中沥青质沉淀条件、沉淀机理及其危害的研究,探讨了CO2注入参数与沥青质沉淀的热力学关系,获取了沥青质沉积前缘与注气前缘一致,在注入端、泡点压力附近沥青质沉淀最多,低驱替压差比高驱替压差对应的沥青质沉淀量高的实验结论。利用P-X相图表征第二液相与沥青质沉淀的关系,建立了油气多次接触过程中沥青质沉淀的相态预测模型,指出较低的CO2注入压力和较高的驱替压差或注入芳烃类溶剂有利于减少沥青质在近井地带沉淀,提高CO2驱替增油效果。

关键词: 草舍油田, CO2驱油, 混相驱, 沥青质沉淀, 沉淀机理, 驱替压差

Abstract: The easily precipitation of aphaltine from crude oil during the CO2 displacement results in the decreasing of permeability,wettablity alteration,the damage of the layer and reduction of gas injection recovery efficiency.This article focuses on the condition and mechanism of asphaltine precipitation and harm during the process of CO2 miscible flooding in the case study of oil reservoir of Taizhou Group in Caoshe Oilfield.After the discussion of the thermodynamic relationship between the parameters of CO2 injection and asphaltene precipitation,it can be concluded that the front of asphaltine deposition is in accordance with the front of gas injection,most of the asphaltine near the bubble point pressure on the injection side deposits and the amount of asphaltene precipitation is much more in the condition of low differential-pressure displacement than the high differential-pressure displacement.According to the relationship between the second liquid phase and asphaltine precipitation characterized by the phase diagram of P-X,the phase model predicting asphaltine precipitation during the process of the oil multi-contacting with gas is established and the asphaltine precipitation near the well-bore zones can be reduced in the condition of lower CO2 injection pressure and higher differential-pressure displacement or injecting solvent similar to aromatic hydrocarbon.The increasing of oil production by CO2 displacement is improved.

Key words: Caoshe Oilfield, CO2 displacement, miscible flooding, asphaltine precipitation, deposit mechanism, displacement pressure

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