MCM–41 介孔分子筛中负载酞菁配合物的研究

西南石油大学学报(自然科学版) ›› 2012, Vol. 34 ›› Issue (5): 153-158.

MCM–41 介孔分子筛中负载酞菁配合物的研究

崔子祥1，薛永强1，李萍2

1. 太原理工大学化学化工学院，山西太原0300242. 山西大学环境科学与工程研究中心，山西太原030006

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2012-10-01 发布日期:2012-10-01

Study of Metal-phthalocyanine Encapsulated in Mesoporous MolecularSieves MCM-41

Cui Zixiang1, Xue Yongqiang1, Li Ping2

1. College of Chemistry and Chemical Engineering；Taiyuan University of Technology，Taiyuan，Shanxi 030024，China2. Search Center of Environmental Science and Engineering，Shanxi University，Taiyuan，Shanxi 030006，China

Received:1900-01-01 Revised:1900-01-01 Online:2012-10-01 Published:2012-10-01

摘要/Abstract

摘要： 合成了Zn–酞菁化合物，通过水热法将酞菁化合物负载在MCM–41 介孔分子筛中。利用FT–IR、UV–vis–Nir、
XRD、FESEM、TEM 及N2 吸附–脱附仪对酞菁负载后的样品进行了表征。研究结果表明：较高浓度Zn–酞菁能够负
载到介孔分子筛中，并且随着酞菁配合物浓度的增加，介孔分子筛孔道的有序性及结晶度都提高。

关键词: MCM–41, 负载, Zn–酞菁配合物

Abstract: Zn-phthalocyanine complex（Ⅱ），which periphery has substituents was synthesized，and encapsulated in mesoporous
molecular sieves MCM-41. The prepared samples was characterized by FT-IR，UV-vis-Nir，XRD，FESEM，TEM and
N2 adsorption-desorption instrument. The research shows that the prepared phthalocyanine copper zinc can be encapsulated in
mesoporous molecular sieves MCM-41 in the form of monomer and dipolymer. The prepared phthalocyanine zinc with high
concentration encapsulated in MCM-41 is in favour of preparing mesoporous molecular sieves samples with higher crystallinity
and pore canal order.

Key words: MCM-41, load, phthalocyanine

崔子祥;薛永强;李萍. MCM–41 介孔分子筛中负载酞菁配合物的研究[J]. 西南石油大学学报(自然科学版), 2012, 34(5): 153-158.

Cui Zixiang;Xue Yongqiang;Li Ping. Study of Metal-phthalocyanine Encapsulated in Mesoporous MolecularSieves MCM-41[J]. 西南石油大学学报(自然科学版), 2012, 34(5): 153-158.