西南石油大学学报(自然科学版) ›› 2006, Vol. 28 ›› Issue (2): 92-96.DOI: 10.3863/j.issn.1000-2634.2006.02.024

• 石油机械工程及其它 • 上一篇    下一篇

超临界C 02对钢材的腐蚀实验研究

张颖1,2 李春福1,2 王斌2

  

  1. (1.“油气藏地质及开发工程”国家重点实验室·西南石油大学,四川成都610500; 2.西南石油大学材料科学与工程学院)
  • 收稿日期:2005-01-04 修回日期:1900-01-01 出版日期:2006-04-20 发布日期:2006-04-20
  • 通讯作者: 张颖

EXPERIMENTAL STUDY OF CORROSION OF STEEL IN SUPERCRITICAL FLUID CO2

ZHANG Ying 1,2 LI Chun-fu 1,2 WANG Bin2 et al.

  

  1. (Southwest Petroleum University, Chengdu Sichuan 610500,China )
  • Received:2005-01-04 Revised:1900-01-01 Online:2006-04-20 Published:2006-04-20
  • Contact: ZHANG Ying

摘要:

采用静态高温高压釜及SEM现代分析测试手段,在分析超临界CO2存在形式及与原油、水交互作用的基础上,进行了超临界CO2对钢材的腐性实脸研究。结果表明,在腐蚀系统SCF-CO2气相中,存在CO2腐独现象;液相中,腐饮速率随压力增加而上升,12 MPa达到峰值后下降。在纯水中12 MPa时,液相和气相中的腐独速率趋于一致,庸蚀形貌表现为庸性瘤。30%的原油含童可在液相促进钢材庸蚀,腐性形貌表现为腐蚀瘤与腐独坑并存;但随含油童增加,会抑制钢材腐蚀。

关键词: 超临界CO2腐蚀, N 80钢, 油水混相流体

Abstract: With the static high pressure and high temperature kettle and the SEM method,and based on the analysis between the supercritical fluid CO2 and the interaction of the water and oil, the corrosion experimental study for the N80 steel grade in the supercritical fluid CO2 was investigated. The results were show that the C02 corrosion was found in the SCF-CO2 gas phase. In the liquid phase, the corrosion rate was accelerated with the increas-ing of pressure; it got the peak at 12 MPa and then down. In the medium of pure water, the corrosion rate in the gas was agreed with the corrosion rate in the liquid at 12 MPa, the tubercules were observed in corrosion film. The corrosion rate in the liquid was accelerated if the civde oil content was 30%.The tuber-
rules and poles were found in the corrosion film together. The C02 corrosion of steel was restrained with the increasing of the oil content.

Key words: SCF-C02corrosion, corrosion rate, oil and water blending fluid, cormsion film

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