西南石油大学学报(自然科学版) ›› 2003, Vol. 25 ›› Issue (5): 64-66.DOI: 10.3863/j.issn.1000-2634.2003.05.18

• 油气化学工程与化工 • Previous Articles     Next Articles

REACTION MECHANISM AND CHARACTERIZATION OF A SUPER ABSORBENT RESIN OF CELLULOSE /AM/AA

ZHOU Ming1 PU Wan-fen1 YANG Yan1 ZHAO Jin-zhou2

  

  1. (Southwest Petroleum Institute, Nanchong Sichuan 637001, China)
  • Received:2002-05-28 Revised:1900-01-01 Online:2003-10-20 Published:2003-10-20

Abstract:

Reaction mechanism of a super absorbent resin (SAR) of cellulose/AM/AA, with (NH4)2Ce(No3)6as Initiator, has been studied, which is free radical mechanism that contains the process of chain initiation, chain growth, chain ending and oxidation. Identifying SAR by infrared spectroscopy (IR), the advent of characteristic peak has indicated that AA and AM have grafted on the chain of cellulose. Graft effectiveness of the SAR is determined with the method of bromine (Br) and up to 76%.

Key words: cellulose, super absorbent resin, reaction mechanism, graft effectiveness

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