西南石油大学学报(自然科学版) ›› 2004, Vol. 26 ›› Issue (4): 61-64.DOI: 10.3863/j.issn.1000-2634.2004.04.018

• 油气化学工程与化工 • 上一篇    下一篇

缔合聚合物耐温抗盐性能评价

陈洪1 翟中军1 张三辉1 郑青松2 曾玲1 许国甫1 高美丽1   

  1. 1.中石化中原油田分公司采油三厂,河南濮阳252439; 2.中石化中原油田分公司销售公司
  • 收稿日期:2003-06-04 修回日期:1900-01-01 出版日期:2004-08-20 发布日期:2004-08-20
  • 通讯作者: 陈洪

PERFORMANCE EVALUATION OF HYDROPHOBIC ASSOCIATING POLYMER ON TEMPERATURE AND SALT RESISTANCE

CHEN Hong Zhai Zhong-jun, Zhang San-hui et al   

  1. Zhongyuan Oilfield, Puyang Henan 252439, China
  • Received:2003-06-04 Revised:1900-01-01 Online:2004-08-20 Published:2004-08-20
  • Contact: CHEN Hong

摘要: 疏水缔合聚合物分子间可产生具有一定强度而又可逆的物理缔合,使聚合物体系具有良好的增粘、耐温、耐盐、抗剪切特性。在文、卫、马油田的高温高盐油藏条件下,对缔合聚合物性能进行评价,并与HPAM、AMPS聚合物进行对比。结果表明:缔合聚合物体系具有良好的抗温、抗盐及剪切恢复性能,在95℃、305块注入污水配制条件下和75℃、95块注入污水配制条件下,1 500 mg/l浓度时的体系粘度可达到11.6 mPa·s和16.5 mPa·s;缔合聚合物具有理
想的抗Fe3+离子的作用,不必考虑配制容器和注入设备产生的Fe3+离子对聚合物溶液粘度的影响;在同浓度下(>1 000 mg/l),与聚丙烯酰胺、AMPS聚合物常温增粘特性相比,缔合聚合物粘度高于前二者两个数量级以上。
    

关键词: 疏水缔合聚合物, 增粘, 耐温, 耐盐, 抗剪切

Abstract: Hydrophobic associating polymer systems have better properties in viscosity increase, temperature, salt and shearing resistance because there is some physical association with strength and reversibility between molecules of the polymer. Under the conditions of high temperature and salt reservoir in Wen、Wei、Ma oilfield, we evaluate performance of the associating polymer and compare with HPAM and AMPS. Results show that the system of the associating polymer has better properties in temperature and salt resistance and shearing recovery. In 95℃,formulated by 305 Kuai injecting waste water and in 75℃, formulated by 95 Kuai injecting waste water, when the concentra
tion is 1500ml/l, the viscosity of the system can reach 11.6 mPa.s and 16.5mPa.s. In addition, the associating polymer has perfect action on Fe3+resistance, so we needn’t consider the influence of Fe3+produced by formulating container and injecting equipment on polymer solution viscosity. At the same concentration (>1000mg/l), comparing with thickening properties of polyacrylamide and AMPS in normal temperature, the viscosity of the associating polymer is higher than the formers two orders of magnitude.

Key words: hydrophobic associating polymer, thickening, temperature resistance, salt resistance, shearing resistance

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