西南石油大学学报(自然科学版) ›› 2005, Vol. 27 ›› Issue (4): 50-53.DOI: 10.3863/j.issn.1000-2634.2005.04.15

• 油气化学工程与化工 • 上一篇    下一篇

PLS新型调剖剂的研制和应用

蒲万芬1,郭旭跃1,2,陈凯1

  

  1. 1.西南石油学院.四川成都610500; 2.人港油田南部开发公司
  • 收稿日期:2005-03-22 修回日期:1900-01-01 出版日期:2005-08-20 发布日期:2005-08-20
  • 通讯作者: 蒲万芬

A NEW PROFILE CONTROL AGENT PLS

PU Wan-fen1,GUO Xu-yao1,2, CHEN Kai1.   

  1. Southwest Petroleum Institute, Chengdu Sichuan 610500, China
  • Received:2005-03-22 Revised:1900-01-01 Online:2005-08-20 Published:2005-08-20
  • Contact: PU Wan-fen

摘要:

采用插层原位聚合法制备了聚合物/层状硅酸盐PLS复合吸水性凝胶,在考虑MMT组成、细度和表面性质的情况下,通过X衍射分析和Bragg公式计算,MMT层间距撑开0.6-1.2nm,客体分子AM+AA有效进入主体MMT层间,形成复合吸水材料——一种新的流体转向调剖剂,优化了PLS复合吸水材料的组成,并对其性能做了评价,根据水矿化度不同,PLS颗粒膨胀倍数可达13-62,抗盐25x104mg/L、耐温90℃,PLS凝胶在油中具有收缩性,当温度为90℃时,韧性系数为0.8-1.0,说明PLS材料韧性好、不易破碎。2002年通过大港官195油田官48-4-1和官45-1两个井组的现场实施,增油约2400t,效果显著.

关键词: PLS复合材料, 插层, 吸水性, 韧性, 调剖

Abstract:

A polymer/layer silicate PLS compound water absorher gel,a new kind of profile control agent,has been developed by using the monomer intercalated hybrids polymerizing method.Consideying the MMT’s constitute, fineness and surface character,through X diffraction analysis and Bragg formulae calculation,the interlamination spacing strutted by MMT is 0.6-1.2 nm.The objective numerators enter the main body of MMT’s interlamination effectively and form the compound sop stuff.In this paper, we not only optimize the construction of PLS, but also appraise its performance.Results have shown that the expanded ratio of PLS can be reached 13~62,is salt tolermore is 2.5×104mg/L,temprratare tolerance is 90℃ according to water salinity.PLS gel has contractility in the oil.Furthermore,PLS gel has good tenacity and is unbreakable when temperature is 90℃ and the tenacity coefficient reaches 0.8-1.0. Through in-situ operation on Guan 48-4-1 well and 45-1 well in Dagang Oilfield,oil production has increased to 2 400 t. The input/output ratio has been reached 6:1,which has obvious effect.

Key words: PLS compound material, intercalated bed, hydroscopicity, tenacity, profile control

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