多价金属离子对有机硼胍胶压裂液的影响及对策

doi:10.11885/j.issn.1674-5086.2018.08.12.03

西南石油大学学报(自然科学版) ›› 2019, Vol. 41 ›› Issue (3): 177-184.DOI: 10.11885/j.issn.1674-5086.2018.08.12.03

• 石油机械与油田化学 • 上一篇

多价金属离子对有机硼胍胶压裂液的影响及对策

汪志臣, 吕振虎, 董景锋, 张凤娟, 周培尧

中国石油新疆油田分公司工程技术研究院, 新疆克拉玛依 834000

收稿日期:2018-08-12 出版日期:2019-06-10 发布日期:2019-06-10
通讯作者: 吕振虎,E-mail:lvzhenhu2016@petrochina.com.cn
作者简介:汪志臣,1983年生,男,汉族,湖北黄石人,工程师,硕士,主要从事油气田储层改造方面的研究。Email:wzhichen@petrochina.com.cn;吕振虎,1990年生,男,汉族,新疆奇台人,工程师,硕士,主要从事井下控制与测量及储层改造方面的研究工作。E-mail:lvzhenhu2016@petrochina.com.cn;董景锋,1984年生,男,汉族,山东定陶人,高级工程师,博士,主要从事油气田储层改造研究。E-mail:dongjingfeng0530@petrochina.com.cn;张凤娟,1987年生,女,汉族,山东临沂人,工程师,硕士,主要从事油气田储层改造研究。E-mail:zhangfengjuan@petrochina.com.cn;周培尧,1989年生,男,汉族,湖北蕲春人,工程师,硕士,主要从事油气田储层改造研究。E-mail:zhoupeiyao@petrochina.com.cn
基金资助:
国家科技重大专项（2016ZX05070）

Influence of Multivalent Metal Ions on Organic Borate-crosslinked Guanidine Gum Fracturing Gluids: Analysis and Countermeasures

WANG Zhichen, LÜ Zhenhu, DONG Jingfeng, ZHANG Fengjuan, ZHOU Peiyao

Engineering Research Institute, PetroChina Xinjiang Oilfield Company, Karamay, Xinjiang 834000, China

Received:2018-08-12 Online:2019-06-10 Published:2019-06-10

摘要/Abstract

摘要： 针对新疆油田环玛湖地区浅层地下水、稠油热采水、压裂返排液中存在多价金属离子（Ca²⁺、Mg²⁺、Fe³⁺、Fe²⁺），影响其配制的胍胶压裂液性能。通过模拟不同种类和浓度多价金属离子水溶液，分析多价金属离子对有机硼胍胶压裂液溶胀、交联及耐温耐剪切性能的影响规律，研究了NSA、EDTA、CA，3种络合剂对多价金属离子的屏蔽效果。研究表明，多价金属离子对有机硼胍胶压裂液影响程度依次为Fe²⁺ > Fe³⁺ > Mg²⁺ > Ca²⁺；3种络合剂对Mg²⁺屏蔽能力为CA>NSA>EDTA，对Ca²⁺屏蔽能力为NSA > EDTA > CA，对Fe³⁺屏蔽能力为EDTA > NSA。为不同水质配制有机硼胍胶压裂液选择络合剂提供了依据。

关键词: 有机硼胍胶压裂液, 稠油热采水, 多价金属离子, 络合剂, 屏蔽效果

Abstract: In this study, we investigate the influence of multivalent metal ions (such as Ca²⁺, Mg²⁺, Fe³⁺, and Fe²⁺) present in shallow groundwater, heavy oil thermal recovery-produced water, and fracturing flowback fluids in the periphery of the Mahu oilfield in Xinjiang, on the performance of organic borate-crosslinked guanidine gum fracturing fluids. Through the simulations of aqueous solutions containing different types and concentrations of multivalent metal ions, the influence patterns of multivalent metal ions on the swelling, crosslinking, thermal resistance, and shear resistance properties of organic boratecrosslinked guanidine gum fracturing fluids were analyzed. Furthermore, the shielding effects of three complexing agents (NSA, EDTA, and CA) toward various multivalent metal ions were investigated. The results indicated that the order of influence of the various multivalent metal ions on organic borate-crosslinked guanidine gum fracturing fluids is Fe²⁺ > Fe³⁺ > Mg²⁺ > Ca²⁺, and the order of shielding ability of the three complexing agents toward Mg²⁺, Ca²⁺, and Fe³⁺ are CA > NSA > EDTA, NSA > EDTA > CA, and EDTA>NSA, respectively.

Key words: organic borate-crosslinked guanidine gum fracturing fluid, heavy oil thermal recovery-produced water, multivalent metal ions, complexing agents, shielding effect

中图分类号:

TE357.12

汪志臣, 吕振虎, 董景锋, 张凤娟, 周培尧. 多价金属离子对有机硼胍胶压裂液的影响及对策[J]. 西南石油大学学报(自然科学版), 2019, 41(3): 177-184.

WANG Zhichen, LÜ Zhenhu, DONG Jingfeng, ZHANG Fengjuan, ZHOU Peiyao. Influence of Multivalent Metal Ions on Organic Borate-crosslinked Guanidine Gum Fracturing Gluids: Analysis and Countermeasures[J]. 西南石油大学学报(自然科学版), 2019, 41(3): 177-184.

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http://journal15.magtechjournal.com/Jwk_xnzk/CN/Y2019/V41/I3/177

参考文献

[1] 郭晓霞,杨金华,钟新荣. 北美致密油钻井技术现状及对我国的启示[J]. 石油钻采工艺, 2014, 36(4):1-5, 9. doi:10.13639/j.odpt.2014.04.001 GUO Xiaoxia, YANG Jinhua, ZHONG Xinrong. The status of tight oil drilling technique in North America and its enlightenment to China[J]. Oil Drilling & Production Technology, 2014, 36(4):1-5, 9. doi:10.13639/j.odpt.-2014.04.001
[2] 李洪,邹灵战,汪海阁,等. 玛湖致密砂砾岩2000 m水平段水平井优快钻完井技术[J]. 石油钻采工艺, 2017, 39(1):47-52. doi:10.13639/j.odpt.2017.01.009 LI Hong, ZOU Lingzhan, WANG Haige, et al. Highquality fast drilling and completion technologies for horizontal wells with horizontal section of 2000 m long in Mahu tight glutenites[J]. Oil Drilling & Production Technology, 2017, 39(1):47-52. doi:10.13639/j.odpt.-2017.01.009
[3] 张振龙,孙慧,苏洋. 新疆干旱区水资源生态足迹与承载力的动态特征与预测[J]. 环境科学研究, 2017, 30(12):1880-1888. doi:10.13198/j.issn.1001-6929.2017.03.32 ZHANG Zhenlong, SUN Hui, SU Yang. Dynamic characteristics and prediction of ecological footprint and carrying capacity of water resources in arid areas of Xinjiang[J]. Research of Environmental Sciences, 2017, 30(12):1880-1888. doi:10.13198/j.issn.1001-6929.2017.03.32
[4] 胡俊龙. 川西气田地层水配制压裂液研究[D]. 成都:成都理工大学, 2015. HU Junlong. The study of the preparation of formation water fracturing fluid of western Sichuan Gas Field[D]. Chengdu:Chengdu University of Technology, 2015.
[5] 姜阿娜. 王家岗油田高凝油储层热污水压裂液技术[J]. 特种油气藏, 2013, 20(6):126-128. doi:10.-3969/j.issn.1006-6535.2013.06.032 JIANG A'na. Application of hot sewage fracturing fluid in High-pour-point oil reservoir of Wangjiagang Oilfield[J]. Special Oil and Gas Reservoirs, 2013, 20(6):126-128. doi:10.3969/j.issn.1006-6535.2013.06.032
[6] 马红,黄达全,李广环,等. 瓜胶压裂返排液重复利用的室内研究[J]. 钻井液与完井液, 2017, 34(4):122-126. doi:10.3969/j.issn.1001-5620.2017.04.023 MA Hong, HUANG Daquan, LI Guanghuan, et al. Laboratory study on recycling of flowback fluid of guar gun fracturing fluid[J]. Drilling Fluid & Completion Fluid, 2017, 34(4):122-126. doi:10.3969/j.issn.1001-5620.-2017.04.023
[7] 吴新民,赵建平,陈亚联,等. 压裂返排液循环再利用影响因素[J]. 钻井液与完井液, 2015, 32(3):81-85. doi:10.3969/j.issn.1001-5620.2015.03.023 WU Xinmin, ZHAO Jianping, CHEN Yalian, et al. Study on recycling of fracturing waste fluid[J]. Drilling Fluid & Completion Fluid, 2015, 32(3):81-85. doi:10.3969/j.-issn.1001-5620.2015.03.023
[8] 宁方军. 油田压裂返排液的深度处理技术研究[D]. 大庆:大庆石油学院, 2010. NING Fangjun. Study on the deep disposal of discharged fracturing fluid in oilfield[D]. Daqing:Daqing Petroleum Institute, 2010.
[9] 邹鹏,王林,张建华,等. 高价金属离子对压裂返排液循环利用的影响及其室内处理研究[J]. 石油化工应用, 2016, 35(6):135-138, 141. doi:10.3969/j.issn.-1673-5285.2016.06.033 ZOU Peng, WANG Lin, ZHANG Jianhua, et al. Influence of multivalent metal ions on reusing fracturing flowback fluid and study of a laboratory experimental disposal[J]. Petrochemical Industry Application, 2016, 35(6):135-138, 141. doi:10.3969/j.issn.1673-5285.2016.06.033
[10] 袁长忠,潘永强,杜春安,等. 胜利油田瓜胶压裂液返排液回收利用水质指标[J]. 钻井液与完井液, 2016, 33(5):109-113. doi:10.3696/j.issn.1001-5620.-2016.05.023 YUAN Changzhong, PAN Yongqiang, DU Chun'an, et al. Quality index of water for recycling flowback fluid of grar gum fracturing fluid in Shengli Oilfield[J]. Drilling Fluid & Completion Fluid, 2016, 33(5):109-113. doi:10.-3696/j.issn.1001-5620.2016.05.023
[11] ELSARAWY A M, NASR-EL-DIN H A, CAWIEZEL K E. Compatibility and rheology of high-pH borate gels prepared with produced water for hydraulic-fracturing applications[C]. SPE 185953-PA, 2018. doi:10.2118/185953-PA
[12] ELSARAWY A M, NASR-EL-DIN H A, CAWIEZEL K E. Laboratory study on using produced water in high pH borate gels used in hydraulic fracturing[C]. SPE 179553-MS, 2016. doi:10.2118/179553-MS
[13] DE KRUIJF A S, ROODHART L P, DAVIES D R. Relation between chemistry and flow mechanics of boratecrosslinked fracturing fluids[C]. SPE 25206, 1993. doi:10.2118/25206-PA
[14] 张建国,李艳,于洪江. 油层水配制压裂液研究及性能评价[J]. 西安石油大学学报(自然科学版), 2011, 26(2):60-63. doi:10.3969/j.issn.1673-064X.2011.02. 012 ZHANG Jianguo, LI Yan, YU Hongjiang. Research and evaluation of fracturing fluid compounded by oil-reservoir water[J]. Journal of Xi'an Shiyou University (Natural Science Edition), 2011, 26(2):60-63. doi:10.3969/j.issn.-1673-064X.2011.02.012
[15] 李阳,管保山,胥云,等. 高矿化度水压裂液螯合剂的研制[J]. 科学技术与工程,2016,16(14):175-180. doi:10.3969/j.issn.1671-1815.2016.14.032 LI Yang, GUAN Baoshan, XU Yun, et al. The research of complexant about using high salinity water for fracturing fluid[J]. Science Technology and Engineering, 2016, 16(14):175-180. doi:10.3969/j.issn.1671-1815.-2016.14.032
[16] 李婧,曹欣,樊炜,等. 高矿化度压裂液体系研究及室内评价[J]. 当代化工, 2017, 46(10):2142-2144, 2148. doi:10.3969/j.issn.1671-0460.2017.10.050 LI Jing, CAO Xin, FAN Wei, et al. Research and laboratory evaluation of fracturing fluid system with high salinity[J]. Contemporary Chemical Industry, 2017, 46(10):2142-2144, 2148. doi:10.3969/j.issn.1671-0460.-2017.10.050
[17] 马兵,宋汉华,牛鑫,等. 环江油田抗高矿化度压裂液体系研究[J]. 石油化工应用, 2011, 30(6):14-18. doi:10.3969/j.issn.1007-3426.2011.06.016 MA Bing, SONG Hanhua, NIU Xin, et al. High salinity resistance of fracturing fluid research in Huanjiang Oilfield[J]. Petrochemical Industry Application, 2011, 30(6):14-18. doi:10.3969/j.issn.1007-3426.2011.06.016
[18] 高峰,程芳,李强,等. 长庆气田胍胶返排液离子处理剂RXM 1研究与应用[J]. 石油化工应用, 2017, 36(12):14-17. doi:10.3969/j.issn.1673-5285.2017.12.004 GAO Feng, CHENG Fang, LI Qiang, et al.The research and application of ion treatment agent RXM-1 for the guar gum fracturing flowback fluid in Changqing Gasfield[J]. Petrochemical Industry Application, 2017, 36(12):14-17. doi:10.3969/j.issn.1673-5285.2017.12.004
[19] 尧君. 压裂返排液再配液技术的研究应用[J]. 工业水处理, 2017, 37(8):89-92. YAO Jun. Research and application of fracturing back flow & reusing fluid technology[J]. Industrial Water Treatment, 2017, 37(8):89-92.

多价金属离子对有机硼胍胶压裂液的影响及对策

Influence of Multivalent Metal Ions on Organic Borate-crosslinked Guanidine Gum Fracturing Gluids: Analysis and Countermeasures

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