磷酸酯改性呋喃树脂固砂剂的制备及性能研究

doi:10.11885/j.issn.1674-5086.2019.04.29.01

西南石油大学学报(自然科学版) ›› 2020, Vol. 42 ›› Issue (4): 173-180.DOI: 10.11885/j.issn.1674-5086.2019.04.29.01

• 石油机械与油田化学 • 上一篇

磷酸酯改性呋喃树脂固砂剂的制备及性能研究

宋金波, 赵益忠, 贾培锋, 张雨晨, 陈雪

中国石化胜利油田分公司石油工程技术研究院, 山东东营 257000

收稿日期:2019-04-29 出版日期:2020-08-10 发布日期:2020-08-10
通讯作者: 宋金波,E-mail:songjinbo.slyt@sinopec.com
作者简介:宋金波,1973年生,男,汉族,山东临清人,高级工程师,硕士,主要从事油水井防砂及采油化学剂研发工作。E-mail:songjinbo.slyt@sinopec.com;赵益忠,1980年生,男,汉族,山东青州人,高级工程师,博士,主要从事油气田防砂新技术攻关及应用研究。E-mail:zhaoyizhong.slyt@sinopec.com;贾培锋,1989年生,男,汉族,山东东营人,工程师,博士研究生,主要从事油气渗流理论方面的研究工作。E-mail:jpf89210@163.com;张雨晨,1993年生,女,汉族,山东东营人,工程师,硕士,主要从事油气田开发研究工作。E-mail:601221017@qq.com;陈雪,1985年生,女,汉族,山东济阳人,工程师,硕士,主要从事油水井防砂技术研究工作。E-mail:chenxue710.slyt@sinopec.com
基金资助:
中国石化股份公司重点科技攻关项目（217024-4）；中国石化股份公司重大科技项目（P18023-2）；中国石化股份公司重大示范工程项目（P19005-2）

Synthesis and Performance Evaluation of Phosphate-modified Furan Resin Aqueous Sand Consolidation

SONG Jinbo, ZHAO Yizhong, JIA Peifeng, ZHANG Yuchen, CHEN Xue

Petroleum Engineering Institute of Shengli Oil Field, SINOPEC, Dongying, Shandong 257000, China

Received:2019-04-29 Online:2020-08-10 Published:2020-08-10

摘要/Abstract

摘要： 针对树脂固砂剂一直存在固砂强度与地层渗透率保留率之间的矛盾，开展了磷酸酯改性呋喃树脂固砂剂的研究，研究中以磷酸、聚醚（L35）、呋喃树脂为主要原料，通过羟基缩聚制备出磷酸酯改性呋喃树脂水性聚合物，并将其用水稀释3倍后作为油田固砂剂使用，一方面，以水作为天然增孔剂，另一方面，在水环境下成膜固化，既保证了固砂强度，又保证了高地层渗透率，有效解决了长期困扰化学防砂效果的难题。研究结果表明，磷酸酯改性呋喃树脂用水稀释3倍浸入砂粒后，于水下环境中60～80℃保温48 h可固结砂粒，固砂强度大于4 MPa，适合油田水下环境固砂。截至2019年3月，现场应用10口油井，控砂成功率达100%，累计增油13 000 t，应用效果良好。

关键词: 防砂, 磷酸酯, 呋喃树脂, 水性固砂剂, 渗透率

Abstract: The study aimed at the contradiction between the strength of sand consolidation and the retention rate of formation permeability. Phosphate modified furan resin sand consolidation agent was prepared by hydroxyl polycondensation with phosphate, polyether (L35) and furan resin as main raw materials, and it was used as sand consolidation agent after dilution with water on ratio 1： 3. On the one hand, water was used as natural pore increasing agent, on the other hand, sand consolidation agent film was formed and solidified in water environment, which guaranteed compressive strength and high formation permeability. It effectively solves the difficult problem that puzzles the sand consolidation effect of chemical method for a long time. The results show that the phosphate modified furan resin can be consolidated at 60 ℃ for 48 h after dilute with water for 3 times. The compressive strength is above 4 MPa. It is suitable for sand consolidation in underwater environment of oil field. By March 2019, phosphate modified furan resin sand consolidation agent had been used in 10 wells in oilfield, with a 100% success rate of sand control and acumulative oil increase of 13 000 t. It has obtained the good effect in the practical application.

Key words: sand control, phosphate ester, furan resin, water-base sand consolidation agent, permeability

中图分类号:

TE254

宋金波, 赵益忠, 贾培锋, 张雨晨, 陈雪. 磷酸酯改性呋喃树脂固砂剂的制备及性能研究[J]. 西南石油大学学报(自然科学版), 2020, 42(4): 173-180.

SONG Jinbo, ZHAO Yizhong, JIA Peifeng, ZHANG Yuchen, CHEN Xue. Synthesis and Performance Evaluation of Phosphate-modified Furan Resin Aqueous Sand Consolidation[J]. 西南石油大学学报(自然科学版), 2020, 42(4): 173-180.

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参考文献

[1] 刘宇. 改性酚醛树脂固砂剂制备及性能研究[D]. 大庆:东北石油大学, 2016. LIU Yu. The study on preparation and sand consolidation performance of modified phenolic resin[D]. Daqing:Northeast Petroleum University, 2016.
[2] 李慧,王霞,彭健锋,等. 固砂剂防砂方法的研究发展[J]. 化工时刊, 2007, 21(9):54-57. doi:10.3969/j.issn.1002-154X.2007.09.019 LI Hui, WANG Xia, PENG Jianfeng, et al. Study and development of sand consolidating agent methods[J]. Chemical Industry Times, 2007, 21(9):54-57. doi:10.3969/j.issn.1002-154X.2007.09.019
[3] 戴彩丽,张贵才,周洪涛. 中低温油水井固砂剂实验研究[J]. 石油大学学报(自然科学版), 2001, 25(4):58-60. doi:10.3321/j.issn:1000-5870.2001.04.018 DAI Caili, ZHANG Guicai, ZHOU Hongtao. Sand-consolidation effect of middle-low temperature oil and water wells[J]. Journal of the University of Petroleum, China, 2001, 25(4):58-60. doi:10.3321/j.issn:1000-5870.2001.04.018
[4] 薛锋,佘跃惠,张文斌. 新型改性呋喃树脂固砂剂配套防砂工艺应用研究[J]. 江汉石油学院学报, 2001, 23(2):44-46. doi:10.3969/j.issn.1000-9752.2001.02.019 XUE Feng, SHE Yuehui, ZHANG Wenbin. Corollary sand control techmques with modified furane resin sand consolidation agent[J]. Journal of Jianghan Petroleum Institute, 2001, 23(2):44-46. doi:10.3969/j.issn.1000-9752.2001.02.019
[5] 吴同春. 油井化学固砂工艺研究[D]. 天津:天津大学, 2009. doi:10.7666/d.y1676118 WU Tongchun. Technical study on chemical sand consolidation of well[D]. Tianjin:Tianjin University, 2009. doi:10.7666/d.y1676118
[6] 侯影飞,孟新迪,齐升东. 水分散型活性固砂剂的制备及性能评价[J]. 油田化学, 2018, 35(1):75-80. doi:10.19346/j.cnki.1000-4092.2018.01.014 HOU Yingfei, MENG Xindi, QI Shengdong. Preparation and performance evaluation of active sand consolidation agent with water-dispersion type[J]. Oilfield Chemistry, 2018, 35(1):75-80. doi:10.19346/j.cnki.1000-4092.2018.01.014
[7] 侯燕. 树脂防砂剂在油井防砂中的应用[J]. 石化技术, 2017, 24(5):1. doi:10.3969/j.issn.1006-0235.2017.05.001 HOU Yan. Application of resin sand control agent in sand control of oil wells[J]. Petrochemical Industry Technology, 2017, 24(5):1. doi:10.3969/j.issn.1006-0235.2017.05.001
[8] 陈雄杰,艾亚强. 树脂防砂剂在油井防砂中的应用[J]. 石化技术, 2016, 23(6):138. doi:10.3969/j.issn.1006-0235.2016.06.110 CHEN Xiongjie, AI Yaqiang. Application of resin sand control agent in well sand control[J]. Petrochemical Industry Technology, 2016, 23(6):138. doi:10.3969/j.issn.1006-0235.2016.06.110
[9] 白文海,梁华林. 油砂胶结剂防砂技术在稠油开采中的应用[J]. 特种油气藏, 1996, 3(1):35-39. BAI Wenhai, LIANG Hualin. Application of sand control technique using oil sand consolidating agent in thermal recovery of heavy oil[J]. Special Oil & Gas Reservoirs, 1996, 3(1):35-39.
[10] 文华,刘义坤,程航,等. 新型固砂剂的合成与性能实验研究[J]. 油田化学, 2015, 32(4):507-510, 519. WEN Hua, LIU Yikun, CHENG Hang, et al. Synthesis and performance study of a new sand consolidation agent[J]. Oilfield Chemistry, 2015, 32(4):507-510, 519.
[11] 高斌. 细粉砂岩稳砂剂的研制及应用[J]. 油田化学, 2008, 25(3):204-206, 203. doi:10.3969/j.issn.1000-4092.2008.03.002 GAO Bin. Silicone modified phenolic epoxy resin as sand consolidating agent for fine siltstone oil reservoirs[J]. Oilfield Chemical, 2008, 25(3):204-206, 203. doi:10.3969/j.issn.1000-4092.2008.03.002
[12] LI Ailei, MU Youbing, JIANG Wei, et al. A musselinspired adhesive with stronger bonding strength under underwater conditions than under dry conditions[J]. Chemical Communications, 2015, 51(44):9117-9120. doi:10.1039/c5cc00101c
[13] 宋金波,张雨晨,贾维霞,等. 高泥质砂岩油藏防膨控砂剂体系性能评价与应用[J]. 特种油气藏, 2019, 26(4):160-164. doi:10.3969/j.issn.1006-6535.2019.04.028 SONG Jinbo, ZHANG Yuchen, JIA Weixia, et al. Performance evaluation and application of anti-swelling sand control agent system in high argillaceous sandstone oil reservoir[J]. Special Oil and Gas Reservoirs, 2019, 26(4):160-164. doi:10.3969/j.issn.1006-6535.2019.04.028
[14] 郑延成,周爱莲,赵修太,等. 无机物表面改性原理在高温防砂中的应用[J]. 钻采工艺, 2001, 24(6):76-77. doi:10.3969/j.issn.1006-768X.2001.06.027 ZHENG Yancheng, ZHOU Ailian, ZHAO Xiutai, et al. Surface modification of CaCO3 and CaO and its application in sand consolidation[J]. Drilling & Production Technology, 2001, 24(6):76-77. doi:10.3969/j.issn.1006-768X.2001.06.027
[15] 王浩. 三氟乙酸泥浆解堵固砂剂[J]. 石油钻采工艺, 2003, 25(增):67-68. doi:10.3969/j.issn.1000-7393.2003.z1.025 WANG Hao. Plug removal and sand consolidation agent of tri-fluorine acetic acid mud[J]. Oil Drilling & Production Technology, 2003, 25(S):67-68. doi:10.3969/j.issn.1000-7393.2003.z1.025
[16] 马超,赵林,刘从平. 新疆陆梁油田疏松砂岩化学固砂体系研究[J]. 石油天然气学报, 2013, 35(4):145-149. doi:10.3969/j.issn.1000-9752.2013.04.032 MA Chao, ZHAO Lin, LIU Congping. The research of loose sandstone chemical sand-consolidation system in Luliang Oilfield[J]. Journal of Oil and Gas Technology, 2013, 35(4):145-149. doi:10.3969/j.issn.1000-9752.2013.04.032
[17] 李谦定,张福哲. 一种新型固砂胶结剂的研究[J]. 天然气工业, 2004, 24(9):80-82. doi:10.3321/j.issn:1000-0976.2004.09.023 LI Qianding, ZHANG Fuzhe. Research on a novel sand consolidating agent[J]. Natural Gas Industry, 2004, 24(9):80-82. doi:10.3321/j.issn:1000-0976.2004.09.023
[18] 薛峰,刘承美,张小平,等. 化学防砂新工艺的矿场试验研究[J]. 断块油气田, 2001, 8(2):61-64. doi:10.3969/j.issn.1005-8907.2001.02.019 XUE Feng, LIU Chengmei, ZHANG Xiaoping, et al. Lease test study of new chemical sand control technique[J]. Fault-Block Oil & Gas Field, 2001, 8(2):61-64. doi:10.3969/j.issn.1005-8907.2001.02.019
[19] 宋显民,孙成林,张立民,等. 酚醛树脂防砂与改性树脂固砂[J]. 石油钻采工艺, 2002, 24(6):57-60. doi:10.3969/j.issn.1000-7393.2002.06.017 SONG Xianmin, SUN Chenglin, ZHANG Limin, et al. Sand control uses phenolic resin and sand consolidation uses modified resin[J]. Oil Drilling & Production Technology, 2002, 24(6):57-60. doi:10.3969/j.issn.1000-7393.2002.06.017
[20] 张国荣,孙磉礅,严锦根,等. 有机无机复合防砂固砂剂成型工艺的优化[J]. 化工进展, 2010, 29(增刊):533-536. ZHANG Guorong, SUN Sangdun, YAN Jingen, et al. Optimization of molding process on organic-inorganic combination sand consolidation[J]. Chemical Industry and Engineering Progress, 2010, 29(S):533-536.
[21] 朱杰,刘玉兰. 油田化学防砂技术研究进展[J]. 广东化工, 2015, 42(16):119-120, 61. doi:10.3969/j.issn.1007-1865.2015.16.055 ZHU Jie, LIU Yulan. Research progress on chemical sandcontrol technology in oilfield[J]. Guangdong Chemical Industry, 2015, 42(16):119-120, 61. doi:10.3969/j.issn.1007-1865.2015.16.055
[22] 严忠,王亮,黄连华. 固砂剂的研制及应用[J]. 新疆石油科技, 2002, 12(3):60-63, 69. YAN Zhong, WANG Liang, HUANG Lianhua. Research and application on sand consolidation[J]. Xinjiang Petroleum Technology, 2002, 12(3):60-63, 69.

磷酸酯改性呋喃树脂固砂剂的制备及性能研究

Synthesis and Performance Evaluation of Phosphate-modified Furan Resin Aqueous Sand Consolidation

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