深井含硫工况C110套管环境开裂及表面防护技术

doi:10.11885/j.issn.16745086.2021.04.28.06

西南石油大学学报(自然科学版) ›› 2021, Vol. 43 ›› Issue (4): 118-128.DOI: 10.11885/j.issn.16745086.2021.04.28.06

• 深层和非常规油气钻完井专刊 • 上一篇下一篇

深井含硫工况C110套管环境开裂及表面防护技术

邓虎¹, 李玉飞², 张智³, 卢齐¹, 侯铎³

1. 中国石油川庆钻探工程有限公司钻采工程技术研究院, 四川广汉 618300;
2. 中国石油西南油气田公司工程技术研究院, 四川成都 610031;
3. 油气藏地质及开发工程国家重点实验室·西南石油大学, 四川成都 610500

收稿日期:2021-04-28 发布日期:2021-08-06
通讯作者: 侯铎,E-mail:dragon-duo@hotmail.com
作者简介:邓虎,1974年生,男,汉族,四川阆中人,高级工程师,博士,主要从事气体钻井及欠平衡钻井研究。E-mail:dengh@cnpc.com.cn
李玉飞,1981年生,男,汉族,河南上蔡人,高级工程师,硕士,主要从事高温高压井完井试油、井完整性以及修井等方面的研究工作。E-mail:l_yf@petrochina.com.cn
张智,1976年生,男,汉族,四川南充人,教授,博士生导师,主要从事石油工程教学和科研工作。E-mail:wisezh@126.com
卢齐,1986年生,男,汉族,四川内江人,工程师,硕士,主要从事钻完井井下工具及工艺技术的研究。E-mail:luq_ccde@cnpc.com.cn
侯铎,1984年生,男,汉族,宁夏石嘴山人,讲师,博士,主要从事井筒完整性及失效分析基础研究。E-mail:dragon-duo@hotmail.com
基金资助:
中国石油-西南石油大学创新联合体科技项目（2020CX040100）；川庆钻探公司-西南石油大学工程技术联合研究院基金（CQXN-2019-03）

Environment Cracking and Surface Protection of C110 Casing in Sour and Deep Well

DENG Hu¹, LI Yufei², ZHANG Zhi³, LU Qi¹, HOU Duo³

1. CCDC Drilling & Production Engineering Technology Research Institute, Guanghan, Sichuan 618300, China;
2. Engineering Technology Research Institute, Southwest Oil & Gas Field Company, PetroChina, Chengdu, Sichuan 610031, China;
3. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China

Received:2021-04-28 Published:2021-08-06

摘要/Abstract

摘要： 深井地质复杂、井眼轨迹变化大且面临高温高压含硫等苛刻工况，套管面临磨损、腐蚀损伤、断裂失效等各类风险，针对套管C110服役于含硫腐蚀环境且承受高水平拉应力时频繁发生环境敏感断裂的问题，采用慢应变速率拉伸实验（SSRT）法，研究了表面电镀Ni-W合金的套管C110在某气田模拟地层水中的环境开裂行为，分析研究表面电镀Ni-W合金对套管C110抵抗环境敏感开裂的防护效果。结果表明，套管C110在该模拟地层水中环境开裂敏感性较高，即使腐蚀速率较低仍存在环境开裂风险，且在慢应变速率拉应力作用下呈现典型脆性断裂特征；表面电镀Ni-W合金后套管C110的抗拉强度和屈服强度分别提高2.3%和6.3%；当表面电镀Ni-W合金并经过热处理后，套管C110在模拟地层水中的抗拉强度、屈服强度、断后延伸率和应变能均明显提高、环境开裂敏感性降低，断裂方式转变为韧-脆混合型断裂，说明在套管C110表面电镀Ni-W合金并进行热处理的方式，能够有效抑制套管C110发生腐蚀、开裂及破坏的风险，显著提升其抵抗环境开裂的能力及其在深井复杂含硫工况中的适用性。

关键词: 深井, 套管, 腐蚀, 环境开裂, Ni-W 合金镀层

Abstract: The casing served in deep and ultra-deep wells with complex geological characteristics, well trajectory and high temperature, high pressure and containing H₂S, bears severe wear, corrosion, fracture and other failure risk, frequent environment sensitive cracking occurs to C110 casing when in corrosive environment and high level tensile stress. The slow strain rate test (SSRT) was used to study the environmental cracking behavior of C110 casing plated with Ni-W alloy in the simulated gas field formation water, and the protective effects of Ni-W alloy coating on C110 casing against environment sensitive cracking. The results show that the C110 casing has high sensitivity of SCC in the simulated formation water, risk of environmental cracking exists even if the corrosion rate is low, and it is characteristic of brittle fracture under the action of slow strain rate tensile test. The tensile strength and yield strength of C110 casing after Ni-W alloy surface were increased by 2.3% and 6.3%; after Ni-W alloy coating were heated, the tensile strength, yield strength, elongation and strain energy of C110 casing in simulated formation water increased significantly, the SCC sensitivity is reduced, and the fracture mode is changed into ductile brittle mixed fracture. The phenomena indicates that the Ni-W alloy coating of C110 casing and heat treatment can effectively reduce the risk of corrosion, cracking and damage of C110 casing, significantly improve its ability to resist environmental cracking and applicability in deep and ultra-deep wells.

Key words: deep well, casing, corrosion, environment cracking, Ni-W alloy coating

中图分类号:

TE245

邓虎, 李玉飞, 张智, 卢齐, 侯铎. 深井含硫工况C110套管环境开裂及表面防护技术[J]. 西南石油大学学报(自然科学版), 2021, 43(4): 118-128.

DENG Hu, LI Yufei, ZHANG Zhi, LU Qi, HOU Duo. Environment Cracking and Surface Protection of C110 Casing in Sour and Deep Well[J]. Journal of Southwest Petroleum University(Science & Technology Edition), 2021, 43(4): 118-128.

0
/ / 推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal15.magtechjournal.com/Jwk_xnzk/CN/10.11885/j.issn.16745086.2021.04.28.06

http://journal15.magtechjournal.com/Jwk_xnzk/CN/Y2021/V43/I4/118

参考文献

[1] 赵垒,闫怡飞,王鹏,等. 深井超深井套管风险评估方法[J]. 中国安全科学学报, 2019, 29(5):159-164. doi:10.16265/j.cnki.issn1003-3033.2019.05.026 ZHAO Lei, YAN Yifei, WANG Peng, et al. Risk assessment method of casing for deep and ultra-deep wells[J]. China Safety Science Journal, 2019, 29(5):159-164. doi:10.16265/j.cnki.issn1003-3033.2019.05.026
[2] 张智,刘志伟,谢玉洪,等. 井筒载荷-腐蚀耦合作用对碳钢套管服役寿命的影响[J]. 石油学报, 2017, 38(3):342-347, 362. doi:10.7623/syxb201703011 ZHANG Zhi, LIU Zhiwei, XIE Yuhong, et al. Influence of shaft load-corrosion coupling on the service life of carbon steel casing pipe[J]. Acta Petrolei Sinica, 2017, 38(3):342-347, 362. doi:10.7623/syxb201703011
[3] ZHANG Zhi, LI Jing, ZHENG Yushan, et al. Finite service life evaluation method of production casing for sour-gas wells[J]. Journal of Petroleum Science and Engineering, 2018, 165(1):171-180. doi:10.1016/j.petrol.2018.02.028
[4] 李鹏宇. 深井复杂地层套管应力分析及风险评价研究[D]. 青岛:中国石油大学(华东), 2018. doi:10.27644/d.cnki.gsydu.2018.001814 LI Pengyu. Research of stress analysis and risk assessment of casing in deep complex strata[D]. Qingdao:China University of Petroleum, 2018. doi:10.27644/d.cnki.gsydu.2018.001814
[5] 刘博. 深井套管柱可靠性评价研究[D]. 成都:西南石油大学, 2018. LIU Bo. Research on reliability evaluation of deep well casing column[D]. Chengdu:Southwest Petroleum University, 2018.
[6] 高德利,黄文君,刘永升,等. 钻柱力学与套管磨损预测若干研究进展[J]. 石油管材与仪器, 2020, 6(4):1-9. doi:10.19459/j.cnki.61-1500/te.2020.04.001 GAO Deli, HUANG Wenjun, LIU Yongsheng, et al. Some research advances in drill string mechanics and casing wear prediction for well engineering[J]. Petroleum Tubular Goods & Instruments, 2020, 6(4):1-9. doi:10.19459/j.cnki.61-1500/te.2020.04.001
[7] 张智,孔维伟,刘志伟,等. 腐蚀缺陷套管的剩余强度研究[J]. 中国科技论文,2016,11(21):2467-2472. doi:10.3969/j.issn.2095-2783.2016.21.013 ZHANG Zhi, KONG Weiwei, LIU Zhiwei, et al. Study on residual strength of corrosion defect casing[J]. China Sciencepaper, 2016, 11(21):2467-2472. doi:10.3969/j.issn.2095-2783.2016.21.013
[8] 张智,杨昆,刘和兴,等. 注水井井筒完整性设计方法[J]. 石油钻采工艺, 2020, 42(1):76-85. doi:10.13639/j.odpt.2020.01.013 ZHANG Zhi, YANG Kun, LIU Hexing, et al. A design method for the well integrity of water injector well[J]. Oil Drilling & Production Technology, 2020, 42(1):76-85. doi:10.13639/j.odpt.2020.01.013
[9] 张智,宋闯,窦雪锋,等. CO₂ 吞吐井套管腐蚀规律及极限吞吐轮次研究[J]. 西南石油大学学报(自然科学版), 2019, 41(4):135-143. doi:10.11885/j.issn.1674-5086.2018.07.17.04 ZHANG Zhi, SONG Chuang, DOU Xuefeng, et al. Study of the patterns of well casing corrosion by the CO₂ huffand-puff process and the maximum number of huff-andpuff cycles[J]. Journal of Southwest Petroleum University (Science & Technology Edition), 2019, 41(4):135-143. doi:10.11885/j.issn.1674-5086.2018.07.17.04
[10] 刘然克,张德平,郝文魁,等. H₂S分压对N80油套管钢CO₂ 环境下应力腐蚀开裂的影响[J]. 四川大学学报(工程科学版), 2013, 45(6):196-202. doi:10.15961/j.jsuese.2013.06.007 LIU Ranke, ZHANG Deping, HAO Wenkui, et al. Effect of H₂S partial pressure on stress corrosion cracking behavior of N80 oil casing steel in the environment of CO₂[J]. Journal of Sichuan University (Engineering Science Edition), 2013, 45(6):196-202. doi:10.15961/j.jsuese.2013.06.007
[11] ZHANG Zhi, ZHANG Naiyan, LIU Zhiwei, et al. Synergistic effects of corrosion time and stress on corrosion of casing steel in H₂S/CO₂ gas wells[J]. Materials and Corrosion, 2018, 69(1):386-392. doi:10.1002/maco.201709676
[12] 侯铎. 油井管环境敏感开裂适用性评价方法研究[D]. 成都:西南石油大学, 2013. HOU Duo. Applicable evaluation method on environmental cracking for tubing and casing[D]. Chengdu:Southwest Petroleum University, 2013.
[13] 苏强,陈颖杰,沈欣宇,等. 川西地区超深井井身结构优化研究与应用——以双鱼石构造为例[J]. 中国石油和化工标准与质量, 2017, 37(20):180-181, 184. doi:10.3969/j.issn.1673-4076.2017.20.083 SU Qiang, CHEN Yingjie, SHEN Xinyu, et al. Research and application of wellbore structure optimization for ultra deep wells in western of Sichuan:A case study of Shuangyushi structure[J]. China Petroleum and Chemical Standard and Quality, 2017, 37(20):180-181, 184. doi:10.3969/j.issn.1673-4076.2017.20.083
[14] 郭秀庭,任世举,彭雪梅,等. 大港油田高温深井试油套管强度校核[J]. 油气井测试, 2019, 28(6):38-43. doi:10.19680/j.cnki.1004-4388.2019.06.007 GUO Xiuting, REN Shiju, PENG Xuemei, et al. Strength check of casing in high temperature deep well test in Dagang Oilfield[J]. Well Testing, 2019, 28(6):38-43. doi:10.19680/j.cnki.1004-4388.2019.06.007
[15] IVAN S C, PENNY C, SAMSON S, et al. Corrosion of pipelines used for CO₂ transport in CCS:Is it a real problem[J]. International Journal of Greenhouse Gas Control, 2011, 5(4):749-756. doi:10.1016/j.ijggc.2011.05.010
[16] 张智,刘金铭,刘和兴,等. 页岩气井压裂过程中套管损坏的机理[J]. 天然气工业, 2019, 39(10):82-87. doi:10.3787/j.issn.1000-0976.2019.10.010 ZHANG Zhi, LIU Jinming, LIU Hexing, et al. Mechanisms of casing damage during shale gas well fracturing treatment[J]. Natural Gas Industry, 2019, 39(10):82-87. doi:10.3787/j.issn.1000-0976.2019.10.010
[17] 侯铎,施太和,曾德智,等. 电镀钨合金镀层组织及其耐腐蚀性能研究[J]. 材料导报, 2012, 26(5):12-15. doi:10.3969/j.issn.1005-023X.2012.10.004 HOU Duo, SHI Taihe, ZENG Dezhi, et al. Coating microstructure characteristics and corrosion resistance of electroplating W alloy[J]. Materials Review, 2012, 26(5):12-15. doi:10.3969/j.issn.1005-023X.2012.10.004
[18] 孙福洋,赵国仙,郭清超,等. 镍钨合金镀层对QT-900油管耐CO₂ 腐蚀的影响[J]. 表面技术, 2014, 43(6):6-10, 15. doi:10.16490/j.cnki.issn.1001-3660.2014.06.004 SUN Fuyang, ZHAO Guoxian, GUO Qingchao, et al. Effect of Ni-W alloy coating on the corrosion resistance of QT-900 coiled tubing[J]. Surface Technology, 2014, 43(6):6-10, 15. doi:10.16490/j.cnki.issn.1001-3660.2014.06.004
[19] 陈一胜,张雪辉,陈颢,等. 热处理对电沉积Ni-W合金镀层组织结构、硬度及耐蚀性的影响[J]. 材料保护, 2011, 44(4):43-45, 69. doi:10.16577/j.cnki.42-1215/tb.2011.04.006 CHEN Yisheng, ZHANG Xuehui, CHEN Hao, et al. Effect of heat treatment on microstructure and corrosion resistance of electrodeposited nickel-tungsten alloy coating[J]. Journal of Materials Protection, 2011, 44(4):43-45, 69. doi:10.16577/j.cnki.42-1215/tb.2011.04.006
[20] 徐明,胡传顺,王洪志. 热处理工艺对Ni-Cu-P化学镀层耐蚀性的影响[J]. 热加工工艺, 2015, 44(14):190-192. doi:10.14158/j.cnki.1001-3814.2015.14.053 XU Ming, HU Chuanshun, WANG Hongzhi. Effect of heat treatment process on corrosion resistance of electroless Ni-Cu-P coating[J]. Hot Working Technology, 2015, 44(14):190-192. doi:10.14158/j.cnki.1001-3814.2015.14.053
[21] 唐泽玮,姚斌,姬振宁,等. 非晶态镍钨合金镀层油管的耐CO₂ 腐蚀性能[J]. 腐蚀与防护, 2020, 41(10):12-17, 68. doi:10.11973/fsyfh-202010003 TANG Zewei, YAO Bin, JI Zhenning, et al. CO₂ corrosion resistance of amorphous nickel-tungsten alloy coated tubing[J]. Corrosion & Protection, 2020, 41(10):12-17, 68. doi:10.11973/fsyfh-202010003
[22] 程露,王亚强,张金钰,等. 合金化效应对Ni-W镀层微观组织和力学性能的影响[J]. 稀有金属材料与工程, 2021, 50(1):145-152. CHENG Lu, WANG Yaqiang, ZHANG Jinyu, et al. Effect of microalloying addition on microstructure and mechanical properties of Ni-W coatings[J]. Rare Metal Materials and Engineering, 2021, 50(1):145-152.
[23] 胡静. Ni-W-P-nSiO₂ 化学复合镀层的制备及耐蚀性研究[D]. 成都:西南石油大学, 2019. doi:10.27420/d.cnki.gxsyc.2019.000332 HU Jing. Preparation and corrosion resistance of Ni-W-P-nSiO₂ electroless composite coating[D]. Chengdu:Southwest Petroleum University, 2019. doi:10.27420/d.cnki.gxsyc.2019.000332
[24] RAMAPRAKASH M, DEEPIKA Y, BALAMURUGAN C, et al. Pulse electrodeposition of nano-crystalline Ni-W alloy and the influence of tungsten composition on structure, microhardness and corrosion properties[J]. Journal of Alloys and Compounds, 2021, 866:158987. doi:10.1016/j.jallcom.2021.158987
[25] SONG E J, BHADESHIA H K, SUH D W. Effect of hydrogen on the surface energy of ferrite and austenite[J]. Corrosion Science, 2013, 77(1):379-384. doi:10.1016/j.corsci.2013.07.043
[26] 张智,李晶,张华礼,等. 基于腐蚀时间效应的含 H₂S/CO₂ 环境中的腐蚀速率预测模型[J]. 材料保护, 2018, 51(3):41-45. doi:10.16577/j.cnki.42-1215/tb.2018.03.009 ZHANG Zhi, LI Jing, ZHANG Huali, et al. Prediction model of corrosion rate based on corrosion time effect in the environment containing[J]. Materials Protection, 2018, 51(3):41-45. doi:10.16577/j.cnki.42-1215/tb.2018.03.009
[27] EADIE R L, SZKLARZ K E, SUTHERBY R L. Corrosion fatigue and near-neutral pH stress corrosion cracking of pipeline steel and the effect of hydrogen sulfide[J]. Corrosion, 2005, 61(2):167-173. doi:10.5006/1.3278171
[28] ZHANG Zhi, ZHENG Yushan, HOU Duo, et al. The influence of hydrogen sulfide on internal pressure strength of carbon steel production casing in the gas well[J]. Journal of Petroleum Science and Engineering, 2020, 191(3):107113. doi:10.1016/j.petrol.2020.107113
[29] 伍贤柱,万夫磊,陈作,等. 四川盆地深层碳酸盐岩钻完井技术实践与展望[J]. 天然气工业, 2020, 40(2):97-105. doi:10.3787/j.issn.1000-0976.2020.02.011 WU Xianzhu, WAN Fulei, CHEN Zuo, et al. Drilling and completion technologies for deep carbonate rocks in the Sichuan Basin:Practices and prospects[J]. Natural Gas Industry, 2020, 40(2):97-105. doi:10.3787/j.issn.1000-0976.2020.02.011
[30] 王勤聪,余江松. 顺北油田超深生产井油管腐蚀变形情况研究[C]//油气田勘探与开发国际会议论文集, 2020. doi:10.26914/c.cnkihy.2020.042247 WANG Qincong, YU Jiangsong. Corrosion and deformation of ultra-deep production wells in Shunbei Oilfield[C]//International Field Exploration and Development Conference, 2020. doi:10.26914/c.cnkihy.2020.042247
[31] 赵密锋,付安庆,胡芳婷,等. 高钢级油井管在高温高压气井全生命周期环境中的腐蚀行为及寿命预测[J]. 中国腐蚀与防护学报, 2021, 41(4):535-541. ZHAO Mifeng, FU Anqing, HU Fangting, et al. Corrosion behavior and life prediction of high grade OCTG in fulllife-cycle environment of high temperature high pressure gas well[J]. Journal of Chinese Society for Corrosion and Protection, 2021, 41(4):535-541.

深井含硫工况C110套管环境开裂及表面防护技术

Environment Cracking and Surface Protection of C110 Casing in Sour and Deep Well

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	米光勇, 袁和义, 王强, 缪遥, 董广建. 四川盆地双鱼石区块深井钻井井斜规律研究[J]. 西南石油大学学报(自然科学版), 2021, 43(4): 62-70.
[2]	曾德智, 李祚龙, 李发根, 吴泽, 闫静. 复合管焊接接头整管段应力腐蚀试验方法研究[J]. 西南石油大学学报(自然科学版), 2021, 43(4): 129-137.
[3]	赵海燕, 易勇刚, 于会永, 刘振东, 曾德智. 碳酰胺复合驱吞吐井缓蚀剂优选评价[J]. 西南石油大学学报(自然科学版), 2021, 43(4): 138-146.
[4]	童传新, 张海荣, 徐璧华, 赵琥, 崔策. 深水井精细控压下套管研究[J]. 西南石油大学学报(自然科学版), 2021, 43(4): 175-182.
[5]	袁彬, 袁坤峰, 徐璧华, 颜爽. 基于固体钙含量的CO₂腐蚀水泥石规律预测[J]. 西南石油大学学报(自然科学版), 2021, 43(4): 191-198.
[6]	李皋, 李泽, 蒋祖军, 于浩, 何龙. 页岩-液体作用对套管变形的影响研究[J]. 西南石油大学学报(自然科学版), 2021, 43(1): 103-110.
[7]	何小川, 欧家强. 磨溪雷一¹气藏高效开发主体技术与成效[J]. 西南石油大学学报(自然科学版), 2020, 42(4): 144-154.
[8]	林铁军, 李朝阳, 王雪刚, 邓元洲, 宋琳. 三维复杂井眼上提冲放套管屈曲摩阻模拟研究[J]. 西南石油大学学报(自然科学版), 2020, 42(4): 165-172.
[9]	和志明, 伍东. 套损图像特征模式匹配识别技术及应用[J]. 西南石油大学学报(自然科学版), 2020, 42(2): 175-181.
[10]	张德平, 马锋, 吴雨乐, 董泽华. 用于CO₂注气驱的油井缓蚀剂加注工艺优化研究[J]. 西南石油大学学报(自然科学版), 2020, 42(2): 103-109.
[11]	胡锡辉, 李维, 徐璧华, 马旌伦, 袁彬. 水平井带扶正器套管接触方式及其对摩阻影响[J]. 西南石油大学学报(自然科学版), 2020, 42(2): 158-165.
[12]	祝效华, 郭迎春, 董亮亮. 高压井中套管缺陷对连接螺纹强度行为研究[J]. 西南石油大学学报(自然科学版), 2020, 42(2): 166-174.
[13]	陈立超, 王生维, 张典坤, 郭丁丁, 任龙锋. 陇东地区煤层气井油管柱腐蚀机理研究[J]. 西南石油大学学报(自然科学版), 2020, 42(1): 170-180.
[14]	练章华, 张琎, 王裕海, 张强, 刘永刚. 非等厚度四点弯曲试样环向应力理论研究[J]. 西南石油大学学报(自然科学版), 2020, 42(1): 161-169.
[15]	练章华, 梁建坤, 王裕海, 张强, 牟易升. C型环环向应力与加载载荷的公式推导与验证[J]. 西南石油大学学报(自然科学版), 2019, 41(5): 161-168.