西南石油大学学报(自然科学版) ›› 2002, Vol. 24 ›› Issue (2): 59-62.DOI: 10.3863/j.issn.1000-2634.2002.02.019

• 石油工程 • 上一篇    下一篇

核-壳乳液聚合及其在涂料中的应用

段明 胡星琪
  

  1. (西南石油学院化学化工学院,四川 南充 637001)
  • 收稿日期:2001-08-21 修回日期:1900-01-01 出版日期:2002-04-20 发布日期:2002-04-20
  • 通讯作者: 段明

CORE-SHELL EMULSION POLYMERIZATION AND ITS APPLICATION IN COATING

DUAN Ming HU Xing-qi.    

  1. (Southwest Petroleum Institute, Nanchong Sichuan 637001, China)
  • Received:2001-08-21 Revised:1900-01-01 Online:2002-04-20 Published:2002-04-20
  • Contact: DUAN Ming

摘要: 综述了近10年来核-壳乳液聚合理论的发展,其中包括聚合机理:聚合物沉积机理和种子粒子表面聚合机理;核-壳粒子的制备方法:间歇法、平衡溶胀法、半连续法、连续法;常见的核-壳结构乳胶粒子的几种形态结构以及影响形态结构的动力学和热力学因素、并介绍了核壳结构的表征方法包括对成膜能力的评价。最后介绍了核-壳乳液聚合在涂料中的应用。

关键词: 聚合物, 形态, 成膜能力, 涂料

Abstract: The developments of the theory on core-shell emulsion polymerization during the past ten years have been summarized,which includes that polymerization mechanism—polymers aggradations and polymerization in the surface of particles;preparation methods for core-shell particles—batch, equilibrium
swelling, semi-continuous and continuous; several morphologies and structures of common emulsoid particles and influencing fac-tors of thermodynamics and dynamics; and characteristic meth-ods of core-shell structure including the ability of films forma-tion. Finally applications in coating are introduced.

Key words: polymer, morphology, ability of films forma-tion, coating

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