气体混相驱与最小混相压力测定研究进展

doi:10.11885/j.issn.16745086.2016.01.14.01

摘要/Abstract

摘要： 气体混相驱具有对地下环境影响小、采收系数高、可同时实现温室气体封存等优点。在优选注气工艺时，岩芯驱替实验、气体与原油的最小混相压力测定（MMP）是油藏实现混相驱的基础。针对上述问题，首先讨论了混相驱岩芯驱替实验的影响因素，其次分析了地层温度、气体组成、原油组成等条件对MMP的影响，再次，对比分析了不同测定MMP的实验方法，最后，对近年来新研发的MMP测试手段进行了归纳总结。当用天然岩芯进行混相驱研究时，为达到混相建议选择尽可能长的岩芯。MMP的测试手段种类繁多，但目前仍未形成公认的实验方法。

关键词: 混相驱, 最小混相压力, 注气, 提高采收率, 岩芯驱替

Abstract: Miscible gas flooding has the advantages of negligible effects on the underground environment, high recovery efficiency, and simultaneous storage of greenhouse gases. In the process of optimizing gas injection procedures, core displacement experiments and measurement of the minimum miscibility pressure (MMP) of the gas and crude oil are the basis for the miscible displacement of the oil reservoir. To solve the above problems, the factors influencing miscible core flooding were discussed. Secondly, the effects of formation temperature, gas composition, and crude oil composition on MMP were analyzed. Additionally, the different experimental methods for determining MMP were analyzed and compared. Finally, the new research and development of MMP test methods in recent years were summarized. When using natural cores for miscible flooding studies, it is advisable to select cores as long as possible to achieve miscibility. There is a wide range of MMP test methods, but there is no widely accepted experimental method.

Key words: miscible flooding, minimum miscibility pressure, gas injection, enhanced oil recovery, core displacement

中图分类号:

TE357

梁萌, 袁海云, 杨英, 杨云博, 蔺江涛. 气体混相驱与最小混相压力测定研究进展[J]. 西南石油大学学报(自然科学版), 2017, 39(5): 101-112.

LIANG Meng, YUAN Haiyun, YANG Ying, YANG Yunbo, LIN Jiangtao. Research Progress on Miscible Gas Displacement and Determination of Minimum Miscibility Pressure[J]. 西南石油大学学报(自然科学版), 2017, 39(5): 101-112.

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参考文献

[1] LEENA K. 2014 worldwide EOR survey[J]. Oil & Gas Journal, 2014, 112(4):79-91.
[2] JAMES J P, JAMES S P. Measurement and correlation of CO₂ miscibility pressures[C]. SPE 9790, 1981. doi:10.-2118/9790-MS
[3] VAHIDI A, GHASSEM Z. Sensitivity analysis of important parameters affecting minimum miscibility pressure (MMP) of nitrogen injection into conventional oil reservoirs[C]. SPE 111411, 2007. doi:10.2118/111411-MS
[4] MENOUAR H. Discussion on carbon dioxide minimum miscibility pressure estimation:an experimental investigation[C]. SPE 165351, 2013. doi:10.2118/165351-MS
[5] DONG M, HUANG S, SRIVASTAVA R. Effect of solution gas in oil on CO₂ minimum miscibility pressure[J]. Journal of Canadian Petroleum Technology, 2000, 39(11):53-61. doi:10.2118/165351-MS
[6] ADEKUNLE O O, HOFFMAN B T. Minimum miscibility pressure studies in the bakken[C]. SPE 169077, 2014. doi:10.2118/169077-MS
[7] GHORBANI M, MOMENI A, MORADY B. New correlation for calculation of hydrocarbon gas minimum miscibility pressure (mmp) using wide experimental data[J]. Petroleum Science and Technology, 2013, 31(24):2577-2584. doi:10.1080/10916466.2011.561264
[8] HOU M Z, XIE H, YOON J. Underground storage of CO₂ and energy[M]. Florida:CRC Press, 2010.
[9] 杨红,余华贵. 原油组分对CO₂最小混相压力的影响[J]. 精细石油化工进展, 2014, 15(6):2527. doi:10.3969/j.issn.1009-8348.2014.06.007 YANG Hong, YU Huagui. Experimental study on impact of crude oil components on minimum miscibility pressure between CO₂ and crude oil[J]. Advances in Fine Petrochemicals, 2014, 15(6):25-27. doi:10.3969/j.issn.1009-8348.2014.06.007
[10] HEMMATI-SARAPARDEH A, AYATOLLAHI S, GHAZANFARI M H, et al. Experimental determination of interfacial tension and miscibility of the CO₂-crude oil system; temperature, pressure, and composition effects[J]. Journal of Chemical & Engineering Data, 2014, 59(1):946-955. doi:10.1021/je400811h
[11] XU Anzhu, MU Longxin, ZHAO Liangdong, et al. Analysis of miscibility of high sour component (H₂S and CO₂) content gas flooding under abnormal reservoir pressure[C]. SPE 176491, 2015. doi:10.2118/176491-MS
[12] 尚宝兵,廖新维,赵晓亮,等. 杂质气体对二氧化碳驱最小混相压力和原油物性的影响[J]. 油气地质与采收率,2014,21(6):9294,98. doi:10.3969/j.issn.1009-9603.2014.06.023 SHANG Baobing, LIAO Xinwei, ZHAO Xiaoliang, et al. Research about the influence of impurities on MMP and crude oil properties for CO₂ flooding[J]. Petroleum Geology and Recovery Efficiency, 2014, 21(6):92-94, 98. doi:10.3969/j.issn.1009-9603.2014.06.023
[13] YANG Fulin, ZHAO Guibing, ADIDHARMA H, et al. Effect of oxygen on minimum miscibility pressure in carbon dioxide flooding[J]. Industrial & Engineering Chemistry Research, 2007, 46(4):1396-1401. doi:10.1021/-ie061279g
[14] BELHAJ H, ABUKHALIFEH H, JAVID K. Miscible oil recovery utilizing N₂ and/or HC gases in CO₂ injection[J]. Journal of Petroleum Science and Engineering, 2013, 111(11):144-152. doi:10.1016/j.petrol.2013.08.-030
[15] Нефть. Метод определения коэффициента вытеснения нефти водой в лабораторных условиях[C]. Министерство нефтяной промышленности ОСТ, 39-195-86,1986.
[16] YANG Wenzhe, ZHANG Liang, LIU Yu, et al. Dynamic stability characteristics of fluid fl34853. doi:10.1039/C5RA01877C
[17] SONG Yongchen, YANG Wenzhe, WANG Dayong, et al. Magnetic resonance imaging analysis on the in-situ mixing zone of CO₂ miscible displacement flows in porous media[J]. Journal of Applied Physics, 2014, 115(24):401-410. doi:10.1063/1.4885057
[18] ALEIDAN A, MAMORA D. Comparative study of oil recovery during miscible CO₂ injection in carbonate cores and slimtube[C]. SPE 155411, 2011. doi:10.2118/155411-MS
[19] ABDULRAZAG Z, AL-ATTAR H, AL-FARISI O, et al. Experimental investigation of the effect of injection water salinity on the displacement efficiency of miscible carbon dioxide WAG flooding in a selected carbonate reservoir[J]. Journal of Petroleum Exploration and Production Technology, 2015, 5(4):363-373. doi:10.1007/s13202-015-0155-0
[20] AYIRALA S C, RAO D N, CASTEEL J. Comparison of minimum miscibility pressures determined from gas-oil interfacial tension measurements with equation of state calculations[C]. SPE 84187, 2003. doi:10.2118/84187-MS
[21] NEGAHBAN S, SHIRALKAR G S, GUPTA S P. Simulation of the effects of mixing in gasdrive core tests of reservoir fluids[J]. SPE Reservoir Engineering, 1990, 5(3):402-408. doi:10.2118/17377-PA
[22] NOUAR A, FLOCK D L. Parametric analysis on the determination of the minimum miscibility pressure in slim tube displacements[J]. Journal of Canadian Petroleum Technology, 1983, 23(5):80-88. doi:10.2118/84-05-12
[23] EKUNDAYO J M, GHEDAN S G. Minimum miscibility pressure measurement with slim tube apparatus-how unique is the value?[C]. SPE 165966, 2013. doi:10.2118/-165966-MS
[24] LINDELOFF N, MOGENSEN K, SCHOU P K, et al. Investigation of miscibility behavior of CO₂-rich hydrocarbon systems-with implications for gas injection EOR[C]. SPE 166270, 2013. doi:10.2118/166270-MS
[25] LI F F, YANG S L, CHEN H, et al. An improved method to study CO₂-oil relative permeability under miscible conditions[J]. Journal of Petroleum Exploration & Production Technology, 2015, 5(1):45-53. doi:10.1007/s13202-014-0122-1
[26] OMOLE O, OSOBA J S. Effect of column length on CO₂-crude oil miscibility pressure[J]. Journal of Canadian Petroleum Technology, 1989, 28(4):97-102. doi:10.2118/-89-04-07
[27] EKUNDAYO J M. Configuration of slim tube apparatus for consistent determination of minimum miscibility pressure (MMP) data[J]. Dissertations & Theses-Gradworks, 2012.
[28] 郭平,李苗. 低渗透砂岩油藏注CO₂混相条件研究[J]. 石油与天然气地质, 2007, 28(5):687692. doi:10.-3321/j.issn:0253-9985.2007.05.022 GUO Ping, LI Miao. A study on the miscible conditions of CO₂ injection in low-permeability sandstone reservoirs[J]. Oil & Gas Geology, 2007, 28(5):687-692. doi:10.3321/-j.issn:0253-9985.2007.05.022
[29] TUYET H L. The effect of flow rate and core length on the longitudinal dispersion coefficient[D]. Canada:University of Alberta, 1995.
[30] YELLIG W F, BAKER L E. Factors affecting miscible flooding dispersion coefficients[J]. Journal of Canadian Petroleum Technology, 1981, 20(4):69-75. doi:10.2118/-81-04-04
[31] Хлебников В Н, Губанов В Б, Полищук А М. Использование слим-моделей пласта дляфизического моделирования процессов вытеснения нефти смешивающимися агентами. Часть3. Особенности массопереноса при вытеснении нефти двуокисью углерода[J]. Нефтепромысловое дело, 2014(9):43-47.
[32] Полищук А М, Хлебников В Н, Губанов В Б. Использование слим-моделей пласта(slim tubе) для физического моделирования процессов вытеснения нефти смешивающимися агентами. Часть1. Методология эксперимента[J]. Нефтепромысловое дело, 2014(5):19-24.
[33] Хлебников В Н, Губанов В Б, Полищук А М. Использование слим-моделей пласта(slim tubе) для физического моделирования процессов вытеснения нефти смешивающимися агентами. Часть2. Оценка возможности применения стандартного фильтрационного оборудования для осуществления слим-методики[J]. Нефтепромысловое дело, 2014(6):32-38.
[34] FERNø M A, STEINSBø M, ØYVIND Eide, et al. Parametric study of oil recovery during CO₂ injections in fractured chalk:influence of fracture permeability, diffusion length and water saturation[J]. Journal of Natural Gas Science & Engineering, 2015, 27:1063-1073. doi:10.1016/-j.jngse.2015.09.052
[35] ПесоцкаяД В, Федоров М В, КлимовМ Ю, et al. Оценка потенциала утилизации газа путем его закачки в пла с тсцелью повышения коэффициента извлечения нефти[J]. Нефтяное хозяйство, 2013(2):74-77.
[36] 刘玉章,陈兴隆. 低渗油藏CO₂驱油混相条件的探讨[J]. 石油勘探与开发, 2010, 37(4):466470. LIU Yuzhang, CHEN Xinglong. Miscible conditions of CO₂ flooding technology used in low permeability reservoirs[J]. Petroleum Exploration and Development, 2010, 37(4):466-470.
[37] TEKLU T W, ALHARTHY N, KAZEMI H, et al. Phase behavior and minimum miscibility pressure in nanopores[J]. SPE Reservoir Evaluation & Engineering 2014, 17(3):396-403. doi:10.2118/168865-PA
[38] TEKLU T W, ALHARTHY N, KAZEMI H, et al. Vanishing interfacial tension algorithm for MMP determination in unconventional reservoirs[C]. SPE 169517, 2014. doi:10.2118/169517-MS
[39] TEKLU T W, ALHARTHY N, KAZEMI H, et al. Hydrocarbon and non-hydrocarbon gas miscibility with light oil in shale reservoirs[C]. SPE 169123, 2014. doi:10.2118/-169123-MS
[40] TEKLU T W, ALHARTHY N, KAZEMI H, et al. Minimum miscibility pressure in conventional and unconventional reservoirs[C]//Unconventional Resources Technology Conference, 2013:2206-2216. doi:10.1190/-urtec2013-228
[41] NOJABAEI B, SIRIPATRACHAI N, JOHNS R T, et al. Effect of saturation dependent capillary pressure on production in tight rocks and shales:A compositionallyextended black oil formulation[C]. SPE 171028, 2014. doi:10.2118/171028-MS
[42] MA Yixin, AHMAD J. Modeling the effects of porous media in dry gas and liquid rich shale on phase behavior[C]. SPE 169128, 2014. doi:10.2118/169128-MS
[43] PITAKBUNKATE T, BALBUENA P B, MORIDIS G J, et al. Effect of confinement on pressure/volume/temperature properties of hydrocarbons in shale reservoirs[C]. SPE 170685, 2015. doi:10.2118/170685-MS
[44] XIONG Yi, WINTERFIELD P H, WU Yushu, et al. Coupled geomechanics and pore confinement effects for modeling unconventional shale reservoirs[C]. SPE 1923960, 2014. doi:10.2118/1923960-MS
[45] XIONG Yi, WINTERFIELD P H, WANG Cong, et al. Effect of large capillary pressure on fluid flow and transport in stress-sensitive tight oil reservoirs[C]. SPE 175074, 2015. doi:10.2118/175074-MS
[46] DIDAR B R, AKKUTLU I Y. Confinement effects on hydrocarbon mixture phase behavior in organic nanopore[C]//Unconventional Resources Technology Conference, 2015. doi:10.15530/urtec-2015-2151854
[47] ZHANG K, GONZALEZ P M E, KONG B, et al. CO₂ near-miscible flooding for tight oil exploitation[C]. SPE 176826, 2015. doi:10.2118/176826-MS
[48] PARSA E, YIN X, OZKAN E. Direct observation of the impact of nanopore confinement on petroleum gas condensation[C]. SPE 175118, 2015. doi:10.2118/175118-MS
[49] ALHARTHY N S, NGUYEN T, TEKLU T, et al. Multiphase compositional modeling in small-scale pores of unconventional shale reservoirs[C]. SPE 166306, 2013. doi:10.2118/166306-MS
[50] JIN L, PU H, WANG Y, et al. The consideration of pore size distribution in organic-rich unconventional formations may increase oil production and reserve by 25%, eagle ford case study[C]//Unconventional Resources Technology Conference, 2015. doi:10.15530/urtec-2015-2148314
[51] FIRINCIOGLU T, OZGEN C, OZKAN E. An excessbubble-point-suppression correlation for black oil simulation of nano-porous unconventional oil reservoirs[C]. SPE 166459, 2013. doi:10.2118/166459-MS
[52] KHOSHGHADAM M, KHANAL A, MAKINDE I, et al. Numerical study of production mechanisms in unconventional liquid-rich shale volatile oil reservoirs[C]. SPE 175994, 2015. doi:10.2118/175994-MS
[53] SHEDID S A. Influences of different modes of reservoir heterogeneity on performance and oil recovery of carbon dioxide miscible flooding[J]. Journal of Canadian Petroleum Technology, 2009, 48(2):29-36. doi:10.2118/09-02-29
[54] YARBOROUGH L, SMITH L R. Solvent and driving gas compositions for miscible slug displacement[J]. Society of Petroleum Engineers Journal, 1970, 10(3):298-310. doi:10.2118/2543-PA
[55] YELLIG W F, METCALFE R S. Determination and prediction of CO₂ minimum miscibility pressures (includes associated paper 8876)[J]. Journal of Petroleum Technology, 1980, 32(1):160-168. doi:10.2118/7477-PA
[56] KECHUT N I, ZAHIDAH M Z, NORAINI A, et al. New experimental approaches in minimum miscibility pressure (mmp) determination[C]. SPE 57286, 1999. doi:10.2118/-57286-MS
[57] ADYANI W N, WAN Daud W A, DARMAN N B, et al. A systematic approach to evaluate asphaltene precipita-tion during CO₂ injection[C]. SPE 143903, 2011. doi:10.-2118/143903-MS
[58] JAVADPOUR F, FISHER D. Nanotechnology-based micromodels and new image analysis to study transport in porous media[J]. Journal of Canadian Petroleum Technology, 2008, 47(2):30-37. doi:10.2118/08-02-30
[59] WAN N A, KECHUT N I. Advanced technology for rapid minimum miscibility pressure determination (Part 1)[C]. Indonesia:Asia Pacific Oil and Gas Conference and Exhibition. Jakarta, Society of Petroleum Engineer, 2007. doi:10.2118/110265-MS
[60] 李实,秦积舜,陈兴隆,等. 多管式最小混相压力测量方法及装置:中国, CN102798499 B[P].20141126.
[61] 陈兴隆,李实,秦积舜,等. 多管式最小混相压力测量装置:中国, CN202916038U[P].20130501.
[62] ABIODUN M A, SHAMEEM S, MENOUAR H. A new look at the minimum miscibility pressure (mmp) determination from slimtube measurements[C]. SPE 153383, 2012. doi:10.2118/153383-MS
[63] ZHANG K, GU Y. Two different technical criteria for determining the minimum miscibility pressures (MMPs) from the slim-tube and coreflood tests[J]. Fuel, 2015, 161:146-156. doi:10.1016/j.fuel.2015.08.039
[64] RICHARD L C, HIEMI K. Apparatus and method for determining the minimum miscibility pressure of a gas in a liquid US, US 4627273 A[P].1986-12-09.
[65] RAO D N. A new technique of vanishing interfacial tension for miscibility determination[J]. Fluid Phase Equilibria, 1997, 139(1):311-324. doi:10.1016/S0378-3812(97)00180-5
[66] AYIRALA S C, RAO D N. Comparative evaluation of a new gas/oil miscibility-determination technique[J]. Journal of Canadian Petroleum Technology, 2011, 50(9):71-81. doi:10.2118/99606-PA
[67] 黄春霞,汤瑞佳,余华贵,等. 高压悬滴法测定CO₂原油最小混相压力[J]. 岩性油气藏, 2015, 27(1):127130. doi:10.3969/j.issn.1673-8926.2015.01.019 HUANG Chunxia, TANG Ruijia, YU Huagui, et al. Determination of the minimum miscibility pressure of CO₂ and crude oil system by hanging drop method[J]. Lithologic Reservoirs, 2015, 27(1):127-130. doi:10.3969/j.-issn.1673-8926.2015.01.019
[68] 彭宝仔,罗虎,陈光进,等. 用界面张力法测定CO₂与原油的最小混相压力[J]. 石油学报, 2007, 28(3):9395. doi:10.7623/syxb200703018 PENG Baozi, LUO Hu, CHEN Guangjin, et al. Determination of the minimum miscibility pressure of CO₂ and crude oil system by vanishing interfacial tension method[J]. Acta Petrolei Sinica, 2007, 28(3):93-95. doi:10.-7623/syxb200703018
[69] ZOLGHADR A, ESCROCHI M, AYATOLLAHI S. Temperature and composition effect on CO₂ miscibility by interfacial tension measurement[J]. Journal of Chemical & Engineering Data, 2013, 58(5):1168-1175. doi:10.1021/-je301283e
[70] GU Y, HOU P, LUO W. Effects of four important factors on the measured minimum miscibility pressure and first-contact miscibility pressure[J]. Journal of Chemical & Engineering Data, 2013, 58(5):1361-1370. doi:10.-1021/je4001137
[71] NOBAKHT M, MOGHADAM S, GU Y. Determination of CO₂ minimum miscibility pressure from measured and predicted equilibrium interfacial tensions[J]. Industrial & Engineering Chemistry Research, 2008, 47(22):8918-8925. doi:10.1021/ie800358g
[72] SHANG Q, XIA S, SHEN M, et al. Experiment and correlations for CO₂-oil minimum miscibility pressure in pure and impure CO₂ streams[J]. Rsc Advances, 2014, 4(109):63824-63830. doi:10.1039/C4RA11471J
[73] DALVAND K, HEYDARIAN A. Determination of gasoil interfacial tension[J]. Energy Sources Part A Recovery Utilization & Environmental Effects, 2015, 37(16):1790-1796. doi:10.1080/15567036.2011.648305
[74] DAYANAND S, DANDINA N R. Experimental determination of minimum miscibility pressure (mmp) by gas/oil ift measurements for a gas injection EOR project[C]. SPE 132389, 2010. doi:10.2118/132389-MS
[75] GHORBANI M, MOMENI A, SAFAVI S, et al. Modified vanishing interfacial tension (VIT) test for CO₂-oil minimum miscibility pressure (MMP) measurement[J]. Journal of Natural Gas Science & Engineering, 2014, 20(2):92-98.
[76] JR F M O, JESSEN K. An analysis of the vanishing interfacial tension technique for determination of minimum miscibility pressure[J]. Fluid Phase Equilibria, 2007, 255(2):99-109. doi:10.1016/j.jngse.2014.06.006
[77] RAO D N, LEE J I. Application of the new vanishing interfacial tension technique to evaluate miscibility conditions for the Terra Nova Offshore Project[J]. Journal of Petroleum Science & Engineering, 2002, 35(3-4):247-262. doi:10.1016/S0920-4105(02)00246-2
[78] JEANNOËL J, LAURENT A, PIERRE C. Is it still necessary to measure the minimum miscibility pressure?[J]. Industrial & Engineering Chemistry Research, 2002, 41(2):303-310. doi:10.1021/ie010485f
[79] HARMON R A, GRIGG R B. Vapor-density measurement for estimating minimum miscibility pressure (includes associated papers 19118 and 19500)[J]. SPE Reservoir Engineering, 1988, 3(4):1215-1220. doi:10.2118/15403-PA
[80] ABDURRAHMAN M, PERMADI A K, BAE W S. An improved method for estimating minimum miscibility pressure through condensation-extraction process under swelling tests[J]. Journal of Petroleum Science & Engineering, 2015, 131:165-171. doi:10.1016/j.petrol.2015.-04.033
[81] ABEDINI A, MOSAVAT N, TORABI F. Determination of minimum miscibility pressure of crude oil-CO₂, system by oil swelling/extraction test[J]. Energy Technology, 2014, 2(5):431-439. doi:10.1002/ente.201400005
[82] MOUDI F Al-Ajmi, OSAMAH A A, MOHAMED A E. Planning miscibility tests and gas injection projects for four major kuwaiti reservoirs[C]. Kuwait:Kuwait International Petroleum Conference and Exhibition. Society of Petroleum Engineer, 2009. doi:10.2118/127537-MS
[83] 赵金省,刘笑春,杨棠英,等. 一种测定CO₂驱最小混相压力的实验方法[J]. 科技导报,2013,31(15):5658. doi:10.3981/j.issn.1000-7857.2013.15.009 ZHAO Jinsheng, LIU Xiaochun, YANG Tangying, et al. A new method for predicting the CO₂ flooding minimum miscibility pressure[J]. Science & Technology Review, 2013, 31(15):56-58. doi:10.3981/j.issn.1000-7857.2013.15.009
[84] NGUYEN P, MOHADDES D, RIORDON J, et al. Fast fluorescence-based microfluidic method for measuring minimum miscibility pressure of CO₂ in crude oils[J]. Analytical Chemistry, 2015, 87(6):3160-3164. doi:10.-1021/ac5047856
[85] 刘瑜,汤凌越,宋永臣,等. 一种应用CT测量油气最小混相压力的装置与方法:中国, CN103900755 A[P].20140702.
[86] LIU Y, JIANG L, SONG Y, et al. Estimation of minimum miscibility pressure (MMP) of CO₂ and liquid n-alkane systems using an improved MRI technique[J]. Magnetic Resonance Imaging, 2015, 34(2):97-104. doi:10.1016/j.-mri.2015.10.035
[87] HAWTHORNE S B, MILLER D J. Determining minimum miscibility pressure of an oil compositon with a fluid:US, US20150060057A1[P].2015-03-05.
[88] MICHEL R. Method and device for measuring the minimum miscibility pressure of two phases:US, US7779672B2[P].2010-08-24.