西南石油大学学报(自然科学版) ›› 2008, Vol. 30 ›› Issue (5): 133-136.DOI: 10.3863/j.issn.1000-2634.2008.05.031

• 油气化学工程与化工 • 上一篇    下一篇

高矿化度产出水集输中的阻垢实验研究

李洪建1 李振志2 陈宗林2 杨进京2 李光伟3   

  1. 1.“油气藏地质及开发工程”国家重点实验室•西南石油大学,四川成都610500;2.中原油田分公司第一采油厂,河南濮阳457100;3.河南油田第一采油厂,河南桐柏474700
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2008-10-20 发布日期:2008-10-20

SCALE PREVENTION EXPERIMENT RESEARCH IN GATHERING ABOUT HIGHLY MINERALIZED PRODUCTION WATER

LI Hong-jian1 LI ZHEN-zhi2 CHEN Zong-lin2 YANG Jin-jing2 LI Guang-wei3   

  1. 1.The State Key Lab of Oil and Gas Reservoir Geology and Exploitation·Southwest Petroleum University,Chengdu Sichuan 610500,China; 2.The NO.1 Oil Production Plant of Zhongyuan Oilfield,Puyang Henan 457100,China; 3.The NO.1 Oil Production Plant of Henan Oilfield,Tongbai Henan 474700,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2008-10-20 Published:2008-10-20

摘要:

中原油田采油一厂九区42#站产出水矿化度高,文侧215-5井产出水中SO42-和HCO3- 含量分别为1734mg/L与2343mg/L;文215-10井产出水中Ca2+含量为12600mg/L;文215-2和文215-4井产出水离子成份复杂。预测结果和配伍性实验表明,此井站产出水混配有无机垢产生,由X衍射分析该沉淀大部分为硫酸钙水合物,这是因为混合体系中Ca2+

和SO42-离子浓度高,CaSO4 过饱和所致。通过静态阻垢实验优选出适合此井站的阻垢剂CD-1,在pH为5~7时阻垢剂的阻垢效果最佳。当阻垢剂CD-1加量为200mg/L、助剂加

量为0.5‰时阻垢率达97.2%,并且不会产生乳化现象,动态实验表明在此加量下阻垢率均在95%以上;现场应用表明,4口井产出液和N13-323等10口井产出液集输都没有垢产生,有效解决

了现场结垢问题。

关键词: 中原油田, 阻垢, 集输系统, 无机垢, 高矿化度

Abstract: The total salinity of produced water of station 42# of the ninth area in the 1st oil production factory in Zhongyuan oil field is high.The contents of SO42- and HCO3- of produced water of Wence well 215-5 are 1734mg/L and 2343mg/L respectively,the content of Ca2+ of Wen well 215-10 produced water of Wen well 215-10 is 12600mg/L; the contents of ions of Wen well 215-2 and Wence well 215-4 are complicated.The results of prediction and compatible experiment indicate that produced water from the station is mixed,it will format inorganic scales.The most component is CaSO4 hydrate by Xdiffraction analysis,as the result of the high content Ca2+ and SO42-in the mixed system and supersaturation CaSO4.The inhibitor CD-1 is optimized according to static state experiment which is suitable to the produced water from the station,and the scale inhibition effectiveness is good at pH 5~7.The inhibition rate is 97.2%,when the inhibitor CD-1 and adjuvant is at 200mg/L and 0.5‰ respectively,and it is not emulsified.The dynamic experiment shows that the inhibition rate is above 95% at the amount of inhibitor;field application shows that there is not format inorganic scale when produced water of 4 wells and 10 wells are gathered,which effectively solves the scaling problem at working sites.

Key words: Zhongyuan Oilfield, scale inhibition, gathering system, inorganic scale, highly total salinity

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