西南石油大学学报(自然科学版) ›› 2012, Vol. 34 ›› Issue (3): 150-156.

• 油气化学工程与化工 • 上一篇    下一篇

聚胺与氯化钾抑制性的对比实验研究

钟汉毅1,黄维安1,邱正松1,黄达全2,王富伟1   

  1. 1. 中国石油大学(华东)石油工程学院,山东东营2570612. 渤海钻探工程有限公司泥浆技术服务分公司,天津大港300280
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2012-06-01 发布日期:2012-06-01

Experimental Study of the Shale Inhibition Between Polyamine andPotassium Chloride

Zhong Hanyi1, Huang Weian1, Qiu Zhengsong1, Huang Daquan2, Wang Fuwei1   

  1. 1. College of Petroleum Engineering,China University of Petroleumm,Dongying,Shandong 257061,China2. Drilling Fluid Service of Bohai Drilling and Exploration Engineering Company Ltd.,Dagang,Tianjin 300280,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2012-06-01 Published:2012-06-01

摘要: 近年来开发出的聚胺水基钻井液,被认为是最接近逆乳化钻井液性能的高性能水基钻井液。新型聚胺强页岩
抑制剂也因其分子结构独特、抑制性能突出越来越受到人们重视。通过抑制膨润土造浆实验、屈曲硬度实验、页岩滚
动分散实验、耐崩散实验、页岩膨胀实验以及X 射线衍射粘土层间距分析等实验手段,对比评价了聚胺强页岩抑制剂
与传统常用抑制剂氯化钾的抑制性。结果表明,与氯化钾相比,聚胺抑制性能优异,能有效抑制粘土水化分散,在加量
较少时即能发挥长期抑制作用,且具有较好的抗温性能。配伍性实验表明,聚胺与膨润土及常用处理剂具有较好的配
伍性。以SDA 为主要水化抑制剂构建了聚胺水基钻井液,实验评价表明,该体系具有优良的抗盐、抗钙和抗劣土污染
性能。此外,对聚胺的抑制机理进行了探讨分析。

关键词: 聚胺, 氯化钾, 抑制性, 粘土水化, 井壁稳定

Abstract: Polyamine water-based drilling fluid is considered to be of high performance and most close to the properties
of water-based invert emulsion mud developed in recent years. Because of the unique molecular structure and outstanding
inhibition,the new polyamine shale inhibitor has been showing more and more attention. The inhibitive properties between
polyamine and potassium chloride are evaluated by bentonite inhibition test,buckle hardness test,shale hot-rolling dispersion
test,slake durability test,shale linear swelling test and the interlayer spacing measurement and so on. The results indicate that,
compared to potassium chloride,polyamine can suppress clay hydration and dispersion with low concentration but long effect.
Also polyamine exhibits high temperature resistance. Compatibility tests indicate that polyamine is compatible with bentonite
and common additives. Based on SDA,polyamine water-based drilling fluid is developed. The experiments demonstrate that
the system shows high performance of anti-salt,anti-calcium and anti-cuttings pollution.

Key words: polyamine, potassium chloride, inhibition, clay hydration, wellbore stability

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