西南石油大学学报(自然科学版) ›› 2012, Vol. 34 ›› Issue (6): 136-140.

• 油气化学工程与化工 • 上一篇    下一篇

高效自组装超分子驱油体系研究

徐亮1,程玉桥2   

  1. 1. 中国石化胜利油田分公司纯梁采油厂,山东博兴2565042. 中国石化胜利油田分公司地质科学研究院,山东东营257001
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2012-12-01 发布日期:2012-12-01

Study on Efficient Self-assembly Supramolecular Oil Displacement System

Xu Liang1, Chen Yuqiao2   

  1. 1. Chunliang Oil Production Factory of Sinopec Shengli Oilfield Branch,Boxing,Shandong 256504,China2. Geological Science Research Institute,Sinopec Shengli Oilfield Branch Company,Dongying,Shandong 257001,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2012-12-01 Published:2012-12-01

摘要: 胜利油田化学驱优质资源一、二类油藏储量基本动用完毕,以高温高盐油藏为主的三类储量(油藏温度>85 ℃,矿化度> 30 000 mg/L)将是今后三次采油的主阵地,但在高温高盐油藏实施聚合物驱油的过程中遇到诸如聚合物遇盐降黏、高温水解、高温降解等问题,严重影响了聚合物驱油技术的应用。超分子体系是一种小分子通过分子间的作用力进行自组装的一个分子聚集体系,以超分子工程学及超分子化学理论为基础,通过设计合成三种高效超分子产品及驱油体系,并对合成的超分子体系进行驱油性能评价,实验表明RTS 型超分子体系增黏效果显著、具有良好的耐温抗盐性、对污水有良好的适应性,并且具有优良的老化稳定性,室内物模实验表明具有良好的提高采收率效果,应用前景良好。

关键词: 三次采油, 聚合物驱, 超分子, 耐温抗盐, 污水适应性

Abstract: High quality chemical flooding resources of type I and II reservoir reserves have nearly run out in Shengli Oilfiled.
Type III reserves with high temperature and high salt reservoirs(reservoir temperature > 85 ℃,salinity > 30 000 mg/L)will
be in the main position in the tertiary oil recovery in the future. But in the implementation of polymer flooding process in
high temperature and high salt reservoir meets such problem as viscosity reduction after polymer comes across salt,high temperature
hydrolysis,and high temperature degradation,which has a serious impact on polymer flooding technology application.
Supramolecular system is a molecular gather system where a small molecules make self-assembly through the intermolecular
force. With super molecular engineering and supramolecular chemistry theory as the foundation,and by synthetizing three
kinds of efficient supramolecular products and oil displacement system,are make evaluation of oil displacement performance
of the synthesis of supramolecular system. Experiments show that RTS type supramolecular system viscosifying action effect
is remarkable,with good heat and salt resistance,and a good adaptability to sewage,and excellent ageing stability. Indoor
physical model experiments show that it is quite effective in improving oil recovery,and has good application prospect.

Key words: tertiary oil recovery, polymer flooding, Supramolecular, heat resistance and salt resistance, sewage adaptability