SELENIUM CATALYZED CARBONYLATION TO CARBONIC ACID DERIVATIVES

doi:10.3863/j.issn.1000-2634.2000.01.019

西南石油大学学报(自然科学版) ›› 2000, Vol. 22 ›› Issue (1): 70-73.DOI: 10.3863/j.issn.1000-2634.2000.01.019

• 油气化学工程 • Previous Articles Next Articles

SELENIUM CATALYZED CARBONYLATION TO CARBONIC ACID DERIVATIVES

ZHENG Yan¹JIA Zhaoxia¹ZHANG Shanyan²

Southwest Petroleum Inst

Received:1999-03-23 Revised:1900-01-01 Online:2000-02-20 Published:2000-02-20
Contact: ZHENG Yan

Abstract

Abstract: Carbonic acid derivatives (such as ureas,carbamates and carbonates)have been conveniently synthesized by selenium catalyzed carbonlylation of nitrocompounds,amines, alcohols and phenols under mild conditions. The yields was satisfied and products was easy to be separated. The possible mechanisms were suggested. It was experimentally illustrated that it is help-
ful to the carbonylation reaction in the presence of a little water and the activator such as amines.

Key words: Carbonylation, Catalyst, synthetic, mechanism

CLC Number:

O623.66

ZHENG Yan JIA Zhaoxia ZHANG Shanyan. SELENIUM CATALYZED CARBONYLATION TO CARBONIC ACID DERIVATIVES[J]. 西南石油大学学报(自然科学版), 2000, 22(1): 70-73.

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SELENIUM CATALYZED CARBONYLATION TO CARBONIC ACID DERIVATIVES

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