西南石油大学学报(自然科学版) ›› 2006, Vol. 28 ›› Issue (1): 52-55.DOI: 10.3863/j.issn.1000-2634.2006.01.015

• 油气化学工程与化工 • Previous Articles     Next Articles

THE DETERMINATION OF WATER CONTENT AND BOUND WATER TYPE ON HYDRO-CLAY SURFACE BY THERMAL-WEIGHTLESSNESS

WANG Ping-quan1 CHEN Di-kui2.

  

  1. ( Southwest Petroleum Institute,Chengdu Sichuan 610500, China)
  • Received:2005-01-18 Revised:1900-01-01 Online:2006-02-20 Published:2006-02-20
  • Contact: WANG Ping-quan

Abstract:

Thermal-weightlessness is utilized to determine the type boundary line and relative content of bound water on montmoril-lonite and the results of isothermal adsorption have been tom-pared. The results show that each water relative content and total water mass on hydro-montmorillonite场the method are incon-sistent to them by isothermal adsorption. Thermal weight loss a-nalysis ( 25~250`0)results show that water on hydro-mont-morillonite is free water, loose bound water and sirong bound water which respectively corresponding to the water loss in 25-75oC,75~120oC,and 120~230oC.According to thermal-weightlessness regularity(25~250oC),it also has two clear turning points which are plp。p/ps=0.9~0.98,the two turning points are the-special humidity of clay一water system. The rela-
five vapor pressure 0. 9 is the boundary line between the strong bound water and the loge bound water(osmotic bound water ) on clays, the relative vapor pressure 0. 98 is the boundary line between the loge bound water and free water on clays. The method verifies the "two special humidity" by isothermal adso p-lion and the boundary line of bound water on clays.

Key words: hydro clay, thermal weightlessness, bound water, relative content, special

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