The Study of Effect of Inhibitors on BaSO4 Crystallization Kinetic Parameters

doi:10.11885/j.issn.1674-5086.2022.01.05.03

Abstract

Abstract: Taking the process of barium sulfate crystal as the research object, induction period, Gibbs free energy and activation energy of barium sulfate solution with and without odium diethylene triamine pentacetate (DTPA-5Na), ethylene diamine tetra methylene phosphonate (EDTMPS) and diethylene triamine penta (DTPMP) were analyzed based on the homogeneous theory. The impact of inhibitor on the morphology and characteristic peak also were studied by SEM and XRD respectively. It was found that the induction period and activation energy increased, Gibbs free energy of barium sulfate also increased by 10.52, 8.06, 6.18 mJ/m² respectively at the temperature from 298 K to 318 K and concentration of Ba²⁺ and SO₄^2- from 0.5～1.2 mmol/L. Meanwhile, morphology of BaSO₄ crystals were changed significantly and crystalline grain was smaller and more dispersed. Characteristic peak of some surface of BaSO₄ became weaker. DTPA–5Na, EDTMPS and DTPMP prevented barium sulfate from growing at different levels.

Key words: barium sulfate crystal, induction period, Gibbs free energy, inhibitors, crystal morphology and diffracted intensity

CLC Number:

TE39

LI Haitao, LI Ran, LIU Tao, ZHENG Chao, LIU Wenju. The Study of Effect of Inhibitors on BaSO₄ Crystallization Kinetic Parameters[J]. Journal of Southwest Petroleum University(Science & Technology Edition), 2022, 44(5): 175-184.

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