非水相化学蒸气发生-原子荧光光谱分析技术研究

›› 2018, Vol. 3 ›› Issue (6): 42-47.

非水相化学蒸气发生-原子荧光光谱分析技术研究

（大理大学药学与化学学院，云南大理671000）

收稿日期:2017-11-03 出版日期:2018-06-15 发布日期:2018-06-15
作者简介:温晓东，教授，博士，主要从事分析化学专业光谱分析研究.
基金资助:
国家自然科学基金资助项目（21465001）

An Investigation of Non-aqueous Phase Chemical Vapor Generation-Atomic Fluorescence Spectrometry
Technology

（College of Pharmacy and Chemistry, Dali University, Dali, Yunnan 671000, China）

Received:2017-11-03 Online:2018-06-15 Published:2018-06-15

摘要/Abstract

摘要：

目的：创新性地开展非水相（non-aqueous phase）化学蒸气发生（CVG）在原子荧光光谱分析（AFS）中的应用研究。方
法：研究适用于该体系的元素种类、非水相介质种类并优化实验条件，建立分析性能指标体系。结果：目前已成功实现了汞
（Hg）、砷（As）、锑（Sb）、铋（Bi）、镉（Cd）、锡（Sn）、碲（Te）7种元素通过不同的萃取方法将其由水相转移到非水相介质并在非水
相CVG-AFS体系中的分析测定，且大部分元素分析性能良好。结论：非水相CVG-AFS技术具有较好的可行性和分析性能，该
研究工作为后期非水相CVG技术应用于其他仪器分析方法提供了很好的研究基础。

关键词: 非水相化学蒸气发生, 原子荧光光谱分析, 元素分析

Abstract:

Objective: The paper is to innovatively investitgate the application of non-aqueous phase chemical vapor generation
（CVG）in atomic fluorescence spectrometry（AFS）. Methods: The types of elements and non-aqueous media suitable for the system
were studied, and the experimental conditions were optimized, and the analytical performance index system was established. Results:
Seven elements including mercury（Hg）, arsenic（As）, antimony（Sb）, bismuth（Bi）, cadmium（Cd）, stannum（Sn）and tellurium
（Te）had been successfully determined in non-aqueous phase CVG-AFS system after transferring from solution to non-aqueous phase
medium via different extraction methods, with good analytical performance for large part of the elements. Conclusion: Non-aqueous
phase CVG-AFS technology has good feasibility and analytical performance. This work provides a good basis for the later application
of non-aqueous phase CVG technology in other instrumental analysis methods.

Key words: non-aqueous phase chemical vapor generation, atomic fluorescence spectrometry, elemental analysis

中图分类号:

O657.3

温晓东，雷自荣，陈路琼，胡侃. 非水相化学蒸气发生-原子荧光光谱分析技术研究[J]. , 2018, 3(6): 42-47.

Wen Xiaodong, Lei Zirong, Chen Luqiong, Hu Kan. An Investigation of Non-aqueous Phase Chemical Vapor Generation-Atomic Fluorescence Spectrometry
Technology[J]. , 2018, 3(6): 42-47.

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