Investigation on the Enhancement Effect of Several Surfactants in the
Spectrophotometric Determination of Tin

Abstract

Abstract:

Objective: To study the enhancement effect of several surfactants in the spectrophotometric determination of trace tin and
effect on tin（Ⅱ）-benzfluorenone complex. Methods: Under the optimum experimental conditions, the analytical performance of the
method was investigated. Results: The detection limits（LODs）of tween-80, Triton X-114, Triton X-100 and tween-20 were 0.018,
0.021, 0.024 and 0.027 μg/mL. The sensitivity was improved about 2 times. Conclusion: The surfactants improved the sensitivity of
the method. The analysis method was more environmentally friendly.

Key words: spectrophotometry, surfactant, enhancement effect, tin, benzfluorenone

CLC Number:

O657

Chen Luqiong, Zhong Lijiang, Lei Zirong, Wen Xiaodong. Investigation on the Enhancement Effect of Several Surfactants in the
Spectrophotometric Determination of Tin[J]. , 2016, 1(12): 36-39.

References

〔1〕马卫兴，周亚文，仇香，等. 苯芴酮-吐温-20体系分光光
度测定聚烯烃树脂中的铁〔J〕. 淮海工学院学报，2008，
17（1）：49-51.
〔2〕李合庆. 原子荧光光谱法测定锌及锌合金中锡量的研
究〔J〕. 有色矿冶，2013，29（2）：50-53.
〔3〕冯治芬，卢志刚. 苯芴酮直接光度法测定锌及合金中锡
量〔J〕. 兵器材料科学与工程，1993，16（1）：66-68.
〔4〕杨丽君，王小静，康译友，等. 氢化物发生-原子荧光光谱
法测定血液透析用水中锡〔J〕. 微量元素与健康研究，
2016，33（1）：72-74.
〔5〕胡翼淇. 流动注射-氢化物发生-原子吸收光谱法测钨制
品粉末及水样中痕量锡〔J〕. 硬质合金，2006，23（2）：
100-102.
〔6〕樊勇，杨再江，杨学新. ICP-OES 测定四氯化钛中的
锡〔J〕. 湖南有色金属，2016，32（1）：75-76.
〔7〕王铁，亢德华，于媛君. 电感耦合等离子体质谱法测定锰
铁中痕量铅锡锑〔J〕. 冶金分析，2013，33（5）：13-16.
〔8〕成勇. ICP-AES法直接测定70钛铁中V，Sn〔J〕. 冶金分
析，2003，23（6）：15-17.
〔9〕全国有色金属标准化技术委员会. GB/T4103.1-2012，铅
及铅合金化学分析方法-锡量的测定〔S〕. 北京：中国标
准出版社，2013.
〔10〕赵国琴，高永清，储成顶，等. 苯芴酮光度法测定聚乳酸
辅料中Sn残留量〔J〕. 安徽医科大学学报，2004，39（1）：
76-78.
〔11〕徐智娟. 苯基萤光酮分光光度法测定细砂岩中的锡
量〔J〕. 广东化工，2016，43（2）：121.
〔12〕赵珍义，于吉，宋金和. 新FIA微分光度法测合金钢中
微量锡〔J〕. 现代科学仪器，2008（5）：52-53.
〔13〕刘文明，马卫兴. 双显色剂协同显色光度法测定锡〔J〕.
光谱学与光谱分析，1999，19（5）：765-767.
〔14〕苏洋，刘红英. 苯芴酮-溴化十六烷基三甲基铵分光光
度法测定钛铁中锡〔J〕. 冶金分析，2015，35（4）：65-67.
〔15〕周林宗，张宗贵. 表面活性剂在分析化学中的应用简
介〔J〕. 楚雄师范学院学报，2002，17（3）：67-70.
〔16〕张文德. Triton-100-苯芴酮分光光度法测定食品中微
量锡〔J〕. 中华预防医学杂志，1989，23（2）：104-105.

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