外加电位对X80钢在满洲里土壤应力腐蚀的影响

doi:10.11885/j.issn.1674-5086.2018.10.12.02

西南石油大学学报(自然科学版) ›› 2019, Vol. 41 ›› Issue (5): 181-188.DOI: 10.11885/j.issn.1674-5086.2018.10.12.02

• 石油机械与油田化学 • 上一篇

外加电位对X80钢在满洲里土壤应力腐蚀的影响

张文建, 祝宗祥, 肖鹏, 陈玉忠, 董帅

河北华北石油工程建设有限公司, 河北任丘 062552

收稿日期:2018-10-12 出版日期:2019-10-10 发布日期:2019-10-10
通讯作者: 张文建,E-mail:978061326@qq.com
作者简介:张文建,1989年生,男,汉族,内蒙古赤峰人,工程师,硕士,主要从事管线钢腐蚀与防护方面研究工作。E-mail:978061326@qq.com;祝宗祥,1970年生,汉族,河北威县人,工程师,主要从事油田地面和炼油化工项目的管理工作。E-mail:zzx1970@qq.com;肖鹏,1974年出生,男,汉族,辽宁开原人,助理工程师,主要从事油田地面和炼油化工项目管理工作。E-mail:gj-2c-xp@cnpc.com.cn;陈玉忠,1973年生,男,汉族,河北东光人,高级工程师,主要从事管线、钢结构工程施工。E-mail:292723760@qq.com;董帅,1980年生,男,汉族,山东掖县人,高级工程师,主要从事工程施工和LNG相关业务研究工作。E-mail:110445835@qq.com
基金资助:
国家自然科学基金（51574147，50771053）；辽宁省教育厅科学研究基金（L2014156）

Influence of Applied Potential on Stress Corrosion Cracking of X80 Steel in Manchurian Soil

ZHANG Wenjian, ZHU Zongxiang, XIAO Peng, CHEN Yuzhong, DONG Shuai

Huabei Petroleum Engineering Construction Co. Ltd., Renqiu, Hebei 062552, China

Received:2018-10-12 Online:2019-10-10 Published:2019-10-10

摘要/Abstract

摘要： 针对埋地管道应力腐蚀开裂（SCC）问题，开展了X80管线钢（X80钢）在满洲里土壤模拟溶液中的SCC研究，以期对X80钢的SCC防护提供数据支撑。采用交流阻抗技术、动电位极化技术和慢应变速率拉伸实验研究了X80钢在不同外加电位下满洲里土壤模拟溶液中的SCC行为，并用扫描电镜观察了断口表面微观形貌。结果表明：自腐蚀电位下，X80钢裂纹萌生于点蚀坑处，SCC机制为阳极溶解（AD）；在外加电位为-850 mV和-930 mV时，X80钢的应力腐蚀受到抑制作用，SCC敏感性较低，-850 mV为最佳阴极保护电位。这两个电位下X80钢SCC机制为AD和氢致开裂（HIC）混合机制，其中-930 mV下SCC机制由HIC占主导地位；在外加电位为-1 000 mV和-1 200 mV时，X80钢表现出较高的SCC敏感性，SCC机制为氢和应力协同作用下的HIC。

关键词: X80钢, 外加电位, 慢应变速率拉伸实验, 应力腐蚀开裂, 土壤环境

Abstract: Stress corrosion cracking (SCC) of X80 pipeline steel (X80 steel) in a simulated Manchurian soil solution was studied, with the aim of providing data to support the design of methods to prevent SCC in X80 steel used for manufacturing buried pipelines. By means of an AC impedance technique, a potentiodynamic polarization technique, and slow strain rate tensile tests, the SCC behavior of X80 steel in simulated Manchurian soil solution was investigated under different applied potentials, and the microscopic morphologies of the fracture surfaces were observed using a scanning electron microscope. The results indicated that the self-corrosion potential led to the initiation of cracks at corrosion pits in X80 steel, with anodic dissolution (AD) being the mechanism underlying SCC. Applied potentials of -850 mV and -930 mV provided inhibitory effects against SCC in X80 steel, and reduced sensitivity to SCC; in particular, -850 mV was determined to be the optimal cathodic protection potential. Under these two potentials, SCC in X80 steel occurred via a combination of AD and hydrogen-induced cracking (HIC), with HIC being the dominant mechanism of SCC under the applied potential of -930 mV. Under applied potentials of -1 000 mV and -1 200 mV, X80 steel exhibited higher sensitivity to SCC, with SCC occurring via HIC through the synergistic effects of hydrogen and stress.

Key words: X80 steel, applied potential, slow strain rate tensile test, stress corrosion cracking, soil environment

中图分类号:

张文建, 祝宗祥, 肖鹏, 陈玉忠, 董帅. 外加电位对X80钢在满洲里土壤应力腐蚀的影响[J]. 西南石油大学学报(自然科学版), 2019, 41(5): 181-188.

ZHANG Wenjian, ZHU Zongxiang, XIAO Peng, CHEN Yuzhong, DONG Shuai. Influence of Applied Potential on Stress Corrosion Cracking of X80 Steel in Manchurian Soil[J]. 西南石油大学学报(自然科学版), 2019, 41(5): 181-188.

0
/ / 推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal15.magtechjournal.com/Jwk_xnzk/CN/10.11885/j.issn.1674-5086.2018.10.12.02

http://journal15.magtechjournal.com/Jwk_xnzk/CN/Y2019/V41/I5/181

参考文献

[1] 杨武. 埋地油气管线应力腐蚀破裂研究的一些新进展[J]. 腐蚀与防护, 2003, 24(11):461-467. doi:10.3969/j.issn.1005-748X.2003.11.001 YANG Wu. Some new advances in research of SCC of buried oil and gas pipelines[J]. Corrosion & Protection, 2003, 24(11):461-467. doi:10.3969/j.issn.1005-748X.-2003.11.001
[2] 方丙炎,韩恩厚,朱自勇,等. 管线钢的应力腐蚀研究现状及损伤机理[J]. 材料导报, 2001, 15(12):1-3, 20. doi:10.3321/j.issn:1005-023X.2001.12.001 FANG Bingyan, HAN Enhou, ZHU Ziyong, et al. Current state of research on stress corrosion cracking in pipeline steels and damage mechanisms[J]. Materials Reports, 2001, 15(12):1-3, 20. doi:10.3321/j.issn:1005-023X.2001.12.001
[3] PARKINS R N, BEAVERS J A. Some effect of strain rate on the transgranular stress corrosion cracking of ferritic steels in dilute near-neutral-pH solution[J]. Corrosion, 2003, 59(3):258-271. doi:10.5006/1.3277559
[4] PARKINS R N. Mechanistic aspects of intergranular stress corrosion cracking of ferric steels[J]. Corrosion, 1996, 52(5):363-374. doi:10.5006/1.3292124
[5] National Energy Board (NEB). Public inquiry concerning stress corrosion cracking on Canada oil and gas pipelines[G]//NEB Report Mh-2-95, Calgary, AB, Canada:1996, 2001, 37(5):453-458.
[6] 方丙炎,王俭秋,朱自勇,等. 埋地管道在近中性pH和高pH环境中的应力腐蚀开裂[J]. 金属学报, 2001, 37(5):453-458. doi:10.3321/j.issn:0412-1961.-2001.05.002 FANG Bingyan, WANG Jianqiu, ZHU Ziyong, et al. The stress corrosion cracking of buried pipelines in nearneutral-pH and high-pH solutions[J]. Acta Metallurgica Sinica, 2001, 37(5):453-458. doi:10.3321/j.issn:0412-1961.2001.05.002
[7] 门长峰,帅建. 输送管道应力腐蚀开裂和氢致开裂[J]. 天然气工业, 2006, 26(11):133-135. doi:10.3321/j.issn:1000-0976.2006.11.041 MEN Changfeng, SHUAI Jian. SCC and HIC in transmission pipelines[J]. Natural Gas Industry, 2006, 26(11):133-135. doi:10.3321/j.issn:1000-0976.2006.11.041
[8] 王茂堂,何莹,王丽,等. 西气东输二线X80级管线钢的开发和应用[J]. 电焊机, 2009, 39(5):6-14. doi:10.3969/j.issn.1001-2303.2009.05.003 WANG Maotang, HE Ying, WANG Li, et al. Development and application of X80 alloy steel pipe for second west to east gas pipeline project[J]. Electric Welding Machine, 2009, 39(5):6-14. doi:10.3969/j.issn.1001-2303.-2009.05.003
[9] 刘智勇,翟国丽,杜翠薇,等. X70钢在鹰潭酸性土壤中的应力腐蚀行为[J]. 四川大学学报(工程科学版), 2008, 40(2):76-81. LIU Zhiyong, ZHAI Guoli, DU Cuiwei, et al. SCC of X70 pipeline steel in Yingtan acid soil environment[J]. Journal of Sichuan University (Engineering Science Edition), 2008, 40(2):76-81.
[10] 程远,俞宏英,王莹,等. 外加电位对X80钢在玉门土壤模拟溶液中应力腐蚀的影响[J]. 材料工程,2014(8):55-60. doi:10.11868/j.issn.1001-4381.2014.08.011 CHENG Yuan, YU Hongying, WANG Ying, et al. Effects of potential on stress corrosion cracking of X80 steel in Yumen simulated soil solution[J]. Journal of Materials Engineering, 2014(8):55-60. doi:10.11868/j.issn.1001-4381.-2014.08.011
[11] CHARLES E A, PARKINS R N. Generation of stress corrosion cracking environment at pipeline surface[J]. Corrosion, 1995, 51(7):518-527. doi:10.5006/1.3294372
[12] PARKINS R N. Predictive approaches to stress corrosion cracking failure[J]. Corrosion Science, 1980, 20(2):147-166. doi:10.1016/0010-938X(80)90128-6
[13] 王炳英,霍立兴,王东坡,等. X80管线钢在近中性pH溶液中的应力腐蚀开裂[J]. 天津大学学报, 2007, 40(6):757-760. doi:10.3969/j.issn.0493-2137.-2007.06.024 WANG Bingying, HUO Lixing, WANG Dongpo, et al. Stress corrosion cracking of X80 pipeline steel in nearneutral pH values solutions[J]. Journal of Tianjin University, 2007, 40(6):757-760. doi:10.3969/j.issn.0493-2137.2007.06.024
[14] LI H L, GAO K W, QIAO L J, et al. Strength effect in stress corrosion cracking of high-strength steel in aqueous solution corrosion[J]. Corrosion, 2001, 57(2):295-299. doi:10.5006/1.3290352
[15] 程远,俞宏英,王莹,等. 应变速率对X80管线钢应力腐蚀的影响[J]. 材料工程, 2013(3):77-82. doi:10.3969/j.issn.1001-4381.2013.03.015 CHENG Yuan, YU Hongying, WANG Ying, et al. Effect of strain rate on stress corrosion cracking of X80 pipeline steel[J]. Journal of Materials Engineering, 2013(3):77-82. doi:10.3969/j.issn.1001-4381.2013.03.015
[16] 谭文志,杜元龙,傅超,等. 阴极保护导致ZC 120钢在海水中环境氢脆[J]. 材料保护, 1988, 21(3):10-13.
[17] 张林,杜敏,刘吉飞,等. 海水中极化电位对X70钢氢脆敏感性的影响[J]. 材料科学与工艺, 2011, 19(5):96-101. ZHANG Lin, DU Min, LIU Jifei, et al. Effect of polarized potentials on the susceptibility to hydrogen embrittlement of X70 steel in seawater[J]. Materials Science & Technology, 2011, 19(5):96-101.
[18] 刘智勇,王长朋,杜翠薇,等. 外加电位对X80管线钢在鹰潭酸性土壤中应力腐蚀行为的影响[J]. 金属学报, 2011, 47(11):1434-1439. doi:10.3724/SP.J.1037.-2011.0004 LIU Zhiyong, WANG Changpeng, DU Cuiwei, et al. Effect of applied potentials on stress corrosion cracking of X80 pipeline steel in simulated Yingtan soil solution[J]. Acta Metallurgica Sinica, 2011, 47(11):1434-1439.
[19] 刘智勇,翟国丽,杜翠薇,等. X70钢在酸性土壤模拟溶液中的应力腐蚀行为[J]. 金属学报, 2008, 44(2):209-214. doi:10.3321/j.issn:0412-1961.2008.02.016 LIU Zhiyong, ZHAI Guoli, DU Cuiwei, et al. Stress corrosion behavior of X70 pipeline steel in simulated solution of acid soil[J]. Acta Metallurgica Sinica, 2008, 44(2):209-214. doi:10.3321/j.issn:0412-1961.2008.02.016
[20] 张亮,李晓刚,杜翠薇,等. 外加电位对X70管线钢在库尔勒土壤模拟溶液中应力腐蚀开裂敏感性的影响[J]. 中国腐蚀与防护学报, 2009, 29(5):353-359. doi:10.3969/j.issn.1005-4537.2009.05.007 ZHANG Liang, LI Xiaogang, DU Cuiwei, et al. Effect of applied potentials on stress corrosion cracking of X70 pipeline steel in simulated Ku' erle soil solution[J]. Journal of Chinese Society for Corrosion and Protection, 2009, 29(5):353-359. doi:10.3969/j.issn.1005-4537.2009.05.-007
[21] YANG Wu, LIU Guangfu, GUO Hao, et al. Effect of environmental factors on stress corrosion cracking of pipeline steels[J]. J Key Engineering Materials, 2005:297-300. doi:10.4028/www.scientific.net/KEM.297-300.939
[22] PARKINS R N. A review of stress corrosion cracking of high pressure gas pipelines[J]. Corrosion, 2000:363-372.
[23] 陈旭,吴明,何川,等. 外加电位对X80钢及其焊缝在库尔勒土壤模拟溶液中SCC行为的影响[J]. 金属学报, 2010, 46(8):951-958. doi:10.3724/SP.J.1037.-2010.00102 CHEN Xu, WU Ming, HE Chuan, et al. Effect of applied potential on SCC of X80 pipeline steel and its weld joint in Ku'erle simulated solution[J]. Acta Metallurgica Sinica, 2010, 46(8):951-958. doi:10.3724/SP.J.1037.2010.00102
[24] VAN-BOVEN G, CHEN W, ROGGE R. The role of residual stress in neutral pH stress corrosion cracking of pipeline steels. Part I:Pitting and cracking occurrence[J]. Acta Master, 2007, 55(26):29-42. doi:10.1016/j.actamat.2006.08.037
[25] CHU R, CHEN W, WANG S H, et al. Microstructure dependence of stress corrosion cracking initiation in X65 pipeline steel exposed to a near-neutral pH soil environment[J]. Corrosion, 2004, 60(3):274-283. doi:10.5006/1.3287732
[26] 陈旭,何川,刘硕,等. 应力对X70钢在溶液中腐蚀行为的影响[J]. 石油化工高等学校学报, 2011, 24(5):69-72. doi:10.3969/j.issn.1006-396X.2011.05.018 CHEN Xu, HE Chuan, LIU Shuo, et al. Effect of stress on corrosion behavior of X70 steel in solution[J]. Journal of Petrochemical Universities, 2011, 24(5):69-72. doi:10.3969/j.issn.1006-396X.2011.05.018
[27] 王炳英,霍立兴,张玉凤,等. CO₃^2-HCO₃^-溶液中X80管线钢焊接接头的应力腐蚀开裂分析[J]. 焊接学报, 2007, 28(7):85-88. doi:10.3321/j.issn:0253-360X.2007.07.022 WANG Bingying, HUO Lixing, ZHANG Yufeng, et al. CO₃^2-HCO₃^- stress corrosion test of welded joint of X80 pipiline steel[J]. Transactions of the China Welding Institution, 2007, 28(7):85-88. doi:10.3321/j.issn:0253-360X.2007.07.022

外加电位对X80钢在满洲里土壤应力腐蚀的影响

Influence of Applied Potential on Stress Corrosion Cracking of X80 Steel in Manchurian Soil

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

[1]	练章华, 张琎, 王裕海, 张强, 刘永刚. 非等厚度四点弯曲试样环向应力理论研究[J]. 西南石油大学学报(自然科学版), 2020, 42(1): 161-169.
[2]	练章华, 梁建坤, 王裕海, 张强, 牟易升. C型环环向应力与加载载荷的公式推导与验证[J]. 西南石油大学学报(自然科学版), 2019, 41(5): 161-168.