含水稠油在纳米-微波协同下的降黏实验研究

doi:10.11885/j.issn.1674-5086.2019.07.12.01

西南石油大学学报(自然科学版) ›› 2020, Vol. 42 ›› Issue (5): 179-186.DOI: 10.11885/j.issn.1674-5086.2019.07.12.01

• 石油机械与油田化学 • 上一篇

含水稠油在纳米-微波协同下的降黏实验研究

李汉勇¹, 高航², 秦守强¹, 王业骢¹

1. 北京石油化工学院深水油气管线关键技术与装备北京市重点实验室, 北京大兴 102617;
2. 中国石油大学(北京)机械与储运学院, 北京昌平 102249

收稿日期:2019-07-12 出版日期:2020-10-10 发布日期:2020-10-10
通讯作者: 李汉勇,E-mail:lihanyong@bipt.edu.cn
作者简介:李汉勇,1975年生,女,汉族,河南洛阳人,副教授,博士,主要从事油气长距离管输方面的研究工作。E-mail:lihanyong@bipt.edu.cn;高航,1993年生,女,汉族,黑龙江伊春人,硕士,主要从事稠油降黏方面的研究工作。E-mail:523182850@qq.com;秦守强,1999年生,男,汉族,河南辉县人,主要从事稠油降黏方面的研究工作。E-mail:377526076@qq.com;王业骢,2000年生,男,汉族,河北定州人,主要从事稠油降黏方面的研究工作。E-mail:wyc0108@163.com
基金资助:
国家自然科学基金面上项目（51774046）；北京市高水平创新团队建设计划项目（IDHT20170507）；北京市级大学生创新训练项目（2020J00003）

An Experimental Study on Viscosity Reduction of Water-cut Heavy Oil Under the Synergistic Action of Nano Catalyst and Microwave

LI Hanyong¹, GAO Hang², QIN Shouqiang¹, WANG Yecong¹

1. Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing Institute of Petrochemical Technology, Daxing, Beijing 102617, China;
2. College of Mechanical and Transportation Engineering, China University of Petroleum(Beijing), Changping, Beijing 102249, China

Received:2019-07-12 Online:2020-10-10 Published:2020-10-10

摘要/Abstract

摘要： 为降低含水稠油黏度，提高其输送能力，提出了纳米催化剂和微波协同作用的降黏方式。通过响应面实验设计方法，以微波加热功率、加热温度和纳米催化剂浓度为影响因素进行研究，测量得到不同情况下的黏温曲线，通过测得的黏度计算降黏率。通过优化得到不同含水率下的最优降黏处理方法，探究油包水型稠油乳状液在不同含水率下3种因素间的相互作用以及含水率变化对纳米微波协同降黏效果的影响。实验结果表明，在同一含水率下，降黏率随催化剂浓度的增加而增大，随微波功率的增大先增后降，随温度的变化规律与含水率的大小有关。对于不同含水率的稠油，为达到最优降黏效果，随着含水率增大，所需催化剂浓度先增后降，所需的微波功率相近，而温度有一定差别。说明高含水的油包水型乳状液的降黏效果更优，这可为稠油降黏技术提供理论依据。

关键词: 油包水型乳状液, 微波, 纳米催化剂, 降黏, 响应面法

Abstract: Heavy oil has the characteristic of high viscosity, and with the increase of water cut, the viscosity of water-in-oil emulsion will increase further. To reduce the viscosity and improve its transportation capacity, the method of viscosity reduction by synergistic action of nano-catalyst and microwave is proposed. The response surface method is selected as the experimental design method and the influence factors include microwave heat power, temperature and nano-catalyst concentration. The viscosity-temperature curves under different experimental conditions are measured to calculate the viscosity reduction rate, to obtain the optimal viscosity reduction treatment method under different water cuts. The interaction between three factors and the influence of the change of water cut on the synergistic action on viscosity are explored. The experimental result shows that at the same water cut, the viscosity reduction rate increases with the increase of catalyst concentration, and increases first and then decreases with the increase of microwave power, and the variation of viscosity reduction rate with temperature is related to the water cut. In order to achieve the optimal viscosity reduction effect of different water cut, the required catalyst concentration increases first and then decreases. The required microwave power is similar, but the temperature is different. It shows that the viscosity reduction effect of water-in-oil emulsion with high water cut is better, which can provide theoretical basis for heavy oil viscosity reduction technology.

Key words: water-in-oil emulsion, microwave, nano-catalyst, viscosity reduction, response surface method

中图分类号:

TE832

李汉勇, 高航, 秦守强, 王业骢. 含水稠油在纳米-微波协同下的降黏实验研究[J]. 西南石油大学学报(自然科学版), 2020, 42(5): 179-186.

LI Hanyong, GAO Hang, QIN Shouqiang, WANG Yecong. An Experimental Study on Viscosity Reduction of Water-cut Heavy Oil Under the Synergistic Action of Nano Catalyst and Microwave[J]. 西南石油大学学报(自然科学版), 2020, 42(5): 179-186.

0
/ / 推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal15.magtechjournal.com/Jwk_xnzk/CN/10.11885/j.issn.1674-5086.2019.07.12.01

http://journal15.magtechjournal.com/Jwk_xnzk/CN/Y2020/V42/I5/179

参考文献

[1] ABARASI H. A review of technologies for transporting heavy crude oil and bitumen via pipelines[J]. Journal of Petroleum Exploration and Production Technology, 2014, 4(3):327-336. doi:10.1007/s13202-013-0086-6
[2] BERA A, BELHAJ H. Application of nanotechnology by means of nanoparticles and nanodispersions in oil recovery:A comprehensive review[J]. Journal of Natural Gas Science and Engineering, 2016, 34:1284-1309. doi:10.1016/j.jngse.2016.08.023
[3] 杨兆中,朱静怡,李小刚,等. 微波加热技术在非常规油资源中的研究现状与展望[J]. 化工进展,2016,35(11):3478-3483. doi:10.16085/j.issn.1000-6613.2016.11.014 YANG Zhaozhong, ZHU Jingyi, LI Xiaogang, et al. Progress in researches on microwave heating in unconventional oil resources[J]. Chemical Industry and Engineering Progress, 2016, 35(11):3478-3483. doi:10.16085/j.issn.1000-6613.2016.11.014
[4] MUTYALA S, FAIRBRIDGE C, JOCELYN PARÉ J R, et al. Microwave applications to oil sands and petroleum:A review[J]. Fuel Processing Technology, 2010, 91(2):127-135. doi:10.1016/j.fuproc.2009.09.009
[5] PATEL H, SHAH S, AHMED R, et al. Effects of nanoparticles and temperature on heavy oil viscosity[J]. Journal of Petroleum Science and Engineering, 2018, 167:819-828. doi:10.1016/j.petrol.2018.04.069
[6] KHALIL M, LEE R L, LIU Ning, et al. Hematite nanoparticles in aquathermolysis:A desulfurization study of thiophene[J]. Fuel, 2015, 145(2):214-220. doi:10.1016/j.fuel.2014.12.047
[7] 赵法军,刘灏亮,张新宇,等. 稠油水热裂解中的金属纳米粒子催化剂研究进展[J]. 油田化学, 2017, 34(3):567-570. doi:10.19346/j.cnki.1000-4092.2017.03.036 ZHAO Fajun, LIU Haoliang, ZHANG Xinyu, et al. Catalysts of metal nano-particles for aquathermolysis of heavy crude oil[J]. Oilfield Chemistry, 2017, 34(3):567-570. doi:10.19346/j.cnki.1000-4092.2017.03.036
[8] YANG Zhancun, LIU Xueliang, LI Xiaohong, et al. Preparation of silica supported nanoscale zero valence iron and its feasibility in viscosity reduction of heavy oil[J]. Micro & Nano Letters, 2014, 9(5):355-358. doi:10.1049/mnl.2014.0083
[9] 张宏民. 纳米复合材料稠油降粘剂的研制与性能评价[D]. 济南:山东大学, 2015. doi:10.7666/d.Y2792176 ZHANG Hongmin. Study on synthesis and properties of nano-composite viscosity reducer in heavy oil[J]. Ji'nan:Shandong University, 2015. doi:10.7666/d.Y2792176
[10] 汪双清,沈斌,林壬子. 微波作用下稠油粘度变化及其化学因素探讨[J]. 石油实验地质, 2010, 32(6):615-620. doi:10.3969/j.issn.1001-6112.2010.06.019 WANG Shuangqing, SHEN Bin, LIN Renzi. Viscosity and chemical composition changes of heavy oils after microwave processing[J]. Petroleum Geology & Experiment, 2010, 32(6):615-620. doi:10.3969/j.issn.1001-6112.2010.06.019
[11] SHANG Hui, YUE Yude, ZHANG Jie, et al. Effect of microwave irradiation on the viscosity of crude oil:A view at the molecular level[J]. Fuel Processing Technology, 2018, 170:44-52. doi:10.1016/j.fuproc.2017.10.021
[12] LI Kewen, HOU Binchi, WANG Lei, et al. Application of carbon nano catalysts in upgrading heavy crude oil assisted with microwave heating[J]. Nano Letters, 2014, 14(6):3002-3008. doi:10.1021/nl500484d
[13] LI Hanyong, CUI Kexin, JIN Ling, et al. Experimental study on the viscosity reduction of heavy oil with nanocatalyst by microwave heating under low reaction temperature[J]. Journal of Petroleum Science and Engineering, 2018, 170:374-382. doi:10.1016/j.petrol.2018.06.078
[14] 李爱华,王桂兵. 稠油开采新工艺及新技术探讨[J]. 石化技术, 2019, 26(9):112-113. doi:10.3969/j.issn.1006-0235.2019.09.064 LI Aihua, WANG Guibing. Discussion on new technology and new technology of heavy oil exploitation[J]. Petrochemical Industry Technology, 2019, 26(9):112-113. doi:10.3969/j.issn.1006-0235.2019.09.064
[15] 樊泽霞,赵福麟,王杰祥,等. 超稠油供氢水热裂解改质降黏研究[J]. 燃料化学学报, 2006, 34(3):315-318. doi:10.3969/j.issn.0253-2409.2006.03.011 FAN Zexia, ZHAO Fulin, WANG Jiexiang, et al. Upgrading and viscosity reduction of super heavy oil by aquathermolysis with hydrogen donor[J]. Journal of Fuel Chemistry and Technology, 2006, 34(3):315-318. doi:10.3969/j.issn.0253-2409.2006.03.011
[16] FERREIRA S L C, BRUNS R E, FERREIRA H S, et al. Box-behnken design:An alternative for the optimization of analytical methods[J]. Analytica Chimica Acta, 2007, 597(2):179-186. doi:10.1016/j.aca.2007.07.011
[17] 李美蓉,于光松,安波,等. 降黏剂对稠油乳化反相点的影响规律[J]. 油田化学, 2018, 35(3):503-507, 516. doi:10.19346/j.cnki.1000-4092.2018.03.023 LI Meirong, YU Guangsong, AN Bo, et al. Effect of viscosity reducer on emulsification reverse phase point of heavy oil[J]. Oilfield Chemistry, 2018, 35(3):503-507, 516. doi:10.19346/j.cnki.1000-4092.2018.03.023
[18] 黄启玉,张帆,张劲军,等. 原油水乳状液制备条件研究[J]. 油气储运, 2007, 26(6):49-51. doi:10.3969/j.issn.1000-8241-D.2007.06.014 HUANG Qiyu, ZHANG Fan, ZHANG Jinjun, et al. Research on preparation condition of water emulsion for crude oil[J]. Oil and Gas Storage and Transportation, 2007, 26(6):49-51. doi:10.3969/j.issn.1000-8241-D.2007.06.014
[19] 吴梅,张慧,姚闽娜,等. 超声波微波辅助浓硫酸催化油酸制备生物柴油[J]. 中国油脂,2017,42(7):97-100. doi:10.3969/j.issn.1003-7969.2017.07.021 WU Mei, ZHANG Hui, YAO Minna, et al. Ultrasoundmicrowave-assisted preparation of biodiesel from oleic acid using concentrated sulfuric acid as catalyst[J]. China Oils and Fats, 2017, 42(7):97-100. doi:10.3969/j.issn.1003-7969.2017.07.021
[20] 李莉,张赛,何强,等. 响应面法在试验设计与优化中的应用[J]. 实验室研究与探索, 2015, 34(8):41-45. doi:10.3969/j.issn.1006-7167.2015.08.011 LI Li, ZHANG Sai, HE Qiang, et al. Application of response surface methodology in experiment design and optimization[J]. Research and Exploration in Laboratory, 2015, 34(8):41-45. doi:10.3969/j.issn.1006-7167.2015.08.011
[21] NASRI Z, MOZAFARI M. Multivariable statistical analysis and optimization of iranian heavy crude oil upgrading using microwave technology by response surface methodology(RSM)[J]. Journal of Petroleum Science and Engineering, 2018, 161:427-444. doi:10.1016/j.petrol.2017.12.004
[22] PEI Haihua, ZHANG Guicai, GE Jijiang, et al. Investigation of synergy between nanoparticle and surfactant in sta-bilizing oil-in-water emulsions for improved heavy oil recovery[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2015, 484:478-484. doi:10.1016/j.colsurfa.2015.08.025
[23] 戴静君,李益良,张立新,等. 稠油微波降黏效果实验研究[J]. 北京石油化工学院学报, 2013, 21(3):1-3. doi:10.3969/j.issn.1008-2565.2013.03.001 DAI Jingjun, LI Yiliang, ZHANG Lixin, et al. The experiment study of heavy crude oil viscosity reduction effect by microwave[J]. Journal of Beijing Institute of Petrochemical Technology, 2013, 21(3):1-3. doi:10.3969/j.issn.1008-2565.2013.03.001
[24] BINNER E R, ROBINSON J P, SILVESTER S A, et al. Investigation into the mechanisms by which microwave heating enhances separation of water-in-oil emulsions[J]. Fuel, 2014, 116:516-521. doi:10.1016/j.fuel.2013.08.042
[25] AKBARI S, NOUR A H, SAIDATUL S J, et al. Demulsification of water-in-crude oil emulsion via conventional heating and microwave heating technology in their optimum conditions[J]. Australian Journal of Basic and Applied Sciences, 2016, 10(4):66-74.
[26] LI Ning, YAN Bo, XIAO Xianming. A review of laboratory-scale research on upgrading heavy oil in supercritical water[J]. Energies, 2015, 8(8):8962-8989. doi:10.3390/en8088962
[27] GREFF J, BABADAGLI T. Use of nano-metal particles as catalyst under electromagnetic heating for insitu heavy oil recovery[J]. Journal of Petroleum Science and Engineering, 2013, 112:258-265. doi:10.1016/j.petrol.2013.11.012
[28] MUTYALA S, FAIRBRIDGE C, PARÉ J R. Microwave applications to oil sands and petroleum:A review[J]. Fuel Processing Technology, 2010, 91(2):127-135. doi:10.1016/j.fuproc.2009.09.009
[29] SANTOS D, ROCHA E C L, ROBSON L M, et al. Demulsification of water-in-crude oil emulsions using single mode and multimode microwave irradiation[J]. Separation and Purification Technology, 2017, 189:347-356. doi:10.1016/j.seppur.2017.08.028
[30] 崔可心. 纳米催化剂辅助微波加热降粘实验研究[D]. 北京:中国石油大学, 2019. CUI Kexin. Experimental study on viscosity reduction by microwave heating assisted by nano-catalyst[D]. Beijing:China University of Petroleum, 2019.

含水稠油在纳米-微波协同下的降黏实验研究

An Experimental Study on Viscosity Reduction of Water-cut Heavy Oil Under the Synergistic Action of Nano Catalyst and Microwave

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 8

编辑推荐

Metrics

本文评价

[1]	王卫强, 李佳, 王国付, 张晓博. 嗜蜡菌的筛选及其对稠油流变性的影响[J]. 西南石油大学学报(自然科学版), 2017, 39(4): 176-182.
[2]	郭日鑫*. 热自生CO2 吞吐中技术研究及其应用[J]. 西南石油大学学报(自然科学版), 2015, 37(5): 139-144.
[3]	胡书勇1 *，刘学2，黄晶3，王勇4，李建国4. 克拉玛依油田注水井解堵增注技术研究[J]. 西南石油大学学报(自然科学版), 2015, 37(4): 147-151.
[4]	崔盈贤1，2，唐晓东3，李晶晶3，苏旭4，赵文森1，2. 稠油氧化自生表面活性剂乳化降黏实验研究[J]. 西南石油大学学报(自然科学版), 2013, 35(3): 154-159.
[5]	唐钢;薄纯辉;刘承杰;唐存知;秦延才. 断块稠油油藏化学吞吐工艺技术研究与应用[J]. 西南石油大学学报(自然科学版), 2012, 34(4): 141-146.
[6]	吴川;陈艳玲王元庆杨超 . 超稠油改质降黏机理研究[J]. 西南石油大学学报(自然科学版), 2010, 32(2): 145-148.
[7]	周体尧程林松李春兰朱召峰郭双生. 过热蒸汽与稠油之间的水热裂解实验[J]. 西南石油大学学报(自然科学版), 2009, 31(6): 89-92.
[8]	石智强a 季宁宁b 卿大勇 . 聚氨酯/钛酸钡杂化材料及介电性质研究[J]. 西南石油大学学报(自然科学版), 2007, 29(5): 126-129.