西南石油大学学报(自然科学版) ›› 2002, Vol. 24 ›› Issue (4): 63-64.DOI: 10.3863/j.issn.1000-2634.2002.04.018

• 油气化学工程与化工 • 上一篇    下一篇

聚硅硫酸铁絮凝剂的研制

万里平 赵立志 孟英峰
  

  1. 西南石油学院,四川南充637001
  • 收稿日期:2001-11-28 修回日期:1900-01-01 出版日期:2002-08-20 发布日期:2002-08-20
  • 通讯作者: WAN Li-ping

SYNTHESIS OF POLYFERRIC SILICATE SULFATE FLOCCULANT

WAN Li-ping ZHAO Li-zhi MENG Ying-feng   

  1. Southwest Petroleum Institute, Nanchong Sichuan 637001, China
  • Received:2001-11-28 Revised:1900-01-01 Online:2002-08-20 Published:2002-08-20
  • Contact: 万里平

摘要:

以Na2SiO3、H2SO4和Fe2(SO4)3为主要原料,采用复合共聚生产工艺,制备了聚硅硫酸铁絮凝剂(PFSS)。研究了pH值、SiO2含量、温度对硅酸聚合过程的影响,并考察了Fe3+/SiO2摩尔比对PFSS稳定性和CODcr去除率的影响。结果表明,在最佳条件下合成的PFSS在脱色、CODcr去除率方面比PFS和PAC效果更显著,具有广阔的应用前景。

关键词: 聚硅硫酸铁, 复合共聚, 絮凝剂

Abstract:

A polyferric silicate sulfate(PFSS) flocculant has been prepared by using Na2SiO3、H2SO4and Fe2(SO4)3as raw materials according to compound co-polymerization.The pH value , SiO2content and temperature have different effects on the process of silicate preparation.The influence of molar ratio of Fe3+/SiO2on the stability of PFSS and removal rate of CODcr has been
studied.Results have shown that optimally-prepared-PFSS has more advantages than PFS and PAC on decoloration and removal rate of CODcr , and has widely applied prospects.

Key words: polyferric silicate sulfate, compound co-polymerization, flocculant

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