西南石油大学学报(自然科学版) ›› 2004, Vol. 26 ›› Issue (3): 71-74.DOI: 10.3863/j.issn.1000-2634.2004.03.021

• 油气化学工程与化工 • 上一篇    下一篇

含蜡原油结构抑制机理研究

敬加强
  

  1. (“油气藏地质及开发工程”国家重点实验室(西南石油学院),四川南充637001)
  • 收稿日期:2003-06-05 修回日期:1900-01-01 出版日期:2004-06-20 发布日期:2004-06-20
  • 通讯作者: 敬加强

STUDY OF WAXY CRUDE OILS STRUCTURE DEPRES-SION MECHANISM

JING Jia-qiang   

  1. (Southwest Petroleum Institute, Chengdu Sichuan 610500, China)
  • Received:2003-06-05 Revised:1900-01-01 Online:2004-06-20 Published:2004-06-20
  • Contact: JING Jia-qiang

摘要: 基于含蜡模拟油加抑制剂GY1前后的特征温度、流变参数、析蜡量及微观结构的实验分析,研究含蜡原油结构抑制机理。结果表明:①抑制剂GY1不能阻止蜡结晶与晶核的形成,反而使析蜡量有所增加;②对于含粗晶蜡的模拟油,抑制剂GY1将阻碍其蜡晶生长,使蜡晶尺寸变小、非对称性增大,进而增强蜡晶颗粒相互作用与连接趋势,宏观表现为降凝与降粘效果差;③对于含微晶蜡的模拟油,抑制剂GY1有助于其蜡晶的聚集生长,使蜡晶尺寸变大、表面结合力降低,进而抑制蜡晶颗粒相互作用与连接趋势,宏观表现为降凝降粘效果显著;④含蜡原油结构抑制的机理就是使蜡晶颗粒聚集变大、提高其对称性、降低其分散度、抑制其相互作用与连接的机理。

关键词: 含蜡原油, 结构抑制, 降凝, 降粘, 抑制剂, 蜡晶颗粒

Abstract:

Based on experimental analysis of characteristic tempera tures, rheological parameters, crystallized paraffin amount and microstructure of simulative oil before and after the addition of depressant GY1, structure depression mechanism of waxy crude oil has been investigated. Results show that:①Depressant GY1 cannot prevent wax crystallizing and crystalline nucleuses
forming but increases the crystallized paraffin amount.②For simulative oil with macrocrystal waxes, depressant GY1 can obstruct the growth of paraffin crystal, reduce their size and symmetry and increase their interaction and connecting trend. As a macroscopical result, the effect of pour point depression and viscosity reduction becomes worse.③For simulative oil with microcrystal waxes, depressant GY1 can promote the growth of paraffin crystal, increase their size, reduce their surface binding force and depress their interaction and connecting trend. As a macroscopical result, the effect of pour point depression and viscosity reduction is obvious.④The structure depression mechanism of waxy crude oil is the mechanism of increasing the size of paraffin particles, improving their symmetry, reducing their dispersivity, depressing their interaction and connection.

Key words: waxy crude oils, structure depression, pourpoint depression, viscosity reduction, depressant, paraffin particles

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