西南石油大学学报(自然科学版) ›› 2006, Vol. 28 ›› Issue (1): 52-55.DOI: 10.3863/j.issn.1000-2634.2006.01.015

• 油气化学工程与化工 • 上一篇    下一篇

用热失重法确定水合粘上水分含量及存在形式

王平全1 陈地奎2   

  1. (1.西南石油大学CNPC钻井液重点研究室,四川成都610500;2.西南石油局十一普)
  • 收稿日期:2005-01-18 修回日期:1900-01-01 出版日期:2006-02-20 发布日期:2006-02-20
  • 通讯作者: 王平全

THE DETERMINATION OF WATER CONTENT AND BOUND WATER TYPE ON HYDRO-CLAY SURFACE BY THERMAL-WEIGHTLESSNESS

WANG Ping-quan1 CHEN Di-kui2.

  

  1. ( Southwest Petroleum Institute,Chengdu Sichuan 610500, China)
  • Received:2005-01-18 Revised:1900-01-01 Online:2006-02-20 Published:2006-02-20
  • Contact: WANG Ping-quan

摘要: 以蒙脱土为例,采用热失重法定性定量确定了水合粘土中结合水类型、界限及其相对含量,并与等温吸附法结果进行了时比。结果表明,用该方法得到的水合蒙脱土中各种水分的相对含量及总含水量与等温吸附实验结果相一致。热失重(25~250℃)分析结果表明,水合蒙脱土中水分子主要存在自由水、松散吸附结合水、紧密吸附水(强吸附结合水)三种状态,分别劝应于25~75℃、75~120℃、120~230℃区间里的失水。从热失重(25~250℃)规律来看,仍存在两个明显的转折点。p/ps=0.9~0.98,它们为粘土一水体系的两个特征湿度,前者为粘土表面强结合水与松散结合水(渗透结合水)之间的界限,后者为松散结合水与自由水之间的界限,验证了等温吸附法确定的两个特征湿度及对粘土表面结合水界限划分的正确性。

关键词: 水合粘土, 热失重法, 结合水, 相对含量, 特征湿度

Abstract:

Thermal-weightlessness is utilized to determine the type boundary line and relative content of bound water on montmoril-lonite and the results of isothermal adsorption have been tom-pared. The results show that each water relative content and total water mass on hydro-montmorillonite场the method are incon-sistent to them by isothermal adsorption. Thermal weight loss a-nalysis ( 25~250`0)results show that water on hydro-mont-morillonite is free water, loose bound water and sirong bound water which respectively corresponding to the water loss in 25-75oC,75~120oC,and 120~230oC.According to thermal-weightlessness regularity(25~250oC),it also has two clear turning points which are plp。p/ps=0.9~0.98,the two turning points are the-special humidity of clay一water system. The rela-
five vapor pressure 0. 9 is the boundary line between the strong bound water and the loge bound water(osmotic bound water ) on clays, the relative vapor pressure 0. 98 is the boundary line between the loge bound water and free water on clays. The method verifies the "two special humidity" by isothermal adso p-lion and the boundary line of bound water on clays.

Key words: hydro clay, thermal weightlessness, bound water, relative content, special

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