西南石油大学学报(自然科学版) ›› 2010, Vol. 32 ›› Issue (1): 125-129.DOI: 10.3863/j.issn.1674-5086.2010.01.024

• 油气化学工程与化工 • 上一篇    下一篇

生物法应用于脱除硫化氢的实验研究

赵会军;刘凯;李俊玲   

  1. 江苏省油气储运技术重点实验室·江苏工业学院,江苏 常州 213016
  • 收稿日期:2008-12-09 修回日期:1900-01-01 出版日期:2010-02-20 发布日期:2010-02-20
  • 通讯作者: 赵会军

THE EXPERIMENTAL STUDY ON THE THIOBACILLUS DESULFURIZATION APPLIED TO REMOVING HYDROGEN SULFIDE

ZHAO Hui-jun;LIU Kai;LI Jun-ling   

  1. Jiangsu Key Laboratory of Oil and Gas Storage and Transportation Technology,Jiangsu Polytechnic University,Changzhou Jiangsu 213016,China
  • Received:2008-12-09 Revised:1900-01-01 Online:2010-02-20 Published:2010-02-20
  • Contact: ZHAO Hui-jun

摘要:

根据脱氮硫杆菌利用硫代硫酸盐、硫化物作为能源的性质,研究了脱氮硫杆菌应用于脱除硫化氢工艺中的碳酸钠溶液再生。通过单因素分析,进行了碳酸钠溶液含量、温度、pH值、进气速率、喷淋量、停留时间及洗涤液中含脱氮硫杆菌等因素对脱硫率影响的实验研究,初步确定了含H2S(浓度≤1300mg/m3)天然气脱硫的最佳工艺条件为:温度25~35℃,pH值8~9,初始碳酸钠质量分数5%,停留时间90s。实验结果还表明:喷淋量和进气速率都会影响脱硫率;进入吸收塔的再生碱液携带有脱氮硫杆菌,而含脱氮硫杆菌的洗涤液(再生碱液)有利于提高脱硫率。

关键词: 脱氮硫杆菌, 生物脱硫, 涡流扩散系数, 硫化氢, 脱硫率

Abstract:

In this paper,such factors as concentration of sodium carbonate solution,pH value,temperature,intake rate,spray amount,residence time and thiobacillus desulfurization in the washing solution influencing on the desulfurization rate are inspected by single factor analysis,and initially defined the optimal conditions for the natural gas containing H2S(concentration≤1300mg/m3) are as following,pH value is 8~9,temperature 25℃~35℃,initial concentration of the sodium carbonate solution 5%,residence time 90s.The experimental results also indicate that the spray amount and the intake rate influences the desulfurization rate,the regenerative lye which enters absorption tower carries thiobacillus desulfurization,which can help to improve desulfurization rate.

Key words: thiobacillus desulfurization, BDS, eddy diffusion coefficient, hydrogen sulfide, desulfurization rate

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