An Experimental Study on Influencing Factors of Dissolution Effect of#br#
Barium Sulfate Scale

doi:10.11885/j.issn.1674-5086.2014.12.03.01

Abstract

Abstract:

To study the influence factors of the dissolving effect of scale dissolving solvent DEED，we conducted weight loss
method experiments on the effects of solvent concentration，temperature，time and pH value on scale dissolving. First，we
analyzed the scale-dissolving mechanism of DEED via chemical methods through which the main functional groups of DEED
that can chelate Ba2+ are found. As a result，the reason behind different scale dissolving effects under various conditions can
be explained more accurately and reasonably. Then，a number of experiments were conducted to study the influence factors
of scale dissolving effect of the agent. Under the experimental conditions，when the concentration of scale-dissolving agent is
9%，the highest dissolving rate of 82.41% would be attained. The scale dissolving time and temperature have a great impact
on scale dissolution. With the increase of acting time，scale dissolving rate gradually increases，and the scale dissolving rate
increases greatly during first the 24 hours，which satisfies the requirement of field application. With a 24-hour dissolving time，
dissolving rate increases from 32.02% to 82.88% as temperature increases from 25 ?C to 85 ?C. On the other hand，the pH
value has a significant influence on the dose of carboxyl ionization and chelating performance of scale dissolving agent，thus
affecting scale dissolving effect of the agent. With a 24-hour dissolving time，dissolving rate increases from 8.37% to 81.26%
as pH value increases from 6 to 12. Thus alkaline pre-flush injection is recommended in oil field operation.

Key words: mechanism of scale dissolution, barium sulfate, temperature, time, pH

CLC Number:

TE358+.5

LI Hongjian1*, SUN Jianbo1，2, LI Ran1, YU Xiaowei1, WANG Deyu3. An Experimental Study on Influencing Factors of Dissolution Effect of#br# Barium Sulfate Scale[J]. 西南石油大学学报(自然科学版), DOI: 10.11885/j.issn.1674-5086.2014.12.03.01.

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References

[1] 李洪建，孟雪，李然，等. 影响硫酸钡阻垢效果因素
实验研究[J]. 西南石油大学学报（自然科学版），2014，
36（1）：139 144.
LI Hongjian，MENG Xue，LI Ran，et al. Experimental
study on factors affecting the effect of barium sulfate
scale inhibition[J]. Journal of Southwest Petroleum University（
Science & Technology Edition），2014，36（1）：
139 144.
[2] 李洪建，孙建波，孟雪，等. 碳酸钙阻垢效果影响因素
实验研究[J]. 西南石油大学学报（自然科学版），2016，
38（2）：143 148.
LI Hongjian，SUN Jianbo，MENG Xue，et al. An experimental
study on factors affecting the effect of calcium
carbonate scale inhibition[J]. Journal of Southwest
Petroleum University（Science & Technology Edition），
2016，38（2）：143 148.
[3] 李洪建，李振志，陈宗林，等. 高矿化度产出水集输中
的阻垢实验研究[J]. 西南石油大学学报（自然科学版），
2008，30（5）：133 136.
LI Hongjian，LI Zhenzhi，CHEN Zonglin，et al. Scale
prevention experiment research in gathering about highly
mineralized production water[J]. Journal of Southwest
Petroleum University（Science & Technology Edition），
2008，30（5）：133 136.
[4] 李洪建，陈一健，钟双飞，等. SZ36 1 油田水源水混注
对储层损害的实验研究[J]. 西南石油学院学报，2002，
24（6）：22 24.
LI Hongjian，CHEN Yijian，ZHONG Shuangfei，et al.
Experimental study of formation damage caused by three
kinds of source water mixed injection in SZ36 1[J].
Journal of Southwest Petroleum Institute，2002，24（6）：
22 24.
[5] MIRZA M S，PRASAD V. Scale removal in Khuff gas
wells[C]. SPE 53345，1999.
[6] RHUDY J S. Removal of mineral scale from reservoir core
by scale dissolver[C]. SPE 25161，1993.
[7] 孙赫. 三元复合驱除垢剂研究[D]. 大庆：东北石油大
学，2013.
SUN He. Research of ASP descaling agent[D]. Daqing：
Northeast Petroleum University，2013.
[8] 徐智艳. 采油四厂三元复合驱结垢机理研究[D]. 大庆：
东北石油大学，2013.
XU Zhiyan. Study on scaling mechanism about ASP
flooding in the fourth plant[D]. Daqing：Northeast
Petroleum University，2013.
[9] 张宇，周洪雷. 波谱解析[M]. 郑州：郑州大学出版社，
2006.
ZHANG Yu，ZHOU Honglei. Spectrum analysis[M].
Zhengzhou：Zhengzhou University Press，2006.
[10] 朱为宏，杨雪艳，李晶，等. 有机波谱及性能分析法[M].
北京：化学工业出版社，2007.
ZHU Weihong，YANG Xueyan，LI Jing，et al. Organic
spectrum and performance analysis[M]. Beijing：Chemical
Industry Press，2007.
[11] 郑延成，王任芳，周爱莲，等. 处理硫酸盐垢的氨羧
复合络合剂[J]. 石油与天然气化工，2004，33（3）：
197 199.
ZHENG Yancheng，WANG Renfang，ZHOU Ailian，et al.
Amino carboxylate chelants for sulfate scale removal[J].
Chemical Engineering of Oil and Gas，2004，33（3）：
197 199.
[12] 王成立，顾明，夏明珠，等. 聚合物阻垢剂阻垢机
理的分子动力学研究[J]. 精细化工，2004，21（增）：
146 148，156.
WANG Chengli，GU Ming，XIA Mingzhu，et al. Molecular
dynamics study of the mechanism of polymer scale inhibitor[
J]. Fine Chemicals，2004，21（S）：146 148，156.
[13] 王倩. 三元复合驱垢的溶解实验研究[D]. 大庆：东北石
油大学，2012.
WANG Qian. Study on experiment of dissolving the filth
about ASP[D]. Daqing：Northeast Petroleum University，
2012.
[14] BARRI A A，MAHMOUD M A. Effect of stimulation
with chelating agents on carbonate rocks integrity[C]. SPE
172709，2015.
[15] 生许磊. 油田阻垢剂的阻垢性能研究[D]. 青岛：中国海
洋大学，2013.
SHENG Xulei. Experiment study on evaluation of scale
inhibitors[D]. Qingdao：Ocean University of China，2013.
[16] SMITH P S，CLEMENT C C Jr，ROJAS A M. Combined
scale removal and scale inhibition treatments[C].
SPE 60222，2000.
[17] TAILBY R J，BEN A C，MCDONOUGH A. Scale removal
from the recesses of side-pocket mandrels[C]. SPE
54477，1999.
[18] 谢水祥，赵连国，苑权，等. 钡锶垢清垢剂ND 1 的
研制与性能评价[J]. 精细石油化工进展，2003，4（4）：
9 11.
XIE Shuixiang，ZHAO Lianguo，YUAN Quan，et al.
Preparation and evaluation of barium/stronitum scale
cleaning agent ND 1[J]. Advances in Fine Petrochemicals，
2003，4（4）：9 11.
[19] 石步乾，黄青松，冯兴武，等. 清除硫酸盐垢的有机溶
垢剂研究[J]. 精细石油化工进展，2004，5（10）：27 30，
34.
SHI Bujian，HUANG Qingsong，FENG Xingwu，et al.
Study of organic scale-dissolving agent for removing sulfate
scale[J]. Advances in Fine Petrochemicals，2004，
5（10）：27 30，34.
[20] 胡丹. 环保型无磷缓蚀阻垢剂的研制及缓蚀阻垢机理
研究[D]. 武汉：武汉理工大学，2012.
HU Dan. Preparation and study on the mechanism of
corrosion-scale inhibition of environmentally friendly corrosion
and scale inhibitor without phosphorus[D]. Wuhan：
Wuhan University of Technology，2012.

An Experimental Study on Influencing Factors of Dissolution Effect of#br# Barium Sulfate Scale

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