西南石油大学学报(自然科学版) ›› 2009, Vol. 31 ›› Issue (5): 125-129.DOI: 10.3863/j.issn.1674-5086.2009.05.027

• 油气化学工程与化工 • 上一篇    下一篇

海洋水合物钻井用甲酸盐钻井液体系研究

蒋国盛 宁伏龙 张昊 涂运中 张凌   

  1. 中国地质大学(武汉)工程学院,湖北武汉430074
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2009-10-20 发布日期:2009-10-20

EXPERIMENTAL EVALUATION ON FORMATE BASED DRILLING FLUIDS FOR GAS HYDRATE DRILLING IN OCEAN WATER

JIANG Guo-sheng NING Fu-long ZHANG Hao TU Yun-zhong ZHANG Ling   

  1. Faculty of Engineering,China University of Geosciences,Wuhan Hubei 430074,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2009-10-20 Published:2009-10-20

摘要: 通过实验测试,对甲酸盐钻井液体系的低温稳定性、水合物抑制剂对体系的影响以及钻井液体系的水合物抑制性进行了初步评价。结果表明,以海水+3.0%HCOONa+3.0%SK2+0.2%KPAM+0.1%LVPAC+2.0%SMP2+0.3%改性淀粉为基本体系(基液)的甲酸盐钻井液低温(-5~20℃)稳定性比较好,热力学抑制剂NaCl和KCl对体系流变性能没有太大影响,而动力学抑制剂PVP(K30)虽然加量很少,但对体系黏度和切力影响比较大。甲酸盐钻井液如果不添加水合物抑制剂,在水深超过1400m后,混入大量天然气,会很容易形成水合物。低剂量的动力学抑制剂PVP(K30)能有效提高甲酸盐钻井液的水合物抑制性,其加量在0.5%左右较为合适。因此,添加较高含量无机盐和较低含量动力学抑制剂的甲酸盐钻井液体系可以较好地满足水合物钻井需求。

关键词: 天然气水合物, 钻井液, 甲酸盐, 低温, 抑制剂

Abstract: The hydrate inhibition and low-temperature stability of formate based drilling fluids,as well as effect of hydrates inhibitors on the fluids,are evaluated elementarily by the experimental test.The results show that a basic system(base liquid)of formate based drilling fluids,which are composed of seawater,3.0% HCOONa,3.0%SK-2,0.2%KPAM,0.1%LV-PAC,2.0%SMP-2 and 0.3% modified starch,has a good performance stability under low temperature environment (-5℃~20℃).Adding NaCl and KCl,thermodynamic inhibitors,has little effect on the rheology properties of the basic system,while PVP (K30),a dynamic inhibitor,has a great effect on the properties.The basic system has a low ability of hydrates inhibition when it is used in deep water over 1400m.Low dosage of PVP (K30) can increasingly improve the hydrate inhibition of the basic system,and the suitable concentration is about 0.5%.Therefore,the formate based drilling fluids which contain high concentration of salts and low dosage of hydrate inhibitors can meet the needs of gas hydrate drilling in the deep water.

Key words: gas hydrate, drilling fluids, formate, low temperature, inhibitor

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