西南石油大学学报(自然科学版) ›› 2010, Vol. 32 ›› Issue (6): 1-4.DOI: 10.3863/j.issn.1674-5086.2010.06.001

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H2S对固井材料的腐蚀过程研究

阿格扎莫夫.法里特.阿克拉莫维奇   

  1. 乌法国立石油技术大学,巴什科尔托斯坦共和国 乌法 450062
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2010-12-20 发布日期:2010-12-20

STUDY ON THE CORROSION PROCESS OF H2S ON CEMENTING MATERIALS

Агзамов.Фарит.Акрамович   

  1. Russia Academy of Natural Science
  • Received:1900-01-01 Revised:1900-01-01 Online:2010-12-20 Published:2010-12-20

摘要: 针对油气田开采中固井水泥石易受损害、不够牢固的问题,开展了H2S对固井材料腐蚀过程的研究。研究分为两个方面:通过对H2S气体与碳酸钙和弱碱性含水碳酸盐的腐蚀过程的研究,获得了水泥石中所有化合物的稳定性顺序,对腐蚀产物体积变化研究后认为,水泥石的破坏是因为在水泥石孔隙空间积累了腐蚀产物;通过对溶解在液体中的H2S对水泥石的腐蚀研究,得到了H2S对水泥石腐蚀的影响因素,认为,降低与固井水泥石接触的岩层的孔隙率和渗透性,可以降低水泥石的被腐蚀速度。研究成果对高含硫储层的开采具有一定意义。

关键词: 高含硫储层, 固井, 水泥, 腐蚀, 硫化氢, 低孔低渗

Abstract: In order to solve the problem that the well-cementing cement is not strong enough and vulnerable during the oil and gas exploitation,a study of the corrosion process of H2S on cementing materials is carried out.The study is carried out in two aspects:through the study of the corrosion process of H2S gas on calcium carbonate and weak alkaline water-bearing carbonates,the stability of all compounds in the cement is obtained.After a research of the change of the volume and size of the corrosion products,it can be concluded that:the destruction of cement is caused by the accumulation of corrosion products in the cement pore space;through the study of the corrosion effect of the H2S dissolved in the liquid on cement,the corrosion factors of H2S on cement have been acquired.And another conclusion is drawn:reducing the porosity and permeability of rocks which are exposed to well-cementing cement can reduce the corrosion rate of cement.These conclusions have a certain significance for the high sulfur reservoir.

Key words: high sulfur reservoir, cementing, cement, corrosion, hydrogen sulfide, low porosity and permeability

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