水合物快速生成技术及装置

doi:10.11885/j.issn.1674-5086.2022.06.28.02

摘要/Abstract

摘要： 气体水合物技术在天然气固态储运、海水淡化和 CO₂ 封存等领域有着广阔的应用前景，水合物快速生成是制约水合物技术应用的关键问题之一；由于对水合物快速生成的研究起步较晚，水合物反应器研制发展尚未成熟，生成速率达不到工业要求。如何提高水合物生成速率，实现水合物的快速生成是实现气体水合物技术应用亟待解决的问题之一。结合水合物的生成机理，分析了制约水合物快速生成的影响因素；回顾了各类水合物快速生成装置的结构和原理，从传质传热角度解析了各类反应器的优缺点，并对未来的研究方向提供几点建议：对有良好应用前景的装置加强改进，逐步扩大规模；结合高科技装备，构建新型反应器；构建一个标准的反应器评价体系。

关键词: 水合物, 快速生成, 传热, 传质, 反应器

Abstract: Gas hydrate technology has broad application prospects in the fields of natural gas solid state storage and transportation, seawater desalination, carbon dioxide storage, etc. The rapid formation of hydrate is considered to be one of the key problems restricting the application of hydrate technology. But the hydrate reactors have not been developed completely, and the formation rate cannot meet the industrial requirements due to the late start of researches on rapid hydrate formation. Therefore, realization of the rapid formation of hydrate is one of the urgent problems to be solved in the application of gas hydrate technology. The influence factors restricting the rapid formation of hydrate are analyzed with consideration of hydrate formation mechanism. Then the structures and principles of rapid hydrate generation devices of various types are reviewed, and the advantages and disadvantages of the reactors are analyzed from the perspective of mass transfer and heat transfer. Finally, suggestions for future research directions are provided: the device with good application prospects should be strengthened and improved gradually to expand the scale; and new types of reactors are constructed using high-tech equipment; standard reactor evaluation system should be established.

Key words: hydrate, rapid formation, heat transfer, mass transfer, reactor

中图分类号:

TE89

葛坤, 魏皓琦, 王佳琪, 张昕宇. 水合物快速生成技术及装置[J]. 西南石油大学学报(自然科学版), 2024, 46(3): 77-93.

GE Kun, WEI Haoqi, WANG Jiaqi, ZHANG Xinyu. Rapid Hydrarate Generation Technology and Devices[J]. Journal of Southwest Petroleum University(Science & Technology Edition), 2024, 46(3): 77-93.

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