纯水体系下水合物的生成及堵塞实验研究

doi:10.11885/j.issn.1674-5086.2018.09.15.01

西南石油大学学报(自然科学版) ›› 2019, Vol. 41 ›› Issue (4): 152-158.DOI: 10.11885/j.issn.1674-5086.2018.09.15.01

纯水体系下水合物的生成及堵塞实验研究

李乐¹, 朱倩谊¹, 陈小康²

1. 江苏城乡建设职业学院公用事业学院, 江苏常州 213147;
2. 常州大学石油工程学院, 江苏常州 213147

收稿日期:2018-09-15 出版日期:2019-08-10 发布日期:2019-08-10
通讯作者: 李乐,E-mail:837323761@qq.com
作者简介:李乐,1992年生,男,汉族,江苏徐州人,硕士,主要从事天然气水合物储运技术以及经济开发方面的研究。E-mail:837323761@qq.com;朱倩谊,1994年生,女,汉族,江苏常州人,硕士,主要从事天然气水合物储运技术以及经济开发方面的研究。E-mail:395547618@qq.com;陈小康,1993年生,男,汉族,陕西渭南人,硕士,主要从事天然气水合物储运技术方面的研究。Email:1591273668@qq.com
基金资助:
国家自然科学基金（51574045）；中国石油科技创新基金（2016D-5007-0607）；江苏省住建厅课题（2018ZD015）

An Experimental Study on Hydrate Formation and Blockage in a Pure Water System

LI Le¹, ZHU Qianyi¹, CHEN Xiaokang²

1. Utilities Department, Jiangsu Urban and Rural Construction Vocational College, Changzhou, Jiangsu 213147, China;
2. Petroleum Engineering Institute, Changzhou University, Changzhou, Jiangsu 213147, China

Received:2018-09-15 Online:2019-08-10 Published:2019-08-10

摘要/Abstract

摘要： 为了保障水合物浆液在管路中安全流动，开展了CO₂水合物生成及堵塞实验，探究纯水体系下CO₂水合物生成到堵塞管路的形态变化以及系统压力、泵速等因素对水合物浆液流动形态的影响。实验结果表明，（1）在纯水体系下，管道中水合物呈浆状和泥状两种形态，且CO₂水合物从生成到堵塞管路时间较短。（2）实验过程中，临界泵速为35 Hz；当泵速大于35 Hz时，水合物在管输过程中不会发生堵塞现象；当泵速小于35 Hz时，在系统压力相同的条件下，随着泵速的增加，水合物发生堵塞的时间延长。（3）同一泵速条件下，随着系统压力升高，水合物发生堵塞时间缩短；且系统压力为3.4 MPa时，水合物发生堵塞的时间为2 100 s；系统压力为2.4 MPa时，水合物发生堵塞的时间为6 225 s。

关键词: CO₂水合物, 生成, 堵塞, 泵速, 压力

Abstract: To ensure the safety of hydrate slurry flow in pipelines, an experiment on CO₂ hydrate synthesis and blockage was performed to investigate the morphological changes to CO₂ hydrates from the point of synthesis to pipeline blockage in a pure water system as well as the influences of system pressure and pump speed on the flow patterns of the hydrate slurry. The experimental results of this study are as follows:(1) In a pure water system, hydrates exist in the form of slurries or slush within pipelines, and the time interval between CO₂ hydrate synthesis and pipeline blockage is relatively short. (2) The critical pump speed during the experiment is 35 Hz. When the pump speed exceeds 35 Hz, the hydrates do not result in blockage during pipeline transportation; when the pump speed is below 35 Hz, an increase in pump speed delays the occurrence of hydrate blockage under conditions of identical system pressure. (3) Under conditions of identical pump speed, an increase in system pressure shortens the time interval between hydrate synthesis and blockage. At system pressures of 3.4 MPa and 2.4 MPa, hydrate blockages respectively occur at 2 100 s and 6 225 s after hydrate synthesis.

Key words: CO₂ hydrates, synthesis, blockage, pump speed, pressure

中图分类号:

TE38
TQ026

李乐, 朱倩谊, 陈小康. 纯水体系下水合物的生成及堵塞实验研究[J]. 西南石油大学学报(自然科学版), 2019, 41(4): 152-158.

LI Le, ZHU Qianyi, CHEN Xiaokang. An Experimental Study on Hydrate Formation and Blockage in a Pure Water System[J]. 西南石油大学学报(自然科学版), 2019, 41(4): 152-158.

0
/ / 推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal15.magtechjournal.com/Jwk_xnzk/CN/10.11885/j.issn.1674-5086.2018.09.15.01

http://journal15.magtechjournal.com/Jwk_xnzk/CN/Y2019/V41/I4/152

参考文献

[1] 周诗岽,李乐,李青岭,等. 天然气水合物浆液流动形态与流变性的研究进展[J]. 石油化工, 2017, 46(2):248-253. doi:10.3969/j.issn.1000-8144.2017.02.018 ZHOU Shidong, LI Le, LI Qingling, et al. Advances in research for the flow rheological properties of natural gas hydrate slurry[J]. Petrochemical Technology, 2017, 46(2):248-253. doi:10.3969/j.issn.1000-8144.2017.02.018
[2] 闫柯乐,邹兵,姜素霞,等. 水合物浆液流动与流变特性研究进展[J]. 化工进展, 2015, 34(7):1817-1825. doi:10.16085/j.issn.1000-6613.2015.07.002 YAN Kele, ZOU Bing, JIANG Suxia, et al. Review on flow characteristics and rheological properties of hydrate slurry[J]. Chemical Industry and Engineering Progress, 2015, 34(7):1817-1825. doi:10.16085/j.issn.1000-6613.2015.07.002
[3] 周诗岽,李青岭,李乐,等. 新型天然气水合物动力学抑制剂的制备及性能[J]. 石油化工, 2017, 46(4):467-470. doi:10.3969/j.issn.1000-8144.2017.04.013 ZHOU Shidong, LI Qingling, LI Le, et al. Synthesis and properties of novel kinetic inhibitors for natural gas hydrate[J]. Petrochemical Technology, 2017, 46(4):467-470. doi:10.3969/j.issn.1000-8144.2017.04.013
[4] 孙贤,刘德俊. 二氧化碳水合物动力学促进剂研究进展[J]. 化工进展, 2018, 37(2):517-524. doi:10.16085/j.issn.1000-6613.2017-0987 SUN Xian, LIU Dejun. Advances in carbon dioxide hydrate kinetic additives[J]. Chemical Industry and Engineering Progress, 2018, 37(2):517-524. doi:10.16085/j.issn.1000-6613.2017-0987
[5] 饶永超,王树立,代文杰,等. 天然气水合物浆体流变性与安全流动边界研究进展[J]. 化工进展,2015,34(10):3551-3556. doi:10.16085/j.issn.1000-6613.2015.10.005 RAO Yongchao, WANG Shuli, DAI Wenjie, et al. Research progress on slurry rheological properties and security flow boundary of natural gas hydrate[J]. Chemical Industry and Engineering Progress, 2015, 34(10):3551-3556. doi:10.16085/j.issn.1000-6613.2015.10.005
[6] 周诗岽,于雪薇,江坤,等. 蜡晶析出对天然气水合物生成动力学特性的影响[J]. 天然气工业, 2018, 38(3):103-109. doi:10.3787/j.issn.1000-0976.2018.03.013 ZHOU Shidong, YU Xuewei, JIANG Kun, et al. Effect of wax crystal precipitation on the kinetic characteristics of hydrate formation[J]. Natural Gas Industry, 2018, 38(3):103-109. doi:10.3787/j.issn.1000-0976.2018.03.013
[7] PENG Baozi, CHEN Jun, SUN Changyu, et al. Flow characteristics and morphology of hydrate slurry formed from (natural gas+diesel oil/condensate oil+water) system containing anti-agglomerant[J]. Chemical Engineering Science, 2012, 84:333-344. doi:10.1016/j.ces.2012.08.030
[8] JOSHI S V, GRASSO G A, LAFOND P G, et al. Experimental flowloop investigations of gas hydrate formation in high water cut systems[J]. Chemical Engineering Science, 2013, 97(7):198-209. doi:10.1016/j.ces.2013.04.019
[9] DARBOURET M, COURNIL M, HERRI J M. Rheological study of TBAB hydrate slurries as secondary twophase refrigerants[J]. International Journal of Refrigeration, 2005, 28(5):663-671. doi:10.1016/j.ijrefrig.2005.01.002
[10] DELAHAYE A, FOURNAISON L, MARINHAS S, et al. Rheological study of CO₂ hydrate slurry in a dynamic loop applied to secondary refrigeration[J]. Chemical Engineering Science, 2008, 63(13):3551-3559. doi:10.1016/j.ces.2008.04.001
[11] SONG Guangchun, LI Yuxing, WANG Wuchang, et al. Investigation of hydrate plugging in natural gas+diesel oil+water systems using a high-pressure flow loop[J]. Chemical Engineering Science, 2017, 158:480-489. doi:10.1016/j.ces.2016.10.045
[12] AMAN Z M, PFEIFFER K, VOGT S J, et al. Corrosion inhibitor interaction at hydrate-oil interfaces from differential scanning calorimetry measurements[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2014, 448:81-87. doi:10.1016/j.colsurfa.2014.02.006
[13] 唐翠萍,赵翔湧,何勇,等. 管道内二氧化碳水合物的形成和流动特性研究[J]. 天然气化工(C1化学与化工), 2015, 40(4):37-40, 63. doi:10.3969/j.issn.1001-9219.2015.04.008 TANG Cuiping, ZHAO Xiangyong, HE Yong, et al. Study on CO₂ gas hydrate formation and flow characteristics in pipe[J]. Natural Gas Chemical Industry, 2015, 40(4):37-40, 63. doi:10.3969/j.issn.1001-9219.2015.04.008
[14] 陈伟军,刘妮,肖晨,等. CO₂水合物浆在蓄冷空调中的应用前景[J]. 制冷学报, 2012, 33(3):1-4, 8. doi:10.3969/j.issn.0253-4339.2012.03.001 CHEN Weijun, LIU Ni, XIAO Chen, et al. Perspective of CO₂ hydrate slurry application in ari conditioning system with cool storage[J]. Journal of Refrigeration, 2012, 33(3):1-4, 8. doi:10.3969/j.issn.0253-4339.2012.03.001
[15] FOUMAISON L, DELAHAYE A, CHATTI I. CO₂ hydrates in refrigeration processes[J]. Industrial & Engineering Chemistry Research, 2012, 43(20):6521-6526. doi:10.1021/ie030861r
[16] OIGNET J, HOANG M H, OSSWALD V, et al. Experimental study of convective heat transfer coefficients of CO₂, hydrate slurries in a secondary refrigeration loop[J]. Applied Thermal Engineering, 2017, 118(5):630-637. doi:10.1016/j.applthermaleng.2017.02.117
[17] WANG Wuchang, FAN Shuanshi, LIANG Deqing, et al. Experimental investigation on formation and blockage of HCFC-141b hydrates in pipeline[J]. Journal of Xi'an Jiaotong University, 2008, 42(5):602-606. doi:10.1016/0039-6028(94)90537-1
[18] BOXALL J A, KOH C A, SLOAN E D, et al. Droplet size scaling of water-in-oil emulsions under turbulent flow[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2012, 28(1):104-10. doi:10.1021/la202293t
[19] BOXALL J A, KOH C A, SLOAN E D, et al. Measurement and calibration of droplet size distributions in waterin-oil emulsions by particle video microscope and a focused beam reflectance method[J]. Industrial & Engineering Chemistry Research, 2010, 49(3):1412-1418. doi:10.1021/ie901228e
[20] 吕晓方,吴海浩,史博会,等. 流动体系中二氧化碳水合物堵管时间实验研究[J]. 实验室研究与探索, 2013, 32(11):197-202. doi:10.3969/j.issn.1006-7167.2013.11.053 LÜ Xiaofang, WU Haihao, SHI Bohui, et al. Experimental study on the time for CO₂ hydrate blockage in a flow loop[J]. Research and Exploration in Laboratory, 2013, 32(11):197-202. doi:10.3969/j.issn.1006-7167.2013.11.053

纯水体系下水合物的生成及堵塞实验研究

An Experimental Study on Hydrate Formation and Blockage in a Pure Water System

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	石榆帆, 唐宜家, 马天寿, 何玉发. 深水环空圈闭压力的破裂盘泄压控制模型[J]. 西南石油大学学报(自然科学版), 2020, 42(5): 153-160.
[2]	罗川, 杨虎. 论构造应力不是油气初次运移的主要动力[J]. 西南石油大学学报(自然科学版), 2020, 42(4): 104-110.
[3]	熊钰, 刘成, 周文胜, 刘晨, 钟浩. 物性结构差对9点井网排状加密前后影响研究[J]. 西南石油大学学报(自然科学版), 2020, 42(3): 80-96.
[4]	石先亚, 黄侠, 史景岩, 赵广渊, 徐丽媛. 压力衰竭下疏松砂岩出砂临界生产压差预测方法[J]. 西南石油大学学报(自然科学版), 2020, 42(3): 115-122.
[5]	胡黎明. 油气聚集形成异常高压机理初探[J]. 西南石油大学学报(自然科学版), 2020, 42(2): 118-124.
[6]	陈晓明, 刘英宪, 吴穹螈, 刘超, 赵汉卿. 海上轻质油藏水驱渗流阻力特征研究[J]. 西南石油大学学报(自然科学版), 2020, 42(1): 101-110.
[7]	张烈辉, 崔乾晨, 谢军, 郑健, 李成勇. 页岩气藏压裂水平井线性耦合渗流模型研究[J]. 西南石油大学学报(自然科学版), 2019, 41(6): 1-12.
[8]	马天寿, 彭念, 陈平, 邓智中. 页岩气水平井井壁裂缝起裂力学行为研究[J]. 西南石油大学学报(自然科学版), 2019, 41(6): 87-99.
[9]	方全堂, 李政澜, 段永刚, 魏明强, 张羽翼. 考虑次生裂缝的页岩气藏有限导流缝网模型[J]. 西南石油大学学报(自然科学版), 2019, 41(6): 139-145.
[10]	王国荣, 王腾, 李蓉, 王斐. 页岩气超高压往复泵工作腔压力测试与分析[J]. 西南石油大学学报(自然科学版), 2019, 41(6): 174-180.
[11]	吴碧波, 邹明生, 陆江, 严恒, 曾小明. 涠西南凹陷TY油田断层封闭性定量评价[J]. 西南石油大学学报(自然科学版), 2019, 41(4): 74-80.
[12]	万伟, 练章华, 彭星煜, 刘力升, 刘畅. 大牛地气田二次增压时机及增压方案优选[J]. 西南石油大学学报(自然科学版), 2019, 41(3): 129-136.
[13]	祖琳. 水平井、直井联合开发压力场及流线分布研究[J]. 西南石油大学学报(自然科学版), 2019, 41(2): 143-151.
[14]	杨向前, 张兴全, 刘书杰, 任美鹏. 深水井环空圈闭压力管理方案研究[J]. 西南石油大学学报(自然科学版), 2019, 41(2): 152-159.
[15]	杨树坤, 郭宏峰, 赵广渊, 季公明, 张博. 致密砂岩油藏注热水降压增注实验研究[J]. 西南石油大学学报(自然科学版), 2019, 41(1): 102-110.