西南石油大学学报(自然科学版) ›› 2009, Vol. 31 ›› Issue (1): 128-132.DOI: 10.3863/j.issn.1674-5086.2009.01.031

• 油气化学工程与化工 • 上一篇    下一篇

盐水完井液缓蚀剂的合成及性能评价

梁发书 唐力 冷曼希   

  1. 西南石油大学化学化工学院,四川成都610500
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2009-02-20 发布日期:2009-02-20

SYNTHESIS AND PERFORMANCE EVALUATION OF CORROSION INHIBITOR FOR BRINE COMPLETION FLUIDS

LIANG Fa-shu TANG Li LENG Man-xi   

  1. College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu Sichuan 610500,China
  • Received:1900-01-01 Revised:1900-01-01 Online:2009-02-20 Published:2009-02-20

摘要:

针对高温高盐的油气开发工程防腐的需要,以乙二胺、甲醛和亚磷酸为主要原料,讨论了反应条件对产物的影响并优选了实验,合成出一种在盐水完井液中使用的缓蚀剂。利用室内挂片失量法对该缓蚀剂体系性能进行了评价。研究结果表明:该缓蚀剂加量小、性能稳定、效果明显、抗温能力强、有较好的抗盐能力。在pH值为5~7,温度低于120℃,加量为0.2g/L时,能使腐蚀速度控制在0.0700mm/a以下,能有效阻止盐水介质的腐蚀。

关键词: 腐蚀, 盐水, 缓蚀剂, 有机膦酸, 合成

Abstract:

Based on the molecular structure of corrosion inhibitor of brine,the product with a good performance is synthesized by selecting ethylenediamine,formaldehyde and sub-phosphate as the main raw materials for high-temperature,high-salt oil and gas exploitation project preservation needs.The reaction conditions and the impact on products are discussed and the optimization is tesed.A corrosion inhibitor used in brine completion fluid is synthesized.In this paper,a detailed description of indoor weightlessness method is given for researching the performance evaluation of corrosion inhibitor system.The results show that the corrosion inhibitor possesses a good salt-resistant and anti-temperature capability with stable performance and evident result by adding a small amount of it.The corrosion rate can be controlled in 0.070mm/a when PH value is 5~8,tempreature lower than 20℃,added amount 0.2g/L.So it has excellent ability to effectively prevent corrosion of saline media.

Key words: corrosion, brine, corrosion inhibitors, organic phosphate, synthesis

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