钻井液用高吸水性树脂的防漏堵漏性能研究

doi:10.11885/j.issn.1674-5086.2024.07.03.02

西南石油大学学报(自然科学版) ›› 2025, Vol. 47 ›› Issue (4): 1-9.DOI: 10.11885/j.issn.1674-5086.2024.07.03.02

• 院士思维 • 下一篇

钻井液用高吸水性树脂的防漏堵漏性能研究

罗平亚^1,2, 代锋^1,3, 刘应民³, 贺佳宁¹, 白杨^1,2,4

1. 西南石油大学石油与天然气工程学院, 四川成都 610500;
2. 油气藏地质及开发工程全国重点实验室·西南石油大学, 四川成都 610500;
3. 四川长宁天然气开发有限责任公司, 四川成都 610000;
4. 油气钻完井技术国家工程研究中心, 北京昌平 102200

收稿日期:2024-07-03 发布日期:2025-07-25
通讯作者: 代锋，E-mail:daifeng99@petrochina.com.cn
作者简介:罗平亚，1940年生，男，汉族，四川隆昌人，中国工程院院士，主要从事钻井液与完井液、储层保护技术和提高采收率方面的研究工作。E-mail:luopy@swpu.edu.cn
代锋，1984年生，男，汉族，四川威远人，高级工程师，博士研究生，主要从事页岩气钻完井工程方面的研究工作。E-mail:daifeng99@petrochina.com.cn
刘应民，1982年生，男，汉族，四川叙永人，高级工程师，主要从事页岩气钻井工程管理和相关科研工作。E-mail:283121983@qq.com
贺佳宁，2000年生，女，汉族，新疆昌吉人，硕士研究生，主要从事油气井工作液方面的研究工作。E-mail:1484327779@qq.com
白杨，1985年生，男，汉族，新疆昌吉人，研究员，博士研究生导师，主要从事油气井工作液方面的研究工作。E-mail:281824767@qq.com
基金资助:
国家自然科学基金（52274008，U23A2026）；国家重点研发计划（2019YFA0708303）；中国石油西南石油大学创新联合体科技合作项目（2020CX040102，2020CX040201）

Research on High Water Absorbent Resin for Leak Prevention and Sealing in Water-based Drilling Fluid

LUO Pingya^1,2, DAI Feng^1,3, LIU Yingmin³, HE Jianing¹, BAI Yang^1,2,4

1. Petroleum Engineering School, Southwest Petroleum University, Chengdu, Sichuan 610500, China;
2. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China;
3. Geological Engineering Department of Sichuan Changning Natural Gas Development Co. Ltd., Chengdu, Sichuan 610000, China;
4. National Engineering Research Center of Oil & Gas Drilling and Completion Technology, Changping, Beijing 102200, China

Received:2024-07-03 Published:2025-07-25

摘要/Abstract

摘要： 针对采用水基钻井液开采页岩油气藏时，容易因页岩含黏土颗粒、天然裂缝等导致井漏且无法堵漏成功的问题，以丙烯酸和聚乙烯醇为单体，N，N'-亚甲基双丙烯酰胺为化学交联剂，采用响应曲面法并以吸水倍率为响应目标，对实验因素进行优化，通过自由基溶液聚合制得一种PAA（聚丙烯酸）和PVA（聚乙烯醇）互穿网络结构的高吸水性树脂堵漏剂。采用红外、热重和扫描电镜分析验证了堵漏剂的合成成功并具备热稳定性。利用封堵及承压能力实验、砂床实验和微裂缝模拟实验对堵漏剂的承压堵漏性能进行评价。实验结果表明，堵漏剂具备良好热稳定性，在裂缝宽度为2 mm，温度为180 ℃，堵漏剂加量为3%，围压为10 MPa条件下，最高承压能力为6.08 MPa，高温高压滤失量为9 mL，能够有效实现页岩地层中水基钻井液的堵漏目标。

关键词: 页岩, 堵漏, 高吸水性树脂, 响应曲面法, 吸水倍率

Abstract: To address the problem of wellbore leakage caused by clay particles and natural fractures in shale oil and gas reservoirs using water-based drilling fluids, which cannot be successfully plugged, acrylic acid and polyvinyl alcohol are used as monomers, N, N'-methylene bisacrylamide is used as a chemical crosslinking agent, and the response surface method is adopted with water absorption rate as the response target. The experimental factors are optimized, and a PAA/PVA interpenetrating network structure high water absorbent resin plugging agent is prepared through free radical solution polymerization. The successful synthesis and thermal stability of the plugging agent were verified by infrared, thermogravimetric, and scanning electron microscopy analysis. Evaluate the pressure sealing performance of the plugging agent through sealing and pressure bearing capacity experiments, sand bed experiments, and micro crack simulation experiments. The test results show that the plugging agent has good thermal stability. Under the conditions of a fracture width of 2 mm, a temperature of 180 ℃, a plugging agent dosage of 3%, and a confining pressure of 10 MPa, the maximum pressure bearing capacity is 6.08 MPa, and the high-temperature and high-pressure filtration loss is 9 mL. It can achieve the plugging effect of water-based drilling fluid in shale formations.

Key words: shale, plugging, high water absorbent resin, response surface methodology, water absorption rate

中图分类号:

TE254.6

罗平亚, 代锋, 刘应民, 贺佳宁, 白杨. 钻井液用高吸水性树脂的防漏堵漏性能研究[J]. 西南石油大学学报(自然科学版), 2025, 47(4): 1-9.

LUO Pingya, DAI Feng, LIU Yingmin, HE Jianing, BAI Yang. Research on High Water Absorbent Resin for Leak Prevention and Sealing in Water-based Drilling Fluid[J]. Journal of Southwest Petroleum University(Science & Technology Edition), 2025, 47(4): 1-9.

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参考文献

[1] AJAYI K M, SCHATZEL S J. Transport model for shale gas well leakage through the surrounding fractured zones of a longwall mine[J]. International Journal of Mining Science and Technology, 2020, 30(5): 635-641. doi: 10.3969/j.issn.2095-2686.2020.05.008
[2] RAHMATABADI D, SOLTANMOHAMMADI K, PAHLAVANI M, et al. Shape memory performance assessment of FDM 3D printed PLA-TPU composites by BoxBehnken response surface methodology[J]. The International Journal of Advanced Manufacturing Technology, 2023, 127(1-2): 935-950. doi: 10.1007/s00170-02311571-2
[3] ABBAS M A, ZAMIR A, ELRAIES K A, et al. A critical parametric review of polymers as shale inhibitors in water-based drilling fluids[J]. Journal of Petroleum Science and Engineering, 2021, 204: 108745. doi: 10.1016/j.petrol.2021.108745
[4] JI Lujun, GUO Quanxin, FRIEDHEIM J, et al. Laboratory evaluation and analysis of physical shale inhibition of an innovative water-based drilling fluid with nanoparticles for drilling unconventional shales[C]. SPE 158895MS, 2012. doi: 10.2118/158895-MS
[5] ZHANG L W, ANDERSON N, DILMORE R, et al. Leakage detection of Marcellus Shale natural gas at an Upper Devonian gas monitoring well: A 3D numerical modeling approach[J]. Environmental Science and Technology, 2014, 48(18): 10795-10803. doi: 10.1021/es501997p
[6] ZHAO Zhen, SUN Jinsheng, LIU Fan, et al. Micro-nano polymer microspheres as a plugging agent in oil-based drilling fluid[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 673: 131808. doi: 10.1016/j.colsurfa.2023.131808
[7] ZHONG Hanyi, GAO Xin, QIU Zhengsong, et al. Insight into beta-cyclodextrin polymer microsphere as a potential filtration reducer in water-based drilling fluids for high temperature application[J]. Carbohydrate Polymers, 2020, 249(21): 116833. doi: 10.1016/j.carbpol.2020.116833
[8] 汪建军. 功能型复合凝胶自适应堵漏技术研究[D]. 成都:四川大学， 2007. doi: 10.7666/d.y1213063 WANG Jianjun. Research on automatic lost circulation prevention technology of the functional compoud gel[D]. Chengdu: Sichuan University, 2007. doi: 10.7666/d.y1213063
[9] KONG Xiangwei, CHEN Mingzhong, ZHANG Chaoju, et al. Optimization of high temperature-resistant modified starch polyamine anti-collapse water-based drilling fluid system for deep shale reservoir[J]. Molecules, 2022, 27(24): 8936. doi: 10.3390/molecules27248936
[10] 牛磊星，孙平贺. 丙烯酸高吸水膨胀树脂在深部钻探中的堵漏试验[J]. 地质科技情报， 2017， 36（1）:208-212. doi: 10.19509/j.cnki.dzkq.2017.0126 NIU Leixing, SUN Pinghe. Experimental study on the plugging of acrylic acid high water absorbing resin in deep drilling[J]. Geological Science and Technology Information, 2017, 36(1): 208-212. doi: 10.19509/j.cnki.dzkq.2017.0126
[11] PEÑAS-CABALLERO M, MARTÍN-CORDÓN J, BARRANCO V, et al. Corrosion control by autonomous selfhealing epoxy coatings based on superabsorbent healing agents[J]. Progress in Organic Coatings, 2023, 182: 107600. doi: 10.1016/j.porgcoat.2023.107600
[12] ZHU Z, SAWUT A, SIMAYI R, et al. Preparation of hypromellose-graft-polyacrylic acid superabsorbent resin by ultraviolet polymerization and its slow-release performance[J]. ACS Applied Polymer Materials, 2024, 6(6): 3128-3138. doi: 10.1021/acsapm.3c02872
[13] 贾丽莉，田陆飞，刘振，等. 堵漏材料研究的进展[J]. 材料研究与应用， 2011， 5（1）:14-16， 38. doi: 10.3969/j.issn.1673-9981.2011.01.004 JIA Lili, TIAN Lufei, LIU Zhen, et al. Research progress of lost circulation materials[J]. Materials Research and Application, 2011, 5(1): 14-16, 38. doi: 10.3969/j.issn.1673-9981.2011.01.004
[14] VERRET R J. Method for decreasing lost circulation during well operation US: US6976537B1[P]. 2005.
[15] 吴瑞红，孙会娟，周晓霞，等. 淀粉基绿色吸水性树脂的制备及抑尘性能[J]. 安徽化工， 2021， 46（7）:57-58， 61. doi: 10.3969/j.issn.1008-553X.2021.06.015 WU Ruihong, SUN Huijuan, ZHOU Xiaoxia, et al. Preparation and dust suppressant properties of green waterabsorbent resin based on starch[J]. Anhui Chemical Industry, 2021, 46(7): 57-58, 61. doi: 10.3969/j.issn.1008553X.2021.06.015
[16] 刘森彪，朱建锋，杜之琳，等. 丙烯酸高吸水性聚合物的室温原位合成与吸/释水性能研究[J]. 陕西科技大学学报， 2023， 41（4）:93-96. doi: 10.19481/j.cnki.issn2096398x.2023.04.009 LIU Senbiao, ZHU Jianfeng, DU Zhilin, et al. Study on in-situ room temperature synthesis and water absorption/release properties of acrylic super absorbent polymer[J]. Journal of Shaanxi University of Science & Technology, 2023, 41(4): 93-96. doi: 10.19481/j.cnki.issn2096-398x.2023.04.009
[17] 朱正，赵宇，张东真，等. 3种丙烯酸系列高吸水树脂的吸水性能[J]. 应用化学， 2013， 30（11）:1265-1269. doi: 10.3724/SP.J.1095.2013.20581 ZHU Zheng, ZHAO Yu, ZHANG Dongzhen, et al. Water absorbency performance of three kinds of polyacrylate superabsorbent polymer[J]. Chinese Journal of Applied Chemistry, 2013, 30(11): 1265-1269. doi: 10.3724/SP.J.1095.2013.20581
[18] XU Zhe, SUN Jinsheng, LI Li, et al. Development and performance evaluation of a high temperature resistant, internal rigid, and external flexible plugging agent for waterbased drilling fluids[J]. Petroleum, 2023, 9(1): 33-40.
[19] 翟科军，范胜，方俊伟，等. 吸水膨胀树脂复合堵漏剂的研发与性能评价[J]. 油田化学， 2021， 38（2）:196-230. doi: 10.19346/j.cnki.1000-4092.2021.02.002 ZHAI Kejun, FAN Sheng, FANG Junwei, et al. Development and evaluation of composite plugging agent of water-absorbent swelling resin[J]. Oilfield Chemistry, 2021, 38(2): 196-230. doi: 10.19346/j.cnki.1000-4092.2021.02.002
[20] 李莉，张赛，何强，等. 响应面法在试验设计与优化中的应用[J]. 实验室研究与探索， 2015， 34（8）:41-45. doi: 10.3969/j.issn.1006-7167.2015.08.011 LI Li, ZHANG Sai, HE Qiang, et al. Application of response surface methodology in experiment design and optimization[J]. Research and Exploration in Laboratory, 2015, 34(8): 41-45. doi: 10.3969/j.issn.1006-7167.2015.08.011
[21] 李强，李志勇，张浩东，等. 响应面法优化纳米材料稳定的泡沫钻井液[J]. 钻井液与完井液， 2020， 37（1）:23-30. doi: 10.3969/j.issn.1001-5620.2020.01.004 LI Qiang, LI Zhiyong, ZHANG Haodong, et al. Study on foam drilling fluid stabilized with nanomaterials optimized with RSM[J]. Drilling Fluid & Completion Fluid, 2020, 37(1): 23-30. doi: 10.3969/j.issn.1001-5620.2020.01.004
[22] SALEHNEZHAD L, HEYDARI A, FATTAHI M. Experimental investigation and rheological behaviors of water-based drilling mud contained starch-ZnO nanofluids through response surface methodology[J]. Journal of Molecular Liquids, 2019, 276: 417-430. doi: 10.1016/j.molliq.2018.11.142
[23] WEREMFO A, ABASSAH-OPPONG S, ADULLEY F, et al. Response surface methodology as a tool to optimize the extraction of bioactive compounds from plant sources[J]. Journal of the Science of Food and Agriculture, 2023, 103(1): 26-36. doi: 10.1002/jsfa.12121
[24] AQUINO G, BASILICATA M G, CRESCENZI C, et al. Optimization of microwave-assisted extraction of antioxidant compounds from spring onion leaves using BoxBehnken design[J]. Scientific Report, 2023, 13(1): 14923. doi: 10.1038/s41598-023-42303-x
[25] BUENAÑO L, ALI E, JAFER A, et al. Optimization by Box-Behnken design for environmental contaminants removal using magnetic nanocomposite[J]. Scientific Reports, 2024, 14(1): 6950. doi: 10.1038/s41598-024-57616-8
[26] NUNES R W, MARTIN J R, JOHNSON J F. Influence of molecular weight and molecular weight distribution on mechanical properties of polymers[J]. Polymer Engineering & Science, 2004, 22(4): 205-228. doi: 10.1002/pen. 760220402
[27] 齐铭策. PAA型丙烯酸系防水堵漏剂的特性及地坪治漏[J]. 新乡学院学报， 1995（1）:50-51. QI Mingce. Characteristics of PAA type acrylic waterproofing and plugging agent and floor leakage control[J]. Journal of Xinxiang University, 1995(1): 50-51.
[28] 樊鹏飞. WY-CN龙马溪组页岩水平井井壁坍塌失稳机理研究[D]. 成都:西南石油大学， 2016. FAN Pengfei. Research on the mechanism of wellbore collapse and instability in the WY-CN Longmaxi Formation shale horizontal well[D]. Chengdu: Southwest Petroleum University, 2016.

钻井液用高吸水性树脂的防漏堵漏性能研究

Research on High Water Absorbent Resin for Leak Prevention and Sealing in Water-based Drilling Fluid

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